Answer:
The correct answer is 0.186 V
Explanation:
The two hemirreactions are:
Reduction: Fe²⁺ + 2 e- → Fe(s)
Oxidation : Co(s) → Co²⁺ + 2 e-
Thus, we calculate the standard cell potential (Eº) from the difference between the reduction potentials of cobalt and iron, respectively, as follows:
Eº = Eº(Fe²⁺/Fe(s)) - Eº(Co²⁺/Co(s)) = -0.28 V - (-0.447 V) = 0.167 V
Then, we use the Nernst equation to calculate the cell potential (E) at 298.15 K:
E= Eº - (0.0592 V/n) x log Q
Where:
n: number of electrons that are transferred in the reaction. In this case, n= 2.
Q: ratio between the concentrations of products over reactants, calculated as follows:
[tex]Q = \frac{ [Co^{2+} ]}{[Fe^{2+} ]} = \frac{0.33 M}{1.47 M} = 0.2244[/tex]
Finally, we introduce Eº= 0.167 V, n= 2, Q=0.2244, to obtain E:
E= 0.167 V - (0.0592 V/2) x log (0.2244) = 0.186 V
a sample of gas occupies a volume of 2.62 liters at 25 C and 1.00 atm. what will be the volume at 50 C and 2 atm
Answer:2.62 L
Explanation:
A sample of gas occupies a volume of 2.62 liters at 25° C and 1.00 atm. and the volume at 50° C and 2 atm then volume is 2.62 liters.
What is ideal gas law ?The equation of state for a fictitious perfect gas is known as the ideal gas law, sometimes known as the generic gas equation. Although it has significant drawbacks, it is a decent approximation of the behavior of many gases under various situations.
An ideal gas is one in which there are no intermolecular attraction forces and all collisions between atoms or molecules are entirely elastic. It may be seen as a group of perfectly hard spheres that collide but do not else interact with one another.
By using ideal gas equation,
P₁ V ₁ ÷ T = P₂V₂ ÷ T
1 × 2.62 ÷ 25 = 2 × V₂ ÷ 50
V₂ = 1 × 2.62 × 50 ÷ 25 × 2
V₂ = 2.62 liters.
Thus, a sample of gas occupies a volume of 2.62 liters at 25° C and 1.00 atm. and the volume at 50° C and 2 atm then volume is 2.62 liters.
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Which describes the molecule below
Answer:
Option D. A lipid with three unsaturated fatty acid.
Explanation:
The molecule in the diagram above contains three fatty acid.
A careful observation of the molecule reveals that each of the three fatty acids contains a double bond.
The presence of a double bond in a compound shows that the compound is unsaturated.
Thus, we can say that the molecule is a lipid with three unsaturated fatty acid.
An 80L capacity steel cylinder contains H2 at a pressure of 110 atm and 30 ° C, after extracting a certain amount of gas, the pressure is 80 atm at the same temperature. How many liters of hydrogen (measured under normal conditions) have been extracted?
Answer:
2200 L
Explanation:
Ideal gas law:
PV = nRT,
where P is absolute pressure,
V is volume,
n is number of moles,
R is universal gas constant,
and T is absolute temperature.
The initial number of moles is:
(110 atm) (80 L) = n (0.0821 L atm / K / mol) (30 + 273.15) K
n = 353.58 mol
After some gas is removed, the number of moles remaining is:
(80 atm) (80 L) = n (0.0821 L atm / K / mol) (30 + 273.15) K
n = 257.15 mol
The amount of gas removed is therefore:
n = 353.58 mol − 257.15 mol
n = 92.43 mol
At normal conditions, the volume of this gas is:
PV = nRT
(1 atm) V = (92.43 mol) (0.0821 L atm / K / mol) (273.15 K)
V = 2162.5 L
Rounded, the volume is approximately 2200 liters.
Divers often inflate heavy duty balloons attached to salvage items on the sea floor. If a balloon is filled to a volume of 1.20 L at a pressure of 6.25 atm, what is the volume of the balloon when it reaches the surface?
