Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus. The reactant is H2NCNHCH2CH2CH2CHCO minus, with an NH group, with a lone pair at the N atom, double-bonded to the first (from left to right) carbon, an NH2 group attached to the fifth carbon, an O atom double-bonded to the sixth carbon and a lone pair of electrons at the first and the second N atoms of the chain. The product has the same structure as the reactant, except that not an NH group with a lone pair, but an NH2 plus group is double-bonded to the first carbon. In addition, an NH3 plus group is attached to the fifth carbon instead of the NH2 group.

Answers

Answer 1

Answer:

Due to the resonance structures

Explanation:

In the question:

"Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus"

We have to take into account the structure of the amino acid arginine. In which, we have the amino and the carboxylic groups in the right and the guanidine group in the left.

In this group, we have a central carbon with three nitrogen atoms around and a double bond with the nitrogen on the top. This nitrogen on the top will accept the proton because the structure produced will have a positive charge on this nitrogen. Then, the double bond with the carbon can be delocalized into the nitrogen producing a positive charge in the carbon.

In this structure (the carbocation), we can have several resonance structures. In the blue option, we can produce a double bond with the nitrogen on the right. In the purple option, we can produce a double bond with the nitrogen on the left.

In conclusion, if the nitrogen in the top on the guanidine group accepts an hydrogen atom and we will have several resonance structures that can stabilize the molecule. Due to this, the nitrogen in the top its the best option to accept hydrogens.

See figure 1

I hope it helps!

Explain Why, When The Guanidino Group Of Arginine Is Protonated, The Double-bonded Nitrogen Is The Nitrogen

Related Questions

Name the following cycloalkane:
H3C-
CH2CH3
A. 1-ethyl-4-methylcyclohexane
B. 4-ethyl-1-methylcyclohexane
C. 1-methyl-4-ethylcyclohexane

Answers

Answer:

A

Explanation:

1-ethyl-4-methylcyclohexane

i believe it is A

hope that helped :)

11. The mass (in grams) of FeSO4.7H2O required for preparation of 125 mL of 0.90 M
solution is:
(a) 16 g
(b) 25 g
(c) 13 g
(d) 31 g
(e) 43 g

Answers

Answer:

what does little birdie say in the birth of their differences lak lak lak nu pasand aayi baby sleep are no longer children all strong industry all strong baby to show the meaning of rice is here to get up from sleep meaning of lips is Hasan let the mother is saying the baby to sleep in a new

Taking into account the definition of molarity and the molar mass of the compound, the correct answer is option (d): the mass of FeSO₄.7H₂O required for preparation of 125 mL of 0.90 M  solution is 31 g.

In first place, you have to know tha molarity is a measure of the concentration of that substance that indicates the number of moles of solute present in the solution.

The molarity of a solution is calculated by dividing the moles of the solute by the volume of the solution.

[tex]molarity=\frac{number of moles of solute}{volume of solution}[/tex]

Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].

In this case, you know:

molarity= 0.90 Mnumber of moles of solute= ?volume= 125 mL= 0.125 L (being 1000 mL=1 L)

So, by definition of molarity, the number of moles is calculated as:

[tex]0.90 M=\frac{number of moles of solute}{0.125 L}[/tex]

Solving:

number of moles of solute= 0.90 M× 0.125 L

number of moles of solute= 0.1125 moles

On the other side, molar mass is the mass of one mole of a substance, which can be an element or a compound. In this case, the molar mass of FeSO₄.7H₂O is 277.85 [tex]\frac{g}{mole}[/tex].

Then you can apply the following rule of three: if by definition of molar mass, 1 mole of the compound contains 277.85 g, 0.1125 mole contains how much mass?

[tex]mass=\frac{0.1125 moles*277.85 g}{1 mole}[/tex]

Solving:

mass ≅ 31 g

Finally, the correct answer is option (d): the mass of FeSO₄.7H₂O required for preparation of 125 mL of 0.90 M  solution is 31 g.

