For a particular reaction, ΔH∘=−28.4 kJ and ΔS∘=−87.9 J/K. Assuming these values change very little with temperature, at what temperature does the reaction change from nonspontaneous to spontaneous?

Answers

Answer 1

Answer:

323 K

Explanation:

Since it is in equilibrium, we get  Δ=0=Δ−Δ

                                                      Δ=Δ

                                                      =ΔΔ

Now we solve for T

T = ( -28.4 kJ) / (-87.9 J/K * 1kJ/1000J) = 323 K

Answer 2

Based on the fact that there is very little change in value with temperature, the temperature that the reaction changes to spontaneous would be 323.1K.

What temperature causes a reaction change to be spontaneous?

This can be found as:

ΔH∘ = Temperature x  ΔS∘

Temperture = ΔH∘ /  ΔS∘

Solving gives:

= - 28.4 / - 87.9

= 323.1 k

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Related Questions

What would be the voltage (Ecell) of a voltaic cell comprised of Cd(s)/Cd2+(aq) and Zr(s)/Zr4+(aq) if the concentrations of the ions in solution were [Cd2+] = 0.5 M and [Zr4+] = 0.5 M at 298K?

Answers

Answer:

1.05 V

Explanation:

Since;

E°cell= E°cathode- E°anode

E°cathode= -0.40 V

E°anode= -1.45 V

E°cell= -0.40-(-1.45) = 1.05 V

Equation of the process;

2Zr(s) + 4Cd^2+(aq) ---->2Zr^4+(aq) + 4Cd(s)

n= 8 electrons transferred

From Nernst's equation;

Ecell = E°cell - 0.0592/n log Q

Ecell= E°cell - 0.0592/8 log [0.5]/[0.5]

Since log 1=0

Ecell= E°cell= 1.05 V

What is Entropy?

A. The opposite of Enthalpy
B. The temperature at which a reaction is feasible.
C. A measure of disorder.
D. Free energy used for a reaction.

Answers

Answer:

C. A measure of disorder :)

Calculate the pH of a solution that is 0.210 M in nitrous acid (HNO2) and 0.290 M in potassium nitrite (KNO2). The acid dissociation constant of nitrous acid is 4.50 × 10-4.

Answers

Answer:

pH = 3.49

Explanation:

We have a buffer system formed by a weak acid (HNO₂) and its conjugate base (NO₂⁻ coming from KNO₂). We can calculate the pH  of a buffer ssytem using the Henderson-Hasselbach equation.

pH = pKa + log [base] / [acid]

pH = -log Ka + log [NO₂⁻] / [HNO₂]

pH = -log 4.50 × 10⁻⁴ + log 0.290 M / 0.210 M

pH = 3.49

The pH of the solution containing 0.210 M nitrous acid (HNO₂) and 0.290 M potassium nitrite (KNO₂) is 3.49

We'll begin by calculating the the pKa of acid. This can be obtained as follow:

Acid dissociation constant (Ka) = 4.50×10¯⁴

pKa =?

pKa = –Log Ka

pKa = –Log 4.50×10¯⁴

pKa = 3.35

Finally, we shall determine the pH of the solution.

pKa = 3.35

Concentration of HNO₂, [HNO₂] = 0.210 M

Concentration of KNO₂, [KNO₂] = 0.290 M

pH =?

The pH of the solution can obtain by using the Henderson-Hasselbach equation as illustrated below:

pH = pKa + log [base] / [acid]

pH = pKa+ log [NO₂⁻] / [HNO₂]

pH = 3.35 + log (0.290 / 0.210)

pH = 3.49

Thus, the pH of the solution is 3.49

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A graph of gas pressure versus the number of particles in a container is a straight line. Which other relationship will have a similar graph?​

Answers

Answer:

volume versus temperature, because they are also directly proportional.

Explanation:

Just took the test!

You wish to construct a galvanic cell with the anode consisting of a Ni electrode in a 1.0 M Ni(NO3)2 solution. What would be the highest standard cell potential if used as the cathode in this galvanic cell?

Answers

Answer:

Au^3+(aq) +3e ------> Au(s). 1.50 V

Explanation:

When we construct the galvanic cell, our intention is to produce energy by spontaneous electrochemical reactions. In order to have a spontaneous electrochemical reaction, E°cell must be positive. The more positive the value of E°cell, the more spontaneous the reaction is.

E°cell= E°cathode - E°anode

If E°cathode= 1.50 V

E°anode= -0.25 V

E°cell= 1.50 -(-0.25)

E°cell= 1.75 V

Hence the process; Au^3+(aq) +3e ------> Au(s) yields the highest standard cell potential

Which of the following has the greatest effect on colligative properties?