Answer:
7.50 L
Explanation:
The balloon has a volume of 1.20 L (V₁) when the pressure at the sea floor is 6.25 atm (P₁). When it reaches the surface, the pressure is that of the atmosphere, that is, 1.00 atm (P₂). If we consider the gas to behave as an ideal gas and the temperature to be constant, we can calculate the final volume (V₂) using Boyle's law.
P₁ × V₁ = P₂ × V₂
V₂ = P₁ × V₁ / P₂
V₂ = 6.25 atm × 1.20 L / 1.00 atm
V₂ = 7.50 L
What element is being reduced in the following redox reaction? MnO4-(aq) + H2C2O4(aq) → Mn2+(aq) + CO2(g) What element is being reduced in the following redox reaction? MnO4-(aq) + H2C2O4(aq) → Mn2+(aq) + CO2(g) H O Mn C
Answer: Mn is getting reduced.
Explanation:
Oxidation-reduction reaction or redox reaction is defined as the reaction in which oxidation and reduction reactions occur simultaneously.
Oxidation reaction is defined as the reaction in which a substance looses its electrons. The oxidation state of the substance increases.
Reduction reaction is defined as the reaction in which a substance gains electrons. The oxidation state of the substance gets reduced.
[tex]MnO_4^-(aq)+H_2C_2O_4(aq)\rightarrow Mn^{2+}(aq)+CO_2(g)[/tex]
Oxidation : As Manganese has an oxidation state of +7 in [tex]MnO_4^-[/tex] and +2 in [tex]Mn^{2+}[/tex], the oxidation state is decreasing and hence it is getting reduced.
Reduction : As carbon has an oxidation state of +3 in [tex]H_2C_2O_4[/tex] and +4 in [tex]CO_2[/tex], the oxidation state is increasing and hence it is getting oxidized.
The element which is reduced in the redox reaction is Mn.
The redox reaction is shown below:
MnO₄⁻(aq) + H₂C₂O₄(aq) → Mn²⁺(aq) + CO₂(g)
A redox reaction is the type of reaction which involves oxidation processes
occurring with a corresponding reduction process.
Oxidation reaction involves the reaction in which a substance loses its
electrons to become positively charged with an increase in the oxidation
state.
Reduction reaction is defined as the reaction in which a substance gains
electrons to become positively charged with a decrease in the oxidation
state.
MnO₄⁻ has an oxidation state of +7 and Mn²⁺ having an oxidation state of +2
signifies a decrease in the oxidation state.
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If one pound is the same as 454 grams, then convert the mass of 78 grams to pounds.
Answer:
0.17 lb
Explanation:
78 g * (1 lb/454 g)=0.17 lb
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A chamber contains equal molar amounts of He, Ne, Ar, and Kr. If the total chamber pressure is 1 atm, then the partial pressure (in atm) of Kr is:
Answer:
The correct answer is 0.25 atm.
Explanation:
As mentioned in the given question that the chamber comprises equal molar concentrations of He, Ne, Ar and Kr gas. So, let us assume that the moles of all the gases will be x then the total number of moles will be 4x.
The formula for calculating mole fraction is,
Mole fraction = mole of the substance/total moles
The mole fraction of Kr = x/4x = 0.25
The total pressure given in the chamber is 1 atm. Therefore, the partial pressure will be,
Partial pressure = mole fraction * Total pressure
Partial pressure = 0.25 * 1 = 0.25 atm.
The partial pressure of Kr is 0.25 atm.
We are told that there is an equal molar amounts of He, Ne, Ar, and Kr. If we decide to say, let the molar amount of each gas be x, the total number of moles of all the gases will now be; x + x+ x + x = 4x
Let us recall that partial pressure of a gas can be obtained form the formula;
Partial pressure = mole fraction × total pressure
Mole fraction of Kr = x/4x = 1/4
Total pressure = 1 atm
Partial pressure of Kr = 1/4 × 1 = 0.25 atm
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Calculate the number of iron atoms contained in 434.52 g of iron: Question 7 options: 2.620 x 10 26 Fe atoms 5.769 x 10 24 Fe atoms 4.685 x 10 24 Fe atoms 3.223 x 10 25 Fe atoms 1.169 x 10 23 Fe atoms
Answer:
[tex]\boxed {\boxed {\sf 4.685 \times 10^{24} \ Fe \ atoms}}[/tex]
Explanation:
We are asked to convert grams of iron to atoms of iron.
