Answer:
The correct answer is -341.2 kJ per mole.
Explanation:
The reaction given is:
CO (g) + Cl₂ (g) ⇔ COCl₂ (g)
Kp = 5.62 × 10³⁵
T = 25 °C or 298 K
The formula for calculating ΔG is,
ΔG° = -RTlnKp
ΔG° = -8.314 × 298 ln (5.62 × 10^35)
ΔG° = -203.9 kJ/mol
ΔG° = ∑nΔG°f (products) -∑nΔG°f (reactants)
ΔG° = ΔG°f (COCl₂ (g)) - [ΔG°f (CO(g)) + ΔG°f (Cl₂(g))]
ΔG°f (COCl₂ (g)) = ΔG° + [ΔG°f (CO (g)) + ΔG°f (Cl₂(g))]
ΔG°f (COCl₂ (g)) = -203.9 + (-137.28 + 0.00)
ΔG°f (COCl₂ (g)) = -341.2 kJ/mol
The standard Gibbs free energy [tex]\mathbf{\Delta G^o_f}[/tex] for COCl2 at 25°C is -341.25 kJ/mol
The given equation for the chemical reaction is
CO(g) + Cl2(g) ⇌ COCl2(g)
At the temperature of 25°C = (273 + 25) K, the equilibrium constant [tex]\mathbf{K_p = 5.62\times 10^{35}}[/tex]
Consider the expression for the relationship between [tex]\mathbf{\Delta G^o}[/tex] and [tex]\mathbf{K_p }[/tex] for the equilibrium reaction can be expressed as:
[tex]\mathbf{\Delta G^o = - RT In K_p}[/tex]
where;
gas constant (R) = 8.314 × 10⁻³ kJ/K.mol∴
[tex]\mathbf{\Delta G^o = - (8.314 \times 10^{-3}\ kJ/K.mol \times 298 \ K) \times In (5.62 \times 10^{35} )}[/tex]
[tex]\mathbf{\Delta G^o = -2.477572\ K \times 82.31680992}[/tex]
[tex]\mathbf{\Delta G^o = 203.95 \ kJ}[/tex]
Thus, the standard free energy for the reaction is 203.95 kJ/mol
For a given reaction, the standard Gibbs free energy can be calculated by using the formula:
[tex]\mathbf{\Delta G^o_{rxn} = \sum n \Delta G^o_f (products) - \sum m \Delta G^o_f (reactants) }[/tex]
[tex]\mathbf{\Delta G^o_{rxn} =\Big [\Delta G^o_{f} (COCl_{2(g)} ) -\Big(\Delta G^o_{f} (CO)_{(g)} + \Delta G^o_{f} (Cl)_{2(g)} ) \Big ) \Big ] }[/tex]
replacing the values of and solving for COCl2 at standard free energy of formation of substances, we have:
[tex]\mathbf{-203.95 \ kJ/mol =\Big [\Delta G^o_{f} (COCl_{2(g)} ) -\Big(-137.3 kJ/mol + 0 \ kJ/mol\Big ) \Big ] }[/tex]
Collecting like terms, we have:
[tex]\mathbf{\Delta G^o_{f} (COCl_{2(g)} ) = -203.95 \ kJ/mol -137.3 kJ/mol }[/tex]
[tex]\mathbf{\Delta G^o_{f} (COCl_{2(g)} ) = -341.25 \ kJ/mol }[/tex]
Therefore, we can conclude that the standard Gibbs free energy [tex]\mathbf{\Delta G^o_f}[/tex] for COCl2 at 25°C is -341.25 kJ/mol
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A filament for a light bulb needs to conduct electricity. Which of the elements listed below might be useful as a light bulb filament? Explain your thinking.
A. Tungsten, W
B. Sulfur, S
C. Bromine, Br
Answer:
A. tungsten
Explanation:
Tungsten is a material which high melting point ie. does not melt easily incase of high temperature
Answer:
option(A):Tungsten
Explanation:
tungsten has highest melting point.
What is the formula of a compound if a sample of the compound contains 0.492 mol X, 0.197 mol Y, and 0.295 mol Z?