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The recommended application for dicyclanil for an adult sheep is 65 mg/kg of body mass. If dicyclanil is supplied in a spray with a concentration of 50. mg/mL, how many milliliters of the spray are required to treat a 70.-kg adult sheep?

Answers

Answer:

91 millilitres

Explanation:

Recommended application = 65mg / Kg

This means 65 mg of dicyclanil per kg (1 kg of body mass).

Concentration = 50 mg / mL

How many millilitres required to treat 70kg adult?

If 65mg = 1 kg

x = 70 mg

x = 70 * 65 = 4550 mg

Concentration = Mass / Volume

50 mg/mL = 4550 / volume

volume = 4550 / 50 = 91 mL

Uhm cell parts and functions

Answers

A cell is the structural and fundamental unit of life. The study of cells from its basic structure to the functions of every cell organelle is called Cell Biology. Robert Hooke was the first Biologist who discovered cells

two types of cell

1) Prokaryotes

2) Eukaryotes

Characteristics of Cells

1) Cells provide structure and support to the body of an organism.

2) The cell interior is organised into different individual organelles surrounded by a separate membrane.

3) The nucleus (major organelle) holds genetic information necessary for reproduction and cell growth

[tex]hope \: its \: helpful \: to \: you \: please \: mark \: me \: a \: brainliest[/tex]

A cell is defined as the fundamental, structural and functional unit of all life.

have a great day

God bless you

Which of the reactions are spontaneous (favorable)? DHAP↽−−⇀glyceraldehyde-3-phosphateΔG=3.8 kJ/mol C4H4O5⟶C4H2O4+H2OΔG=3.1 kJ/mol C2H4+H2−→−−Rh(I)C2H6ΔG=−150.97 kJ/mol glutamate+NAD++H2O⟶

Answers

Answer:

C₂H₄ + H₂ →−−Rh(I) C₂H₆ Δ

The concentration of glucose, C6H12O6, in normal spinal fluid is 75 mg/100g. What is the molality of the solution

Answers

Answer:

4.16x10⁻³m

Explanation:

Molality is defined as the ratio between moles of a solute, in this case glucose, and kg of solvent.

As there are 100g of solvent, the kg are 0.1. Thus, we only need to calculate from the mass of glucose its moles to solve the molality of the solution.

Moles glucose:

There are 75mg = 0.075g of glucose. To conver mass to moles it is necessary molar mass.

Molar mass glucose:

6C = 12.01g/mol*6 = 72.06g/mol

12H = 12*1.008g/mol = 12.10g/mol

6O = 6*16g/mol = 96g/mol

72.06 + 12.10 + 96 = 180.16g/mol

Moles of 0.075g of glucose:

0.075g * (1 mol / 180.16g) =

4.16x10⁻⁴ moles of glucose

Molality of the solution:

4.16x10⁻⁴ moles of glucose / 0.1kg of solvent =

4.16x10⁻³m

The molarity of the solution is 4.16x10⁻³m

Calculation of the molarity:

We know that the molarity refers to the ratio that arise between the moles of a solute.

Since there are 100 g of solvent so here the kg should be 0.1.

Likewise there is 75 mg so it should be 0.075g

Now the Molar mass glucose should be

6C = 12.01g/mol*6 = 72.06g/mol

12H = 12*1.008g/mol = 12.10g/mol

6O = 6*16g/mol = 96g/mol

So,

= 72.06 + 12.10 + 96

= 180.16g/mol

Now

Moles of 0.075g of glucose:

0.075g * (1 mol / 180.16g) =

4.16x10⁻⁴ moles of glucose

Now finally

Molality of the solution:

= 4.16x10⁻⁴ moles of glucose / 0.1kg of solvent

=4.16x10⁻³m

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1.78 L of gas is at a pressure of 735 torr. What is the volume in liters (L) when the pressure decreases to 700.0 torr

Answers

Explanation:

using boyles law

p1v1=p2v2

735 x 1.76 = 700 x V2

1293.6 = 700 x V2

V2 = 1293.6/700

V2 = 1.85L

A voltaic cell is set up as follows: Anode: Zn electrode in a solution of 0.050 M Zn(NO 3 ) 2 Cathode: Pt electrode with 0.500 atm H 2 (g) in 0.010 M HNO 3 a) Write the overall balanced cell reaction.