1. Convert Grams to MolesFirst, we convert grams to moles. We use the molar mass or the mass in 1 mole of a substance. This is found on the Periodic Table because the molar mass is equal to the atomic mass, but the units are grams per mole instead of atomic mass units. Look up iron's molar mass.
Fe: 55.84 g/molWe convert using dimensional analysis, so we must set up a ratio using the molar mass.
[tex]\frac {55.84 \ g \ Fe}{ 1 \ mol \ Fe}[/tex]
We are converting 434.52 grams to moles, so we multiply by this value.
[tex]434.52 \ g \ Fe *\frac {55.84 \ g \ Fe}{ 1 \ mol \ Fe}[/tex]
Flip the ratio so the units of grams of iron cancel.
[tex]434.52 \ g \ Fe *\frac { 1 \ mol \ Fe}{55.84 \ g \ Fe}[/tex]
[tex]434.52 *\frac { 1 \ mol \ Fe}{55.84}[/tex]
[tex]\frac { 434.52}{55.84} \ mol \ Fe[/tex]
[tex]7.781518625 \ mol \ Fe[/tex]
2. Convert Moles to AtomsNext, we convert moles to atoms. We use Avogadro's Number or 6.02 ×10²³. It is the number of particles (atoms, molecules, formula units, etc) in 1 mole of a substance. For this problem, the particles are atoms of iron. We set up another ratio using this number.
[tex]\frac {6.02 \times 10^{23} \ atoms \ Fe }{ 1 \ mol \ Fe}[/tex]
Multiply by the number of moles we calculated.
[tex]7.781518625 \ mol \ Fe *\frac {6.02 \times 10^{23} \ atoms \ Fe }{ 1 \ mol \ Fe}[/tex]
The units of moles of iron cancel.
[tex]7.781518625 *\frac {6.02 \times 10^{23} \ atoms \ Fe }{ 1 }[/tex]
[tex]4.68447421 \times 10^{24} \ atoms \ Fe[/tex]
The correct answer choice is Choice 3: 4.685 × 10²⁴ atoms of iron.
Fill in the blanks with the words given below- [Atoms, homogeneous, metals, true, saturated, homogeneous, colloidal, compounds, lustrous] 1.An element which are sonorous are called................ 2.An element is made up of only one kind of .................... 3.Alloys are ............................. mixtures. 4.Elements chemically combines in fixed proportion to form ........................ 5. Metals are................................... and can be polished. 6. a solution in which no more solute can be dissolved is called a .................... solution. 7. Milk is a .............. solution but vinegar is a .................. solution. 8. A solution is a ................... mixture. pls help, could not get these answers
Answer:
1. metals
2. atom
3. homogeneous
4. compounds
5. lustrous
6. saturated
7. colloidal
8. homogeneous
Explanation:
3. Strontium-90 is produced during the nuclear fission of uranium-235 and is part of nuclear fallout created by weapons testing. If the half-life of Sr-90 is 28 days, how long will it take for grass contaminated with Sr-90 to be safe (<2 percent of the starting radioactivity) for cattle to eat?
A. 158 days
B. 28 days
C. 1 year
D. 158 years
Answer:158 days (D)
Explanation:
It will take 158 days for grass contaminated with Sr-90 to be safe for cattle to eat. Therefore, option (A) is correct.
What is the half-life period?The half-life of a radioactive material is defined as the time that is needed to reduce the initial quantity of a radioactive element to half after disintegration.
The half-life of a radioactive element can be described as the characteristic of the element and does not influence by the initial amount of the radioactive substance.