Answer:
X₅Y₂Z₃
Explanation:
The formula of a compound is determined as the whole number ratio between moles of each element present in the molecule.
The molecule is made from X, Y and Z. To fin the ratio we will divide the given moles in the moles of Y (0.197 moles), because is the element with the low number of moles.
X = 0.492 moles / 0.197 moles = 2.5
Y = 0.197 moles / 0.197 moles = 1
Z = 0.295 moles / 0.197 moles = 1.5
But, as the formula is given just with whole numbers, if we multiply each number twice:
X = 2.5*2 = 5
Y = 1*2 = 2
Z = 1.5*2 = 3
The formula is:
X₅Y₂Z₃When scientists are ready to publish the result of their experiments why is it important for them to include a description of the procedure they used
Answer: So other scientist can replicate the experiment and see if they get the same results in other words, test reliability.
Explanation:
what js the percent yield of lithium hydroxide from a reaction of 7.40 g of lithium with 10.2 g of water? the actual yield was measured to be12.1 g
Answer:
89%.
Explanation:
We'll begin by writing the balanced equation for the reaction. This is given below:
2Li + 2H2O —> 2LiOH + H2
Next, we shall determine the masses of Li and H2O that reacted and the mass of LiOH produced from the balanced equation.
This is illustrated below:
Molar mass of Li = 7 g/mol
Mass of Li from the balanced equation = 2 x 7 = 14 g
Molar mass of H2O = (2x1) + 16 = 18 g/mol
Mass of H2O from the balanced equation = 2 x 18 = 36 g
Molar mass of LiOH = 7 + 16 + 1 = 24 g/mol
Mass of LiOH from the balanced equation = 2 x 24 = 48 g
Summary:
From the balanced equation above,
14 g of Li reacted with 36 g of H2O to produce 48 g of LiOH.
Next, we shall determine the limiting reactant. This can be obtained as follow:
From the balanced equation above,
14 g of Li reacted with 36 g of H2O.
Therefore, 7.4 g of Li will react with = (7.4 x 36)/14 = 19.03 g of H2O.
From the calculation made above, we can see that it will take a higher amount i.e 19.03 g than what was given i.e 10.2 g of H2O to react completely with 7.4 g of Li.
Therefore, H2O is the limiting reactant and Li is the excess reactant.
Next, we shall determine the theoretical yield of LiOH.
In this case we shall use the limiting reactant.
The limiting reactant is H2O and the theoretical yield of LiOH can be obtained as follow:
From the balanced equation above,
36 g of H2O reacted to produce 48 g of LiOH.
Therefore, 10.2 g of H2O will react to produce = (10.2 x 48)/36 = 13.6 g of LiOH.
Therefore, the theoretical yield of LiOH is 13.6 g
Finally, we shall determine the percentage yield of LiOH. This can be obtained as follow:
Actual yield = 12.1 g
Theoretical yield = 13.6 g
Percentage yield =..?
Percentage yield = Actual yield /Theoretical yield x 100
Percentage yield = 12.1/ 13.6 x 100
Percentage yield = 89%
Therefore, the percentage yield LiOH is 89%.
You are working in a lab when radiation alarms go off. You are able to hide inside a steel cabinet, whose sides are about 1.5 inches thick, until the alarm goes off. Preliminary reports show that the radiation was weakly ionizing and negatively charged. Were you safe in the cabinet?
A. Yes, it was beta radiation and the steel was enough to block it.
B. Yes, it was alpha radiation and not harmful.
C. No, it was beta radiation and very dangerous.
D. No, it was gamma radiation and can only be blocked by a thick wall of lead.
Answer
A
Explanation:
Beta radiation is only very dangerous when it is ingested or if there is nothing in the way. The steel should protect you.
Yes, it was beta radiation and the steel was enough to block it. Hence, option A is correct.
What is beta radiation?Beta radiation is a current of electrons released at a rate exceeding the speed of light, with kinetic energy between 0.2 MeV and 3.2 MeV. Due to their lower mass which is approximately 5.5×[tex]10^{-4}[/tex] amu (9.130×[tex]10^(-24)[/tex], interactions between β-particles and the atoms of pass-through materials are much less frequent than the interactions between 5-007-particles: less than 200 ion pairs are typically formed in each centimetre of the air passage.