A. Calcium chloride (CaCl2)
B. Sodium chloride (NaCl)
C. Aluminum Nitrate (Al(NO3)3)
D. Epsom salt (MgSO4)

Answers

Answer:

C. Aluminum Nitrate (Al(NO3)3)

Explanation:

This is because, when Aluminium nitrate dissolves in water, it dissociates to form four ions ( one aluminium ion and three nitrate ions ). Since colligative property depends on number of particles or ions present ( roult's law ), this will create much effect.

[tex]Al(NO _{3} )_{3(aq)} → Al {}^{3 + } _{(aq)} + 3NO {}^{ - } _{(aq)}[/tex]

Answer:

aluminum nitrate (Al(NO3)3)

it has the greatest effect on collimation properties .

Explanation:

(c) is correct option

Using these metal ion/metal standard reduction potentials Cd2+(aq)|Cd(s) Zn2+(aq)|Zn(s) Ni2+(aq)|Ni(s) Cu2+(aq)/Cu(s) -0.40 V -0.76 V ‑0.25 V +0.34 V Calculate the standard cell potential for the cell whose reaction is Ni2+(aq) + Zn(s) →Zn2+(aq)+ Ni(s)

Answers

Answer: The standard cell potential for the cell is +0.51 V

Explanation:

Given : [tex]E^0_{Ni^{2+}/Ni}=-0.25V[/tex]

[tex]E^0_{Zn^{2+}/Zn}=-0.76V[/tex]

The given reaction is:

[tex]Ni^{2+}(aq)+Zn(s)\rightarrow Zn^{2+}(aq)+Ni(s)[/tex]

As nickel is undergoing reduction, it acts as cathode and Zinc is undergoing oxidation, so it acts as anode.

[tex]E^0_{cell}=E^0_{cathode}-E^0_{anode}[/tex]

where both [tex]E^0[/tex]  are standard reduction potentials.

Thus putting the values we get:

[tex]E^0_{cell}=-0.25-(-0.76)[/tex]

[tex]E^0_{cell}=0.51V[/tex]

Thus the standard cell potential for the cell is +0.51 V

The combination of a carbonyl group and a hydroxyl group on the same carbon atom is called a ________ group.

a. carbamate group
b. carbonate
c. carboxlate
d. carboxyl

Answers

Answer:

d. carboxyl

Explanation:

The presence of carbonyl group (>C=O)) and a hydroxyl group ( (−OH) on the same carbon atom is called a "carboxyl" group. A carboxyl group is represented as COOH and acts as the functional group part of carboxylic acids.

For example:

Formic acid or Methanoic acid (H-COOH)  Butanoic acid (C3H7-COOH)

Hence, the correct option is "d. carboxyl ".

When the nuclide bismuth-210 undergoes alpha decay:
The name of the product nuclide is_____.
The symbol for the product nuclide is_____
Fill in the nuclide symbol for the missing particle in the following nuclear equation.
_____ rightarrow 4He+ 234Th
2 90
Write a balanced nuclear equation for the following:
The nuclide radium-226 undergoes alpha emission.

Answers

Explanation:

An atom undergoes alpha decay by losing a helium atom.

So when bismuth undergoes alpha decay, we have;

²¹⁰₈₃Bi --> ⁴₂He + X

Mass number;

210 = 4 + x

x = 206

Atomic number;

83 = 2 + x

x = 81

The element is Thallium. The symbol is Ti.

For the second part;

X --> ⁴₂He + ²³⁴₉₀Th

Mass number;

x = 4 + 234 = 238

Atomic Number;

x = 2 + 90 = 92

The balanced nuclear equation is;

²³⁸₉₂U --> ⁴₂He + ²³⁴₉₀Th

What is a chemical formula, and what does it tell you?

Answers

Explanation:

chemical formula tells you the specific elements included in the compound and the number of atoms of each. The letters in a chemical formula are the symbols for the specific elements. So for example, H means hydrogen.

Explanation:

A chemical formula is a way of presenting information about the chemical properties of atoms that contribute a particular chemical compound or molecule, using chemical elements.

What will be formed when 2,2,3-trimethylcyclohexanone reacts with hydroxylamine?

Answers

Answer:

Following are the solution to this equation:

Explanation:

In the given-question, an attachment file of the choices was missing, which can be attached in the question and its solution can be defined as follows:

In the given question "Option (iii)" is correct, which is defined in the attachment file.

When 2,2,3-trimethylcyclohexanone reacts with hydroxylamine it will produce the 2,2,3-trimethylcyclohexanoxime.