Given, the half-life of the Strontium-90 = 28 days
The rate constant of the decay can be determined as:
[tex]t_{\frac{1}{2} } =\frac{0.693}{k}[/tex]
[tex]k=\frac{0.693}{t_{\frac{1}{2} } }[/tex]
k = 0.693/28
k = 0.025 day⁻¹
The concentration of Strontium-90 reduced to less than 2% is safe. Therefore final concentration [A] = 2 % = 0.02
[tex]t = \frac{2.303}{k} log \frac{[A_o]}{[A]}[/tex]
[tex]t = \frac{2.303}{0.02475} log \frac{1}{[0.02]}[/tex]
t = 158 days
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HELP! A man makes breakfast. He puts some toast in the toaster, and mixes some eggs with a little milk in a bowl. As he begins cooking the eggs, he smells the toast burning. He takes the toast out of the toaster and puts some butter on it, which melts. Finally, he pours some orange juice through a strainer to remove the pulp. He eats the meal, and he digests it as he drives to work in his car.
A. Which option correctly identifies a chemical and a physical change in the scenario?
B. Burning toast is a chemical change; straining orange juice is a physical change.
C. Digesting food is a physical change; the car burning gas is a chemical change.
D. Burning toast is a physical change; straining orange juice is a chemical change.
Digesting food is a chemical change; the car burning gas is a physical change.
Answer:B. Burning toast is a chemical change; straining orange juice is a physical change.
Explanation:
A Physical change Is a type of change on a substance that does not affect its composition but can only change the appearance of the substance.
While
A Chemical changes is one that changes the substance to an entirely new substance.
Now 1. Burning toast is a chemical change, This is because First, Burning is a chemical reaction on its own . The toast also is a different substance from the white bread itself to a brown substance .
2. Straining orange juice is a physical change because no new substance is being formed only a SEPARATION of the orange pulp from the juice.
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We have that Burning toast is a chemical change; straining orange juice is a physical change.
The correct option is Option B
Physical change
This Refers to a change to the Physical Characteristics of a substance
While
Chemical change is a change Chemical Characteristics of a substance
and
Physical changes tends to undergo reversible processes while
chemicals do not
Therefore
The correct option is Option B
Burning toast is a chemical change; straining orange juice is a physical change.
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the following glassware was found in a lab drawer: 12 beakers, 10 flasks and 60 test tubes. what percent of the glassware are test tubes?
Answer:
73.1707317073%
=> Approximately 73.2%
Explanation:
Total = 60 + 10 + 12
=> 82
Test tubes are 60/82
=> 30/41
=> 73.1707317073%
=> Approximately 73.2%
Answer:
73.17%
Explanation:
To find the percentage of test tubes to the overall glassware, we need to get the number of test tubes divided by the total number of glassware.
12 beakers + 10 flasks + 60 test tubes = 82 glassware
% test tube = 60 / 82 = .7317 ==> 73.17 %
So 73.17 % of the glassware was test tubes.
Cheers.
Aqueous ammonia is added to a mixture of silver chloride and water. Given that Kf for the reaction between Ag+ and NH3 is large, which of the following are true?
A) The free ions are favored over the complex ion.
B) The complex ion is favored over solid silver chloride.
C) The free Ag+ ion is unstable.
D) More silver chloride will precipitate.
Answer:
B) The complex ion is favored over solid silver chloride
C) The free Ag+ ion is unstable.
Explanation:
Hello,
In this case, since the dissociation of solid silver chloride occurs at equilibrium with a neglectable solubility product (very small Ksp), which means that the solid tends to remain undissolved:
[tex]AgCl(s)\rightleftharpoons Ag^+(aq)+Cl^-(aq)[/tex]
By the addition of ammonia, the following reaction is favored:
[tex]Ag^+(aq)+2NH_3(aq)\rightleftharpoons [Ag(NH_3)_2]^+(aq)[/tex]
Which has a large equilibrium constant, which means that the formation of the complex is assured. In such a way, by addition of more ammonia, more complex will be formed, therefore B) The complex ion is favored over solid silver chloride is true. Moreover, C) The free Ag+ ion is unstable, since they tend to form the complex once they are formed by the solid silver chloride so it readily reacts.
Best regards.
Predict the order of acid strengths in the following series of cationic species: CH3CH2NH3 +, CH3CH=NH2
Answer:
CH3CH=NH2+>CH3CH2NH3 +
Explanation:
There are certain structural features that determine the stability of cationic species. These features that lead to the stability and higher acid strength of cations are those features that stabilize the cation.