When we are working in a lab when radiation alarms go off and we are able to hide inside a steel cabinet, whose sides are about 1.5 inches thick, until the alarm goes off.
Preliminary reports show that the radiation was weakly ionizing and negatively charged. Yes, it was beta radiation and the steel was enough to block it.
Hence, option A is correct.
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Which balanced redox reaction is occurring in the voltaic cell represented by the notation of A l ( s ) | A l 3 ( a q ) | | P b 2 ( a q ) | P b ( s ) Al(s)|AlX3 (aq)||PbX2 (aq)|Pb(s)
The question is missing. Here is the complete question.
Which balanced redox reaction is ocurring in the voltaic cell represented by the notation of [tex]Al_{(s)}|Al^{3+}_{(aq)}||Pb^{2+}_{(aq)}|Pb_{(s)}[/tex]?
(a) [tex]Al_{(s)}+Pb^{2+}_{(aq)} ->Al^{3+}_{(aq)}+Pb_{(s)}[/tex]
(b) [tex]2Al^{3+}_{(aq)}+3Pb_{(s)} -> 2Al_{(s)}+3Pb^{2+}_{(aq)}[/tex]
(c)[tex]Al^{3+}_{(aq)}+Pb_{(s)} ->Al_{(s)}+Pb^{2+}_{(aq)}[/tex]
(d) [tex]2Al_{(s)}+3Pb^{2+}_{(aq)} -> 2Al^{3+}_{(aq)}+3Pb_{(s)}[/tex]
Answer: (d) [tex]2Al_{(s)}+3Pb^{2+}_{(aq)} -> 2Al^{3+}_{(aq)}+3Pb_{(s)}[/tex]
Explanation: Redox Reaction is an oxidation-reduction reaction that happens in the reagents. In this type of reaction, reagent changes its oxidation state: when it loses an electron, oxidation state increases, so it is oxidized; when receives an electron, oxidation state decreases, then it is reduced.
Redox reactions can be represented in shorthand form called cell notation, formed by: left side of the salt bridge (||), which is always the anode, i.e., its half-equation is as an oxidation and right side, which is always the cathode, i.e., its half-equation is always a reduction.
For the cell notation: [tex]Al_{(s)}|Al^{3+}_{(aq)}||Pb^{2+}_{(aq)}|Pb_{(s)}[/tex]
Aluminum's half-equation is oxidation:
[tex]Al_{(s)} -> Al^{3+}_{(aq)}+3e^{-}[/tex]
For Lead, half-equation is reduction:
[tex]Pb^{2+}_{(aq)}+2e^{-} -> Pb_{(s)}[/tex]
Multiply first half-equation for 2 and second half-equation by 3:
[tex]2Al_{(s)} -> 2Al^{3+}_{(aq)}+6e^{-}[/tex]
[tex]3Pb^{2+}_{(aq)}+6e^{-} -> 3Pb_{(s)}[/tex]
Adding them:
[tex]2Al_{(s)}+3Pb^{2+}_{(aq)} -> 2Al^{3+}_{(aq)}+3Pb_{(s)}[/tex]
The balanced redox reaction with cell notation [tex]Al_{(s)}|Al^{3+}_{(aq)}||Pb^{2+}_{(aq)}|Pb_{(s)}[/tex] is
[tex]2Al_{(s)}+3Pb^{2+}_{(aq)} -> 2Al^{3+}_{(aq)}+3Pb_{(s)}[/tex]
Which of the following processes have a ΔS < 0? Which of the following processes have a ΔS < 0? carbon dioxide(g) → carbon dioxide(s) water freezes propanol (g, at 555 K) → propanol (g, at 400 K) methyl alcohol condenses All of the above processes have a ΔS < 0.
Answer:
All of the above processes have a ΔS < 0.
Explanation:
ΔS represents change in entropy of a system. Entropy refers to the degree of disorderliness of a system.