The equilibrium constant K changes with changes in
the temperature.​

Answers

Answer:Equilibrium constants are changed if you change the temperature of the system. Kc or Kp are constant at constant temperature, but they vary as the temperature changes. You can see that as the temperature increases, the value of Kp falls.

Determine whether each phrase describes carboxylic acids or esters.a. Do not form hydrogen bonds amongst themselves and have higher vapor pressureb. Form hydrogen bonds amongst themselves and have lower vapor pressurec. Notable for their pleasant fragrancesd. Their reactions with base are kn. own as saponificationse. Usually have a sour odorf. Their reactions with base are known as neutralizations

Answers

Explanation:

a. Esters

b. Carboxylic acids

c. Esters (ethyl hexanoate smells like pineapple)

d. Carboxylic acids (produces a carboxylic salt)

For the given phrases the following description is better.

a. Esters

b. Carboxylic acids

c. Esters (ethyl hexanoate smells like pineapple)

d. Carboxylic acids (produces a carboxylic salt)

Esters and carboxylic acids:

An ester is a synthetic compound got from a corrosive in which somewhere around one - OH hydroxyl bunch is supplanted by an - O-alkyl (alkoxy) bunch, as in the replacement response of a carboxylic acid and a liquor.

Carboxylic acid is any of a class of natural mixtures in which a carbon (C) particle is clung to an oxygen (O) molecule by a twofold bond and to a hydroxyl bunch (―OH) by a solitary bond.

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Calculate the molality of a solution containing 141.5 g of glycine (NH2CH2COOH) dissolved in 4.456 kg of H2O

Answers

Answer:

0.423 m.

Explanation:

The following data were obtained from the question:

Mass of glycine (NH2CH2COOH) = 141.5 g

Mass of water = 4.456 kg

Molality =.?

Next, we shall determine the number of mole in 141.5 g of glycine (NH2CH2COOH.

This is illustrated below:

Mass of glycine (NH2CH2COOH) = 141.5 g

Molar mass of glycine (NH2CH2COOH) = 14 + (2x1) + 12 + (2x1) + 12 + 16 + 16 + 1 = 75 g/mol

Mole of glycine (NH2CH2COOH) =.?

Mole = mass /Molar mass

Mole of glycine (NH2CH2COOH) = 141.5/75

Mole of glycine (NH2CH2COOH) = 1.887 moles

Finally, we shall determine the molality of the solution as follow:

Molality is simply defined as the mole of solute per kilogram of water. Mathematically it is expressed as:

Molality = mole / mass (kg) of water

With the above formula, we can obtain the molality of the solution as follow:

Mole of glycine (NH2CH2COOH) = 1.887 moles

Mass of water = 4.456 kg

Molality =.?

Molality = mole /mass (kg) of water

Molality =1.887/4.456

Molality = 0.423 m

Therefore, the molality of the solution is 0.423 m

Which of the following are characteristics of ionic
compounds?

Answers

Answer:

Ionic compounds have high melting points.

Ionic compounds are hard and brittle.

Ionic compounds dissociate into ions when dissolved in water.

Solutions of ionic compounds and melted ionic compounds conduct electricity, but solid materials do not.

Explanation:

The second law of thermodynamics predicts that heat flow from a cooler object to a hotter object:________
a) will be spontaneous at high pressure
b) will be spontaneous at low pressure
c) will never be spontaneous at any pressure
d) will always be spontaneous

Answers

Answer:

c) will never be spontaneous at any pressure.

Explanation:

Hello,

In this case, we need to remember that the second law of thermodynamics states that heat flow is transferred from a hot object to a cold object only, never the other way around, therefore, the answer is c) will never be spontaneous at any pressure. This is supported by driving force that in this case is the temperature difference which must be negative for the hot object (it gets eventually cold) and positive for the cold object (it gets eventually hot) until they reach the equilibrium temperature.

Best regards.

Calculate the silver ion concentration in a saturated solution of silver(I) sulfate (K sp = 1.4 × 10 –5). 1.5 × 10–2 M 1.4 × 10–5 M 3.0 × 10–2 M 2.4 × 10–2 M None of the above.

Answers

Answer:

3.0x10⁻²M

Explanation:

Silver sulfate, Ag₂SO₄, has a product constant solubility equilbrium of:

Ag₂SO₄(s) ⇄ 2Ag⁺ + SO₄²⁻

When an excess of silver sulfate is added, some Ag₂SO₄ will react producing Ag⁺ and SO₄²⁻ until reach the equilbrium determined for the formula:

ksp = 1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

Assuming the Ag₂SO₄ that react until reach equilibrium is X, we can replace in Ksp expression:

1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

1.4x10⁻⁵ = [2X]² [X]

1.4x10⁻⁵ = 4X³

3.5x10⁻⁶ = X³

0.015 = X

As [Ag⁺] is 2X:

[Ag⁺] = 0.030 = 3.0x10⁻²M

The answer is:

3.0x10⁻²M


How has the work of chemists affected the environment over the years?