CH3CH=NH2+ is more acidic than CH3CH2NH3 + owing to the fact that CH3CH=NH2+ contains a double bond in close proximity with the hydrogen that can be lost as a proton. Electron withdrawal by the double bond (greater s character) makes it easier for this hydrogen to be lost as a proton compared to CH3CH2NH3 +.
PV = nRT. If P = 1 atm, V = 5.0 liter, R = 0.0821 L.atm/mol.K, and T = 293 K; what is the value of n?
Answer:
n = 0.207 mole
Explanation:
We have,
P = 1 atm
V = 5 liter
R = 0.0821 L.atm/mol.K
T = 293 K
We need to find the value of n. The relation is as follows :
PV = nRT
Solving for n,
[tex]n=\dfrac{PV}{RT}\\\\n=\dfrac{1\times 5}{0.0821 \times 293}\\\\n=0.207\ \text{mol}[/tex]
So, the value of n is 0.207 mol.
Write a balanced nuclear equation for the following: The nuclide thorium-234 undergoes beta decay to form protactinium-234 .
Answer:
²³⁴₉₀Th --> ²³⁴₉₁Pa + ⁰₋₁e
Explanation:
thorium-234 = ²³⁴₉₀Th
beta decay = ⁰₋₁e
protactinium-234 = ²³⁴₉₁Pa
The balanced nuclear equation is given as;
²³⁴₉₀Th --> ²³⁴₉₁Pa + ⁰₋₁e
What volume of 6.9 M NaOH is needed to completely titrate 0.42 L of 2.39 M phosphoric acid according to
the equation:
H3PO4(aq) + 3NaOH(aq) + Na3PO4(aq) + 3H2O(aq)
A) O 0.05 L
B) O6.93 L
C) O0.44 L
D) 03.01 L
E) 436.43 L
Taking into account the definition of molarity and the stoichiometry of the reaction, the correct option is option C) 0.44 L of 6.9 M NaOH is needed to completely titrate 0.42 L of 2.39 M phosphoric acid.
The balanced reaction is:
H₃PO₄ (aq) + 3 NaOH (aq) → Na₃PO₄ (aq) + 3 H₂O(aq)
Then, by stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:
H₃PO₄: 1 mole NaOH: 3 moles Na₃PO₄: 1 mole H₂O: 3 molesMolarity is the number of moles of solute that are dissolved in a given volume.
Molarity is determined by:
[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]
Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].
In this case, 0.42 L of 2.39 M phosphoric acid reacts. So, by definition of molarity, the number of moles that participate in the reaction is calculated as:
[tex]2.39 \frac{moles}{liter}=\frac{number of moles of phosphiric acid}{0.42 liters}[/tex]
Solving:
number of moles of phosphiric acid= 2.39 [tex]\frac{moles}{liter}[/tex]* 0.42 liters
number of moles of phosphiric acid= 1.0038 moles ≅ 1 mole
Approaching 1 mole of the amount of phosphoric acid required, then by stoichiometry of the reaction, 3 moles of NaOH are necessary to react with 1 mole of the acid.
Then by definition of molarity and knowing that 6.9 M NaOH is needed, you can calculate the necessary volume amount of NaOH by:
[tex]6.9 \frac{moles}{liter} =\frac{3 moles}{volume}[/tex]
Solving:
6.9 [tex]\frac{moles}{liter}[/tex]* volume= 3 moles
[tex]volume=\frac{3 moles}{6.9\frac{moles}{liter} }[/tex]
volume= 0.44 L
The correct option is option C) 0.44 L of 6.9 M NaOH is needed to completely titrate 0.42 L of 2.39 M phosphoric acid.
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A certain covalent compound is named sulfur hexafluoride. What's the chemical formula for this compound? A. F6S2 B. F6S C. S2F6 D. SF6
Answer: The sulphur hexafluoride will have a chemical formula of [tex]SF_6[/tex]
Explanation:
A covalent compound is a compound where the sharing of electrons takes place between two elements which are non-metals.