The question requests us to identify the process that has a negative change of entropy.
carbon dioxide(g) → carbon dioxide(s)
There is a change in state from gas to solid. Solid particles are more ordered than gas particles so this is a negative change in entropy.
water freezes
There is a change in state from liquid to solid. Solid particles are more ordered than liquid particles so this is a negative change in entropy.
propanol (g, at 555 K) → propanol (g, at 400 K)
Temperature is directly proportional to entropy, this means higher temperature leads t higher entropy.
This reaction highlights a drop in temperature which means a negative change in entropy.
methyl alcohol condenses
Condensation is the change in state from gas to liquid. Liquid particles are more ordered than gas particles so this is a negative change in entropy.
Plssssssssss answer this question
Answer:
Table salt: answer salt
Tea: answer acidic
Carbonated drinks: answer acidic
Baking powder: answer acid and base
Detergent: answer acid and basic
Alum: answer acidic
Explanation:
I hope this helps. Enjoy your day!
Need help with chemistry questions
Answer:
1. oxidation
2. reduction
3. oxidation
4. oxidation
Explanation:
Oxidation and Reduction in terms of hydrogen
Oxidation and Reduction with respect to Hydrogen Transfer. Oxidation is the loss of hydrogen. Reduction is the gain of hydrogen.Oxidation and Reduction in terms of Oxygen
Oxidation and Reduction with respect to Oxygen Transfer. Oxidation is the gain of Oxygen. Reduction is the loss of Oxygen.What is the concentration in ppm of 4 g of NaCl dissolved in 100 mL of water?
Which of the following types of electromagnetic radiation have higher frequencies than visible light and which have shorter frequencies than visible light? Sort them accordingly. ltems (6 items) (Drag and drop into the appropriate area below)
a. Gamma rays
b. Infrared radiation
c. Ultraviolet liht
d. X-rays
e. Microwaves
f. Radio waves
Answer:
Higher frequency than visible light - Ultraviolet light, X-rays, and Gamma rays
Lower frequency than visible light - Infrared radiation, microwaves, and Radio waves
Explanation:
The frequencies of electromagnetic radiations vary according to their wavelengths. The relationship between the frequency and wavelength of the waves is expressed such that:
λ = c/f, where λ = wavelength, c = speed of light, and f = frequency.
Thus, there is an inverse relationship between the wavelength and the frequency of electromagnetic waves.
The order of the electromagnetic waves based on their frequency from the lowest to the highest is radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma-rays
Hence, electromagnetic waves with higher frequencies than visible light include ultraviolet light, X-rays, and Gamma rays while those with lower frequencies include Infrared radiation, microwaves, and Radio waves.
Answer:
need points
Explanation:
(9443+45−9.9) (9443+45−9.9) ×8.4× 10 6
2. In what part of an atom can protons be found?
a. Inside the electrons
b. Inside the neutrons
C. Inside the atomic nucleus
d. Inside the electron shells
Answer:
c
Explanation:
it's found inside the atomic nucleus
The front curve of a spectacle lens is called?
Answer:
Corrective lense or just lens.
Explanation:
You are the captain of a ship, and you just hit an iceberg. Water is rushing into the ship and it is quickly sinking. A total of 10 people are on the ship and all of them are in grave danger! Hungry sharks are everwhere! The good news is that you have a lifeboat onboard. The bad news is that it only has room for 5 people. You don't know any of the people very well (only the information provided), and you don't have time to interview them before hopping onto the lifeboat. So, you do you keep, and why (and you do NOT have to keep yourself)?
Answer:
let the people who dont know how to fight on the life boat and the fighters can stay back and try to keep the sharks away.
9
What might happen if acidic chemicals were emitted into
the air by factories? Choose the best answer.
A
The acid would destroy metallic elements in the air
B
The acid would be neutralized by bases within clouds
C
Acid rain might destroy ecosystems and farmland
D
Violent chemical reactions would take place within the
atmosphere
co search
O
BI
Zeros laced at the end of the significant number are...
Answer:
Zeros located at the end of significant figures are significant.
Explanation:
Hope it will help :)
A compound is found to contain 30.45 % nitrogen and 69.55 % oxygen by weight. To answer the questions, enter the elements in the order presented above. 1. What is the empirical formula for this compound? 2. The molecular weight for this compound is 46.01 g/mol. What is the molecular formula for this compound?