Answers

Answer:

Chemistry is one of the causes for global warming, and in some cases it can even cause certain illnesses.

Answer:

Chemists have both hurt the environment and helped the environment by their actions.

Explanation:

<3

How many moles of gold are equivalent to 1.204 × 1024 atoms? 0.2 0.5 2 5

Answers

Answer:

c

Explanation:

How many moles of gold are equivalent to 1.204 × 1024 atoms?

0.2

0.5

2

5

C) 2 Is the correct answer, I took the test and it was correct.

According to the concept of Avogadro's number, there are 2 moles of gold which are equivalent to 1.204×10²⁴ atoms.

What is Avogadro's number?

Avogadro's number is defined as a proportionality factor which relates number of constituent particles with the amount of substance which is present in the sample.

It has a SI unit of reciprocal mole whose numeric value is expressed in reciprocal mole which is a dimensionless number and is called as Avogadro's constant.It relates the volume of a substance with it's average volume occupied by one of it's particles .

According to the definitions, Avogadro's number depend on determined value of mass of one atom of those elements.It bridges the gap between macroscopic and microscopic world by relating amount of substance with number of particles.

Number of atoms can be calculated using Avogadro's number as follows: mass/molar mass×Avogadro's number.Number of moles=number of atoms/Avogadro's number=1.204×10²⁴ /6.023×10²³=1.999≅2

Thus, there are 2 moles of gold which are equivalent to 1.204×10²⁴ atoms.

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The element europium exists in nature as two isotopes: has a mass of u and has a mass of u. The average atomic mass of europium is u. Calculate the relative abundance of the two europium isotopes.

Answers

Answer:

Problem Details

The element europium exists in nature as two isotopes:  151Eu has a mass of 150.9196 amu, and 153Eu has a mass of 152.9209 amu. The average atomic mass of europium is 151.96 amu. Calculate the relative abundance of the two europium isotopes.

answer:

151Eu = 48%, 153Eu = 52%

conversion of 35 mL to ML

Answers

Answer:

1000ml=1l

35ml. = ?

Explanation:

35×1/1000

0.035litres

An ice cube at 0.00C with a mass of 8.32g is placed Into 55g of water, initially at 25C. If no heat is lost to the surroundings, what is the final temperature of the entire water sample after all the ice is melted (answer must be in 3 sig figs)

Answers

Answer:

The final temperature of the entire water sample after all the ice is melted, is 12,9°C. We should realize that if there is no loss of heat in our system, the sum of lost or gained heat is 0.  It is logical to say that the temperature has decreased because the ice gave the water "heat" and cooled it

Thats all i know

how do elasticity ang flexibility differ?

Answers

Answer:

the object will regain its original form as soon as the deforming force is removed. ... Flexibility means the object is just easily deformed, and will stay that way.

Explanation:

All of the following are examples of allotropes of carbon EXCEPT Choose the one alternative that best completes the statement or answers the question. Choose the one alternative that best completes the statement or answers the question. diamond amorphous carbon quartz graphene all of the above

Answers

Answer:

quartz

Explanation:

The correct option would be quartz.

Allotropy is a phenomenon that describes the natural existence of the same element in different forms with different physical characteristics. Allotropes are therefore different forms of the same element.

Carbon as an element has several allotropes which include diamond, graphite, graphene, amorphous carbon, and fullerenes. Quartz is a crystalline solid that is composed of silicon dioxide and not carbon.

Hence, all the options are carbon allotropes except quartz.

what is ammonium nitrate

Answers

Answer:

Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.

Pentanone was treated with excess sodium cyanide in HCl (aq) followed by hydrogen gas has over Pd. This produced:________
A. 2-amino-1-hexanol
B. 1-amino-2-methylpentan-2-ol
C. 1-cyano-1-pentanol
D. 2-aminomethylpentan-1-ol

Answers

Answer:

B. 1-amino-2-methylpentan-2-ol

Explanation:

In this case, the first step, we have the attack of the nucleophile cyanide ([tex] CN^-[/tex] produced by sodium cyanide to the carbon on the carbonyl group (C=O) producing a negative charge in the oxygen.

Then HCl protonates the molecule to produce a cyanohydrin. This cyanohydrin can be reduced by the action of hydrogen gas ([tex]H_2[/tex]) in the presence of a catalyst ([tex]Pd[/tex]), producing an amino group. With this in mind, the final molecule is: 1-amino-2-methylpentan-2-ol.