The naming of covalent compound is given by:
1. The less electronegative element is written first.
2. The more electronegative element is written second. Then a suffix is added with it. The suffix added is '-ide'.
3. If atoms of an element is greater than 1, then prefixes are added which are 'mono' for 1 atom, 'di' for 2 atoms, 'tri' for 3 atoms and so on.
Thus sulphur hexafluoride will have a chemical formula of [tex]SF_6[/tex]
Answer:
D. sf6
Explanation:
Arrange the following substances in the order of increasing entropy at 25°C. HF(g), NaF(s), SiF 4(g), SiH 4(g), Al(s) lowest → highest
Answer:
Al(s)<NaF(s)<HF(g)<SiH4(g)<SiF4(g)
Explanation:
Hello,
In this case, we can arrange the increasing order of entropy at 25 \°C by taking into account, at first, that since solids are more molecularly organized than gases, the first we have solid sodium fluoride and solid aluminium, but in this case, as the higher the molar mass, the higher the entropy, the molar mass of aluminium is 27 g/mol and 42 g/mol for sodium fluoride, therefore, we first have:
Al(s)<NaF(s)
Afterwards, since the molar mass of hydrogen fluoride (HF), silicon fluoride (SiF4) and silane (SiH4) are 20, 104 and 32 g/mol respctively, since silicon fluoride has the greater molar mass, it also has the higher entropy. In such a way, the overall order turns out:
Al(s)<NaF(s)<HF(g)<SiH4(g)<SiF4(g)
Best regards.
Acetonitrile (CH3CN) is an important industrial chemical. Among other things, it is used to make plastic moldings, which have multiple uses, from car parts to Lego bricks. Which one of the following statements about acetonitrile is not correct?a. Acetonitrile has 16 valence electrons in its Lewis structure. b. Acetonitrile has one triple bond. c. Acetonitrile has one pair of nonbonding electrons. d. All atoms satisfy the octet rule in acetonitrile. e. One carbon atom and the nitrogen atom have nonzero formal charges.
Answer:
One carbon atom and the nitrogen atom have nonzero formal charges.
Explanation:
The compound Acetonitrile has sixteen valence electrons as is easily San from its structure. It contains a carbon nitrogen triple bond with a lone pair of electrons on nitrogen. All atoms satisfy the octet rule and there is no hyper valent atom in the molecule.
The formal charge an carbon and nitrogen is calculated as follows;
No. of valence electron on atom - [non bonded electrons + no. of bonds]
Therefore, for carbon and nitrogen, we have;
formal charge on carbon = 4 - (0 + 4) = 0
formal charge on nitrogen = 5 - (2 + 3) = 0
Hence carbon and nitrogen both possess zero formal charges.
The Halogen Group is also known as the?
salt formers
acid makers
Answer:
I think b acid makers
Explanation:
hope it will help you
PLEASE HELP!!!!!!! The boiling point of water is 100ºC. The boiling point of acetone is 56ºC. Which statement about distilling a mixture of acetone and water is correct?\
A. Water will vaporize from the mixture before acetone.
B. Water is collected as it leaves the mixture.
C. Acetone remains in the original container.
D. Acetone is captured and cooled.
Answer:
D. Acetone is captured and cooled.
The correct answer is option D: Acetone is captured and cooled.
Distillation is a method of separation based on the difference in boiling point of two liquids.
The liquid that has a lower boiling point is first separated from the mixture. It vaporizes, cooled and collected before the liquid that has a higher boiling point.
In this case, acetone is captured and cooled before water since it has a boiling point of 56ºC and water has a boiling point of 100ºC.
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Help please due today
Answer:
It is a becaues i am a doctor and i know about that
Explanation:Just here to help
Enter your answer in the provided box.
The equilibrium constant KP for the reaction
CO(g) + Cl2(g) ⇌ COCl2(g)
is 5.62 × 1035 at 25°C. Calculate ΔG
o
f
for COCl2 at 25°C.
Answer:
The correct answer is -341.2 kJ per mole.