Answers

Answer:

[tex]Zn(s) + 2H+(aq)\Rightarrow Zn^{2+}(aq) + H_{2}(g)[/tex]

Explanation:

Given that,

Anode : Zn electrode in a solution of 0.050 M Zn(NO₃)₂

Cathode : Pt electrode with 0.500 atm H₂(g) in 0.010 M HNO₃

Anode :

[tex]Zn(s)\Rightarrow Zn^{2+}(aq) + 2e^{-}[/tex]

Cathode :

[tex]2H+(aq)+2e^{-}\Rightarrow H_{2}(g)[/tex]

We need to write the overall balanced cell reaction

Using anode and cathode

[tex]Zn(s) + 2H+(aq)\Rightarrow Zn^{2+}(aq) + H_{2}(g)[/tex]

Hence, This is required answer.

How many shapes contains the same text: KTKEIHLPEQMKJAPDEK

Answers

In this figure, four shapes contains the same text as in the red oval. The text given in the red oval is KTKEIHLPEQMKJAPDEK.

What is shape?

Shape is "the form of an object or its outline, outer boundary or outer surface".

What is text?

Text is "a collection of words or letters that are understandable by the reader".

What is an oval?

Oval is a rounded and slightly elongated outline or shape like that of an egg.

Hence, four shapes contains the same text as in the red oval.

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Which of the following represents six molecules of water? 6HO 2 6H 2O 1 6H 2O H 6O

Answers

Answer:

6H20 represents six molecules of water

Answer:

6H20 represents six molecules of water

Explanation:

A particular reaction at constant pressure is spontaneous at 390K. The enthalpy change for this reaction is +23.7kJ. What can you conclude about the sign and magnitude of ΔS for this reaction?a. smallb. largec. + smalld. + largee. 0.0

Answers

Answer:

+ small

Explanation:

The entropy is obtained from;

∆S= ∆H/T

Where;

∆S= entropy of the system

∆H= enthalpy if the system = +23.7 KJ

T= absolute temperature of the system = 390 K

∆S= 23.7 ×10^3/390 = 60.8 JK^-

There is a small positive change in entropy.

For a particular reaction, ΔH∘=−28.4 kJ and ΔS∘=−87.9 J/K. Assuming these values change very little with temperature, at what temperature does the reaction change from nonspontaneous to spontaneous?

Answers

Answer:

323 K

Explanation:

Since it is in equilibrium, we get  Δ=0=Δ−Δ

                                                      Δ=Δ

                                                      =ΔΔ

Now we solve for T

T = ( -28.4 kJ) / (-87.9 J/K * 1kJ/1000J) = 323 K

Based on the fact that there is very little change in value with temperature, the temperature that the reaction changes to spontaneous would be 323.1K.

What temperature causes a reaction change to be spontaneous?

This can be found as:

ΔH∘ = Temperature x  ΔS∘

Temperture = ΔH∘ /  ΔS∘

Solving gives:

= - 28.4 / - 87.9

= 323.1 k

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When a marble is dropped into a beamer of water

Answers

Answer:

The water will rise.

Explanation:

hope this helps you

-Sweety<3

The mass of the marble is greater than that of the water. The marble weighs more than an equivalent volume of the water. The force from dropping the marble breaks the surface tension of the water. The marble has greater mass and volume than the water.

What type of chemist exclusively studies most carbon compounds?
-biochemist
-physical chemist
-organic chemist
-inorganic chemist

Answers

Answer:

Organic chemist? I do not know.

Explanation:

Thanks you.

The type of chemist exclusively studies most carbon compounds are organic chemist. Therefore, option C is correct.