See figure 1 to further explanations

I hope it helps!

How many unit cells share an atom that is located at the center of a cube edge of a unit cell?

Answers

Answer:

zero

Explanation:

In a unit cell, an atom that is located at the center of a cube edge is not involved in sharing unit cells because a central atom of a unit cell belongs to the entire cell and only to that unit cell of the lattice.

Hence, the center atom of a unit cell do not share any unit cell and the correct answer is "Zero".

You are a paleontology professor working at a dig site looking for fossils. You come across a deposit that is emitting radiation. Upon further testing you find that the sample is changing from carbon (atomic number 6) into nitrogen (atomic number 7) as radiation is emitted. What type of radiation is it?

Answers

Answer:

β particles

Explanation:

The most common radioactive isotope of carbon is C-13.

The unbalanced nuclear equation is

[tex]\rm _{6}^{13}C \longrightarrow \, ? + \, _{7}^{13N}[/tex]

Let's write the question mark as a nuclear symbol.

[tex]\rm _{6}^{13}C} \longrightarrow \, _{Z}^{A}X+ \, _{7}^{13}N[/tex]

The main point to remember in balancing nuclear equations is that the sums of the superscripts and the subscripts must be the same on each side of the equation.  

Then

13 =  A + 13, so A =  13 - 13 = 0, and

6 = Z + 7, so Z  = 6 - 7 = -1

Then, your nuclear equation becomes

[tex]\rm _{6}^{13}C \longrightarrow \, _{-1}^{0}M + \, _{7}^{13}N[/tex]

The particle with "zero" mass and a charge of -1 is an electron, so the balanced nuclear equation is

[tex]\rm _{6}^{13}C \longrightarrow \, _{-1}^{0}e + \, _{7}^{13}N[/tex]

The radiation consists of β particles (electrons)

Answer:

I think think that the one above me is beta radiation

Explanation:

In the Lewis structure of AB4 where B is more electronegative than A. Both are main group elements where A has 8 valence electrons and each B has 7 valence electrons.

Required:
a. What is the total number of valence electrons?
b. How many lone pairs are in the molecule?

Answers

Answer:

1. 36

2. Two

Explanation:

The Lewis structure shows the valence electrons present in a compound. Usually the valence electrons are shown as dot structures around the symbol of the elements involved in the compound.

For a compound AB4 where B is more electronegative than A and A has 8 electrons in its valence shell, there will be thirty six valence electrons on the outermost shell of the molecule.

There are six electron pair domains present in the molecule, four bond pairs and two lone pairs. The molecule is in a square planar geometry.

Answer: a- 36 valence electrons

b- 14 lone pairs

Explanation:

Valence is equal to A + 4B = 8 + 4(7)

With 4 bonds between A and the 4 B, that is 36 valence minus 8 electrons in those pairs = 28. 28 is 14 lone pairs.

1. Why is it not possible to resolve the compound CH3-NH-CH2-CH3 into a pair of enantiomers?
2. Which one of the following is not affected (or is least affected) by the lone pair of electrons on an amine's nitrogen?
a. solubility in alcohols and in water.
b. hydrogen-bond formation.
c. melting point.
d. dipole moment.
e. basicity.
3. Which of the following compounds is most basic?
a. cyclohexyl amine.
b. p-nitroaniline.
c. 2,6-dimethylaniline.
d. p-methoxyaniline.
d. aniline.

Answers

Answer:

1. In the compound, H3C-NH-CH2-CH3, there are no chiral centers present, chiral centers refer to the configuration in which carbon is attached with four different groups. In the molecules, as there are no chiral centers, therefore the molecule is optically inactive, that is, it will not demonstrate pair of an enantiomer is one of the essential characteristics of optically active compounds is the possession of enantiomeric pairs.  

2. On the nitrogen of aniline, the lone pair of electrons can produce hydrogen bonds, play an essential function in basicity, play an essential role in dipole moment or polarity, and wit the increase in solubility there is an increase in the formation of the hydrogen bond, eventually increasing to boiling point. However, the melting point is not affected. As the melting point is the characteristic of the packing efficacy of a molecule and does not rely upon the anilinic nitrogen's lone pairs.  

3. With the increase in the tendency to donate an electron, basicity increases. However, if the electron is taking part in resonance, the donation will not take place easily, and the compound will be the least basic. Apart from cyclohexyl amine, in all the other given compounds, the lone pair of nitrogen takes part in the process of delocalization or conjugation. Thus, cyclohexyl amine will be most basic as the lone pairs are easily available for donation.  

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