Explanation:
The reaction given is:
CO (g) + Cl₂ (g) ⇔ COCl₂ (g)
Kp = 5.62 × 10³⁵
T = 25 °C or 298 K
The formula for calculating ΔG is,
ΔG° = -RTlnKp
ΔG° = -8.314 × 298 ln (5.62 × 10^35)
ΔG° = -203.9 kJ/mol
ΔG° = ∑nΔG°f (products) -∑nΔG°f (reactants)
ΔG° = ΔG°f (COCl₂ (g)) - [ΔG°f (CO(g)) + ΔG°f (Cl₂(g))]
ΔG°f (COCl₂ (g)) = ΔG° + [ΔG°f (CO (g)) + ΔG°f (Cl₂(g))]
ΔG°f (COCl₂ (g)) = -203.9 + (-137.28 + 0.00)
ΔG°f (COCl₂ (g)) = -341.2 kJ/mol
The standard Gibbs free energy [tex]\mathbf{\Delta G^o_f}[/tex] for COCl2 at 25°C is -341.25 kJ/mol
The given equation for the chemical reaction is
CO(g) + Cl2(g) ⇌ COCl2(g)
At the temperature of 25°C = (273 + 25) K, the equilibrium constant [tex]\mathbf{K_p = 5.62\times 10^{35}}[/tex]
Consider the expression for the relationship between [tex]\mathbf{\Delta G^o}[/tex] and [tex]\mathbf{K_p }[/tex] for the equilibrium reaction can be expressed as:
[tex]\mathbf{\Delta G^o = - RT In K_p}[/tex]
where;
gas constant (R) = 8.314 × 10⁻³ kJ/K.mol∴
[tex]\mathbf{\Delta G^o = - (8.314 \times 10^{-3}\ kJ/K.mol \times 298 \ K) \times In (5.62 \times 10^{35} )}[/tex]
[tex]\mathbf{\Delta G^o = -2.477572\ K \times 82.31680992}[/tex]
[tex]\mathbf{\Delta G^o = 203.95 \ kJ}[/tex]
Thus, the standard free energy for the reaction is 203.95 kJ/mol
For a given reaction, the standard Gibbs free energy can be calculated by using the formula:
[tex]\mathbf{\Delta G^o_{rxn} = \sum n \Delta G^o_f (products) - \sum m \Delta G^o_f (reactants) }[/tex]
[tex]\mathbf{\Delta G^o_{rxn} =\Big [\Delta G^o_{f} (COCl_{2(g)} ) -\Big(\Delta G^o_{f} (CO)_{(g)} + \Delta G^o_{f} (Cl)_{2(g)} ) \Big ) \Big ] }[/tex]
replacing the values of and solving for COCl2 at standard free energy of formation of substances, we have:
[tex]\mathbf{-203.95 \ kJ/mol =\Big [\Delta G^o_{f} (COCl_{2(g)} ) -\Big(-137.3 kJ/mol + 0 \ kJ/mol\Big ) \Big ] }[/tex]
Collecting like terms, we have:
[tex]\mathbf{\Delta G^o_{f} (COCl_{2(g)} ) = -203.95 \ kJ/mol -137.3 kJ/mol }[/tex]
[tex]\mathbf{\Delta G^o_{f} (COCl_{2(g)} ) = -341.25 \ kJ/mol }[/tex]
Therefore, we can conclude that the standard Gibbs free energy [tex]\mathbf{\Delta G^o_f}[/tex] for COCl2 at 25°C is -341.25 kJ/mol
Learn more about standard Gibbs free energy here:
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what volume will it occupied 40 degrees celsius a gas sample was collected when a temperature is 27 degrees celsius and the volume of 1 L
Using Charles law
[tex]\boxed{\sf \dfrac{V_1}{T_1}=\dfrac{V_2}{T_2}}[/tex]
[tex]\\ \sf\longmapsto V_1T_2=V_2T_1[/tex]
[tex]\\ \sf\longmapsto 1(40)=27V_2[/tex]
[tex]\\ \sf\longmapsto V_2=\dfrac{40}{27}[/tex]
[tex]\\ \sf\longmapsto V_2=1.48\ell[/tex]
A scientist observes that the electrical resistance of a superconducting material drops to zero when the material is cooled to very low temperatures. Which of the following statements best describes what the scientist is observing?