What is an organic chemist ?

The structure, characteristics, and reactivity of compounds containing carbon are studied by organic chemists. Additionally, they create novel organic materials with distinct features and uses.

Analytical capabilities, communication skills, and numeracy skills are three of the most important soft skills for an organic chemist.

Organic chemists often work in research and development in labs at universities, pharmaceutical, industrial, and biotechnology businesses, as well as government agencies, according to the American Chemical Society.

According to one assessment, organic chemistry is the hardest college course. According to certain statistics, almost one out of every two students in organic chemistry leave the course. The hopes of a medical career come tumbling down for those who fit this description. Organic chemistry is undoubtedly challenging.

Thus, option C is correct.

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A sample of oxygen gas at a pressure of 1.19 atm and a temperature of 24.4 °C, occupies a volume of 18.7 liters. If the gas is allowed to expand at constant temperature to a volume of 29.4 liters, the pressure of the gas sample will be ______ atm.

Answers

Answer:

[tex]\boxed {\boxed {\sf 0.757 \ atm}}[/tex]

Explanation:

We are asked to find the pressure of a gas given a change in volume. Since the temperature remains constant, we are only concerned with volume and pressure. We will use Boyle's Law, which states the volume is inversely proportional to the pressure. The formula for this law is:

[tex]P_1V_1= P_2V_2[/tex]

Initially, the oxygen gas occupies a volume of 18.7 liters at a pressure of 1.19 atmospheres.

[tex]1.19 \ atm * 18.7 \ L = P_2V_2[/tex]

The gas expands to a volume of 29.4 liters, but the pressure is unknown.

[tex]1.19 \ atm * 18.7 \ L = P_2 * 29.4 \ L[/tex]

We are solving for the new pressure, so we must isolate the variable [tex]P_2[/tex]. It is being multiplied by 29.4 liters. The inverse operation of multiplication is division. Divide both sides of the equation by 29.4 L.

[tex]\frac {1.19 \ atm * 18.7 \ L}{29.4 \ L} =\frac{ P_2 * 29.4 \ L}{29.4 \ L}[/tex]

[tex]\frac {1.19 \ atm * 18.7 \ L}{29.4 \ L} =P_2[/tex]

The units of liters cancel.

[tex]\frac {1.19 \ atm * 18.7 }{29.4 } =P_2[/tex]

[tex]\frac {22.253}{29.4 } \ atm = P_2[/tex]

[tex]0.7569047619 \ atm =P_2[/tex]

The original measurements all have 3 significant figures, so our answer must have the same. For the number we calculated, that is the thousandth place. The 9 in the ten-thousandth place to the right of this place tells us to round the 6 up to a 7.

[tex]0.757 \ atm \approx P_2[/tex]

The pressure of the gas sample is approximately 0.757 atmospheres.

Answer:

According to Boyle's law, for a given mass of ideal gas, pressure of gas is inversely proportional to the volume of gas, Provided the Temprature remains constant.

P₁ = 1.19 atmP₂ = ?V₁ = 18.7 LV₂ = 29.4 LT = constant = 24.4° C = Isothermal process

[tex]\implies \sf P_1 V_1 = P_2 V_2 \\ [/tex]

[tex]\implies \sf 1.19 \times 18. 7= P_2 \times 29.4 \\[/tex]

[tex]\implies \sf 22.253= P_2 \times 29.4 \\[/tex]

[tex]\implies \sf P_2 = \dfrac{22.253}{29.4} \\[/tex]

[tex]\implies \underline{ \red{\boxed{ \bf P_2 \approx0.756 \: atm }}} \\[/tex]

Ammonium phosphate is an important ingredient in many fertilizers. It can be made by reacting phosphoric acid with ammonia . What mass of ammonium phosphate is produced by the reaction of of ammonia?