Answer:
Empirical formulae is NO2
Molecular Formulae is NO2
H2+O=???????????????????
Answer:
H₂O
Explanation:
Two molecules of Hydrogen and one molecules of Oxygen, when mixed, create H₂O, or water. There is no scientific name for H₂O due to it's common name. It is just refereed to as "water" or H₂O.
13. Arrange each group of units from smallest to
largest
a)km, mm, cm, m
b) mg, kg, g
C) L, mL
d) s, ms, min, h
Answer:
A. mm,cm,m,Km
B. mg, g, Kg
C. mL,L
D. ms, s, min, h
Explanation:
How many moles of gaseous boron trifluoride, BF3, are contained in a 4.3421 L bulb at 787.9 K if the pressure is 1.218 atm?
Answer:
The amount of moles of gaseous boron trifluoride, BF₃, contained in a 4.3421 L bulb at 787.9 K if the pressure is 1,218 atm is 0.082 moles
Explanation:
An ideal gas is a theoretical gas that is considered to be made up of point particles that move randomly and do not interact with each other. Gases in general are ideal when they are at high temperatures and low pressures.
The pressure, P, the temperature, T, and the volume, V, of an ideal gas, are related by a simple formula called the ideal gas law:
P*V = n*R*T
where P is the gas pressure, V is the volume that occupies, T is its temperature, R is the ideal gas constant, and n is the number of moles of the gas.
In this case:
P= 1.218 atmV= 4.3421 Ln= ?R= 0.082 [tex]\frac{atm*L}{mol*K}[/tex]T= 787.9 KReplacing:
1.218 atm* 4.3421 L= n*0.082 [tex]\frac{atm*L}{mol*K}[/tex] *787.9 K
Solving:
[tex]n=\frac{1.218 atm* 4.3421 L}{0.082 \frac{atm*L}{mol*K}*787.9 K}[/tex]
n= 0.082 moles
The amount of moles of gaseous boron trifluoride, BF₃, contained in a 4.3421 L bulb at 787.9 K if the pressure is 1,218 atm is 0.082 moles
which of the following is an acid?
HF
KOH
LIF
NH3
Based on a pH scale, the chemical compound which is classified as an acid is: A. Hydrogen fluoride (HF).
What is a pH scale?A pH scale can be defined as a tool that is designed and developed for the measurement of the molar concentration of hydrogen ions (H⁺) in both acidic and alkaline (basic) solutions.
This ultimately implies that, a pH scale can be used to measure and specify the acidity, neutrality or basicity of any chemical solution.
In this scenario, the pH of each of the given chemical compound are as follows:
Hydrogen fluoride (HF): it has a pH of 1.0 but it's a weak acid.Potassium hydroxide (KOH): it has a pH of 13 and as such it's a strong base.Lithium fluoride (LIF): it has a pH of 7.5 and as such it's neutral.Ammonia (NH₃): it has a pH of 10 and as such it's a weak base.Read more on pH here: brainly.com/question/24233266
Describe ask a question in in sincence
Answer:
why do we dream
Explanation:
1. The manufacturer of the vinegar used in the experiment stated that the vinegar contained 5.0% acetic acid. What is the percent error between your result and the manufacturer statement
Answer:
72.8 % (But verify explanation).
Explanation:
Hello,
In this case, with the following obtained results, the percent error is computed as follows:
Volume of vinegar= 7.0 mL
Volume of NaOH= (7+6.6+6.4)/3= 6.7 mL
Used concentration of NaOH= 1.5M
Concentration of acetic acid= (concentration of NaOH*volume of NaOH)/volume of vinegar= (6.7mL*1.5M)/7.0M= 1.44M
Assuming we have 100 mL (0.100L) of vinegar, moles of acetic acid in vinegar = 1.44M x 0.100 L= 0.144 mol
Mass of acetic acid in 100g of vinegar = 0.144 mol x 60.0g/mol= 8.64 g
% of acetic acid in vinegar=8.64 %
% error in percentage of acetic acid = [(8.64% - 5.0%)/5.0] x 100=72.8 %
Clearly, this result depend on your own measurements, anyway, you can change any value wherever you need it.
Regards.