The scientist is observing the electrical power of a superconductor.
The scientist is observing the temperature of a superconductor.
The scientist is observing an intensive property of a superconductor.
The scientist is observing an extensive property of a superconductor
Answer:
The scientist is observing an intensive property of a superconductor.
Explanation:
An intensive property is a bulk property of matter. This means that an intensive property does not depend on the amount of substance present in the material under study. Typical examples of intensive properties include; conductivity, resistivity, density, hardness, etc.
An extensive property is a property that depends on the amount of substance present in a sample. Extensive properties depend on the quantity of matter present in the sample under study. Examples of extensive properties include, mass and volume.
Resistance of a superconducting material has nothing to do with the amount of the material present hence it is an intensive property of the superconductor.
Answer:
The scientist is observing an intensive property of a superconductor.
Explanation:
its the only one that makes logical sense
How does distance between two objects affect their gravitational force? (2 points)
a
Force increases as distance increases.
b
Force decreases as distance increases.
c
Force decreases as distance decreases.
d
Force is not related to distance.
Answer:
Option B: as the distance between the objects increases the Force of gravity decreases
g When considering the effects of temperature on spontaneity, if both ΔH and ΔS are positive, _______. Select the correct answer below: the process is spontaneous at all temperatures
Explanation:
The spontaneity of a system is deduced by the sign of the gibbs free energy value. If it is negative, it means the process / reaction is spontaneous however a positive value indicates the such process is not spontaneous.
Gibbs free energy, enthalpy and entropy are related by the following equation;
ΔG = ΔH - TΔS
A positive value of enthalpy, H and entropy, S means that G would always be a negative value at all temperatures.
11.
What is the value of AH in k cal/mol for the following reaction?
CH3CH2CH3 + Br2
CH3 -CH-CH3 + HBr
Br
(1)
-12
(2)
-13
(3)
-15
(
4)
-16
Answer:
(1) -12 Kcal/mol
Explanation:
Our answer options for this question are:
(1) -12 Kcal/mol
(2) -13 Kcal/mol
(3) -15 Kcal/mol
(4) -16 Kcal/mol
With this in mind, we can start with the chemical reaction (Figure 1). In this reaction, two bonds are broken, a C-H and a Br-Br. Additionally, a C-Br and a H-Br are formed.
If we want to calculate the enthalpy value, we can use the equation:
ΔH=ΔHbonds broken-ΔHbonds formed
If we use the energy values reported, its possible to calculate the energy for each set of bonds:
ΔHbonds broken
C-H = 94.5 Kcal/mol
Br-Br = 51.5 Kcal/mol
Therefore:
105 Kcal/mol + 53.5 Kcal/mol = 146 Kcal/mol
ΔHbonds formed
C-Br = 70.5 Kcal/mol
H-Br = 87.5 Kcal/mol
Therefore:
70.5 Kcal/mol + 87.5 Kcal/mol = 158 Kcal/mol
ΔH of reaction
ΔH=ΔHbonds broken-ΔHbonds formed=(146-158) Kcal/mol = -12 Kcal/mol
I hope it helps!
The ΔHvap of nitrous oxide is 16.53 kJ · mol−1 and its ΔSvap is 89.51 J · mol−1 · K−1. What it the boiling point of nitrous oxide?
Answer:
[tex]T_b=-88.48\°C[/tex]
Explanation:
Hello,
In this case, since the entropy of vaporization is defined in terms of the enthalpy of vaporization and the boiling point of the given substance, nitrous oxide, as shown below:
[tex]\Delta _{vap}S=\frac{\Delta _{vap}}{T_b}[/tex]
Solving for the boiling point of nitrous oxide, we obtain:
[tex]T_b=\frac{\Delta _{vap}H}{\Delta _{vap}S}=\frac{16.53\frac{kJ}{mol}*\frac{1000J}{1kJ} }{89.51\frac{J}{mol} } \\ \\T_b=184.67K[/tex]
Which in degree Celsius is also:
[tex]Tb=184.67-273.15\\\\T_b=-88.48\°C[/tex]
Best regards.