Answers

Answer:

The mass of ammonium phosphate produced is 14.3g

Explanation:

Full question contains: "What mass of ammonium phosphate is produced by the reaction of 4.9g of ammonia"

Ammonium phosphate ((NH₄)₃PO₄) can be produced by the reaction of phosphoric acid (H₃PO₄) with ammonia (NH₃) as follows:

H₃PO₄ + 3NH₃ → (NH₄)₃PO₄

Where 1 mole of phosphoric acid reacts with 3 moles of ammonia producing 1 mole of ammonium phosphate.

To know how many grams of ammonium phosphate we need to find moles of ammonia that react, and, with the chemical equation we can find moles of ammonium phosphate and its mass as follows:

Moles ammonia (Molar mass: 17.031g/mol):

4.9g × (1mol / 17.031g) = 0.288 moles of ammonia you have in 4.9g

Moles of ammonium phosphate (149.09g/mol) and its mass:

As 0.288 moles of NH₃ are reacting and 3 moles of ammonia produce 1 mole of ammonium phosphate, moles produced are:

Moles (NH₄)₃PO₄:

0.288 moles NH₃ ₓ (1 mol (NH₄)₃PO₄  / 3 mol NH₃) = 0.0959 moles (NH₄)₃PO₄

These moles are, in grams:

0.0959 moles (NH₄)₃PO₄ ₓ (149.09g / mol) = 14.3g ammonium phosphate.

The mass of ammonium phosphate produced is 14.3g

Use the following equation to determine the charge on bromine when it dissociates from sodium and determine whether it is being oxidized or reduced: Cl2 + NaBr -> NaCl + Br2A. It starts with a charge of 0 and is oxidized. B. It starts with a charge of -1 and is reduced. C. It starts with a charge of 0 and is reduced. D. It starts with a charge of -1 and is oxidized.

Answers

It starts with a charge of 0 and is oxidized. Hence, option A is correct.

What is a chemical equation?

A chemical reaction is a representation of symbols of the elements to indicate the number of substances and moles of reactant and product.

[tex]Cl_2 + NaBr[/tex] ->[tex]NaCl + Br_2[/tex]

The oxidation number of bromine changes from -1 (in  NaBr) to 0 (in Br

2). Thus, NaBr is oxidized.

The oxidation number of chlorine changes from 0 to -1. Thus, chlorine is reduced.

Hence, option A is correct.

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What is the quantity of heat evolved when 15g of CH4 is completely burned in air? Given that CH4+2O2→ CO2+2H2OΔH=-890Kj/mol

Answers

Answer:

You're going to have to convert the grams to moles, and then multiply that with the ratio of heat produced to the ratio of CH4

PLEASE HELP!!
this is on USAtestprep
a)
b)
c)
d)

Answers

D is the one or Na and MG
I’m pretty sure it’s d

In the pictured cell, the side containing zinc is the Choose... and the side containing copper is the Choose... . The purpose of the N a 2 S O 4 NaX2SOX4 is to

Answers

Answer:

Zinc- anode

Copper- cathode

Sodium sulphate- salt bridge

Explanation:

A galvanic cell is an electrochemical cell in which electrical energy is produced by a spontaneous chemical reaction.

In the pictured galvanic cell, zinc is the anode since it looses electrons according to the reaction; Zn(s) -----> Zn^2+(aq) + 2e

Copper is the cathode as shown here; Cu^2+(aq) + 2e ----> Cu(s)

Sodium sulphate functions as the salt bridge. It keeps the both solutions neutral by ensuring charge balance in the both half cells.

Answer:

zinc=anode

copper=cathode

Explanation:

i) Briefly discuss the strengths and weaknesses of the four spectroscopy techniques listed below. Include in your answer the specific structural information you get from each method.
 IR
 UV-VIS
 NMR
 Mass Spec

Answers

delete please .....................................

g The electronic structure of which ONE of the following species cannot be adequately described by a single Lewis formula? (In other words, the electronic structure of which one can only be described by drawing two or more resonance structures?) A) C2H4 B) SO3 2– C) SO3 D) C3H8 E) HCN

Answers

Answer:

C) SO3

Explanation:

Lewis formula shows the bonding between atoms of a molecule and expresses the lone pair present in the atoms.