A compound (C_9H_9BrO_2) gives the following NMR data. Draw the structure of the compound.
'1^H-NMR: 1.39 ppm, t(3H); 4.38 ppm, q(2H); 7.57 ppm, d(2H); 7.90 ppm, d(2H)
13^C-NMR: 165.73; 131.56; 131.01; 129.84; 127.81; 61.18; 14.18
You do not have to consider stereo chemistry.
You do not have to explicitly draw H atoms.
Do not include lone pairs in your answer.
Answer:
ethyl 4-bromobenzoate
Explanation:
In this question, we can start with the Index of Hydrogen Deficiency (I.H.D):
[tex]I.H.D=\frac{2C+2+N-H-X}{2}=\frac{(2*9)+2+0-9-1}{2}~=~5[/tex]
This indicates, that we can have a benzene ring (I.H.D = 4) and a carbonyl group (I.H.D = 1), for a total of 5.
Additionally, in the 1H-NMR info, we have a triplet 1.39 (3H) followed by a doublet 4.38 (2H), this indicates the presence of an ethyl group ([tex]CH_3-CH_2-[/tex]). Also, in the formula, we have 2 oxygens if we have carbonyl group with 2 oxygens we have a high probability to have an ester group.
[tex]O=C-O-CH_2-CH_3[/tex]
Now, if we add this to the benzene ring and the "Br" atom that we have in the formula, we will have ethyl 4-bromobenzoate.
See figures 1 and 2 to further explanations.
I hope it helps!
which of the following compounds are polar: CH2Cl2, HBr?
Answer : HBr polar
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How many grams of Br are in 445 g CaBr2 ?
Explanation:
The mass of bromine is 79.904, and since there are two of them in the Calcium Bromide molecule, we'll multiply it by 2 to get 159.808. Dividing that by the full mass of the molecule then multiply it by 100 will give you the answer.
Using the standard reduction potentials Ni2+(aq) + 2 e‑Ni(s) ‑0.25 volt Fe3+(aq) + e‑Fe2+(aq) +0.77 volt Calculate the value of E°cell for the cell with the following reaction. Ni2+(aq) + 2 Fe2+(aq) →Ni(s) + 2 Fe3+(aq)
Answer:
The correct answer is - 1.02 V
Explanation:
From the reduction-oxidation reaction:
Ni²⁺(aq) + 2 Fe²⁺(aq) → Ni(s) + 2 Fe³⁺(aq)
Ni²⁺ is reduced to Ni(s) while Fe²⁺ is oxidized to Fe³⁺. Thus, the half reactions are:
Reduction (cathode) : Ni²⁺(aq) + 2 e‑ → Ni(s) Eº= ‑0.25 V
Oxidation (anode) : 2 x (Fe²⁺ → Fe³⁺ + e-)(aq) Eº= -0.77 V
-------------------------------------
Ni²⁺(aq) + 2 Fe²⁺(aq) → Ni(s) + 2 Fe³⁺(aq)
In order to calculate the Eºcell, we have to add the reduction potential of the reaction in cathode (reduction) to the oxidation potential of the anode (oxidation):
Eºcell= Eºr + Eºo= (-0.25 V) + (-0.77 V) = - 1.02 V
What is silica gel commonly used for? A. Absorbing moisture to protect goods from damage. B. As insulation in buildings. C. As a lacquer on wood to make it water-resistant. D. A soft, flexible padding, such as on pen grips or mouse pads.
Answer:
A
Explanation:
Absorbing moisture to protect goods from damage. Hence, option A is correct.
What is silica gel?Silica gel is a desiccant, or drying agent, that manufacturers often place in little packets to keep moisture from damaging certain food and commercial products.
Silica Gel is a good drying agent for preventing corrosion, contamination, spoilage, and mould growth in many commodities and products due to its physical properties.
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The frequency of a signal is found to be 6389 with an uncertainty of 436 Hz. To the correct number of significant digits, it should be reported as:
Answer:
i hope it work
Explanation:
as
accurate reading range = reading ± uncertainty
so you have to say about accurate reading that its,lies in range
=(6389-436) →(6389+436)
=5953→6825
and the correct number of significant would be 3