SO3 or Sulfur trioxide cannot be adequately described by a single Lewis formula because it has majorly 3 resonance structures because Sulfur does not follow the octet rule and can expand electrons in its outer shell.

Hence, the correct answer is C) SO3

What separates the inner planets from the outer planets?

a. Main asteroid belt
b. Main comet belt
c. Kuiper belt
d. Outer planet belt
please help this is for SCIENCE test I need help

Answers

Answer:

main asteroid belt separates the inner planets from the outer planets

A 50.0 L cylinder of oxygen gas is stored at 150. atm. What volume would the oxygen gas occupy if the cylinder were opened into a hot air balloon (completely deflated) until the final pressure is 735 torr

Answers

Answer:

THE VOLUME OF THE OXYGEN GAS AFTER DEFLATION TILL A PRESSURE OF 735 TORR IS ATTAINED IS 7836.99 L

Explanation:

Using Boyle's law,

P1V1 = P2V2

P1 = 150 atm

V1 = 50 L

P2 = 735 Torr

V2 = unknown

We must first convert the pressures into the same SI unit for easy calculation

1torr = 1/760 atm

So converting 735 torr to atm; we have:

1 torr = 1/ 760 atm

735 torr = 735 * 1 / 760 atm

= 0.967 atm

In other words, P2 = 0.957 atm

So rearranging the formula by making V2 the subject of the equation, we have:

V2 = P1 V1 / P2

V2 = 150 * 50 / 0.957

V2 = 7836.99 L

The volume of the oxygen cylinder after deflation to a final pressure of 735 torr or 0.967 atm pressure is 7836.99 L.

Which of the following is an example of an optional deduction ? " a ) Medicare Ob ) Social Security c ) Retirement plan d ) State tax

Answers

Medicare  

United states program for people who are older than 60

Given the equation representing a nuclear reaction in
which X represents a nuclide:
232Th → He + x
Which nuclide is represented by X?
A) 236
B) 228
Ra
SS
C) 236
Ra
92
U
92
D) 228
.
Ss U

Answers

The nuclide represented as X is thorium and this is an alpha decay.

The equation shown represents an alpha decay. In an alpha decay, an alpha particle is given off.

The atomic number of the parent nuclide is greater than that of the daughter nuclide by two units while the mass number of the parent is greater than that of the daughter nuclide by four units.

Hence the equation occurs as follows;

[tex]\frac{232}{92} Th ------> \frac{228}{88} Ra + He[/tex]

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If 11.2 g of naphthalene, C10H8, is dissolved in 107.8 g of chloroform, CHCl3, what is the molality of the solution

Answers

Answer:

CHC12

Explanation:

i am not really sure i am onna do a quick research 4 u tho

Determine whether the following statement about reaction rates is true or false. If the statement is false, select the reason why.
Increasing the temperature of a reaction system decreases the activation energy of the reaction.
A. True
B. False

Answers

Answer:

False

Explanation:

The reaction rate increases if the temperature also increases, as does the concentration of ractives or the presence of catalysts.

The reaction rate talks about how reagents are converted into products as a function of time, this process can take less or more depending on the factors to which the reaction is exposed.

The increasing temperature generates an increase in the kinetic energy of the particles, promoting their proximity and their reaction between them to be able to give the final product, so a faster reaction occurs, which is why it has promoted when the particles collide.

What does Avogadro's number represent? A. How much 1 atom of a substance weighs. B. The number of molecules in 1 mole of a substance. C. The number of molecules in 1 atomic number of a substance. D. How much 1 mole of a substance weighs.

Answers

Answer:

B, the number of molecules in 1 mole of a substance

how is the Sun classified?
A as a giant star
B as a medium star
C as a white star as a neutron star
D as a white dwarf​

Answers

Answer:

As a giant star.

Explanation:

A

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