g What is the major problem with using Friedel-Crafts alkylation to mono-alkylate an aromatic ring?

Answers

Answer 1

Answer:

Explanation:

Following are the problems to mono-alkylate the aromatic ring .

1 ) The carbocations formed in the process undergo rearrangement when the number of carbon to be added in the alkylation process is more than two .

2 ) The formed monoalkylated product is more reactive than reactant so reaction does not stop after monoalkylation . Dialkylation and tri alkylation product too are simultaneously formed . This can be controlled by using benzene in excess as reactant . Monohalo benzene or nitrobenzene  are  too weak to undergo Friedel craft reaction because of presence of deactivating

group .


Related Questions

Johnny was finished with his
experiment so he placed all of his
unused chemicals back into their
original containers. What should
Johnny have done instead?
The sono​

Answers

Johnny should have thrown away the unused chemicals because they still could have mixed with the other chemicals and it could cause a reaction.

So our professor didn't go over this but is freshly cut sodium, but rapidly tarnishes on contact with air a physical or chemical property?​

Answers

Answer:

Hey!

After the slight confusion (haha)...

Your answer should be a CHEMICAL CHANGE / PROPERTY

Explanation:

Its CHEMICAL because the sodium has reacted with the air (oxygen in technical terms) which then forms SODIUM OXIDE...the tarnishing of the cut sodium surface it a thin layer of the SODIUM OXIDE...

HOPE THIS HELPED!

Anatomy+ Chemistry List the 8 common ions in the human body and their charge. Identify each as a cation or anion.

Answers

Answer:

Sodium ions - Na⁺ - cation

Potassium ions - K⁺ cation

Chloride ions - Cl⁻ anion

Magnesium ions - Mg²⁺ cation

Calcium ions - Ca²⁺ cation

Phosphate ions - P³⁻ anion

Iron ions - Fe²⁺ cation

Zinc ions - Zn⁺ cation

Explanation:

Following is a list of 8 common but essential ions in the cells and fluids of human bodies:

1. Sodium ions helps in regulation and control the level of body fluids

2. Potassium ions help regulate cellular functions

3. Calcium ions are essential for building and maintaining strength bones and teeth. and have role in blood clotting, muscle contraction, and the transmission of nerve signals to cells.

4. Chloride ions are the main anions found outside body cells. They acts as counterions

5. Magnesium ions  present in the bones

6. Phosphate ions present in body fluids act as the counterions.

7. Iron

8. Zinc

2. Explain what an isotope is and give two important physical properties of isotopes that make them useful in biological research. Define half-life.​

Answers

Answer:

isotope is a variants of a particular chemical element which differ in neutron number, and consequently in nucleon number.All isotopes of a given element have the same number of protons but different number of neutrons in each atom.

The 2 important physical properties of isotope is

1.Melting Points2.Boiling Points

is another way in which nitrogen gets fixed in the soil​

Answers

Answer:

through Rhizobium bacteria

Some people argue that a policy of putting out wildfires is having a negative long-term effect on the number and strength of wildfires. Suggest why this could be the case.

Answers

Answer:

The reason for this is that putting out the fires only postpones the fire outbreak to a later date, and there is the fear of the fire outbreak being more sever when it actually comes.

When wildfires burn, they clean up the forest off dead trees and falling logs. Also dried leaves and twigs and unnecessarily dense vegetation is cleared up by the fire. These materials are the main fuel of these wildfires. Putting out these fires, especially those that start naturally means that these fuel that should be cleaned up are allowed to accumulate so that when the fire actually happens, it does so with an unnatural intensity. Also, when fire burns, the ashes that are left act as nutrition for the forest, and the forest is allowed to regrow; reborn from the ashes. The only cases that might need human intervention is when the fire is human caused or due to human activities. Natural causes of fire can be due to a very high temperature, lightning striking a tree, etc.

When dipentyl ether is treated with HI, what type of reaction occurs? both SN1 and SN2 SN2 E1 SN1 E2

Answers

Answer:

SN2

Explanation:

The first step of ether cleavage is the protonation of the ether since ROH is a better leaving group than RO-.

The second step of the reaction may proceed by either SN1 or SN2 mechanism depending on the structure of the ether. Methyl and primary ethers react with HI by SN2 mechanism while tertiary ethers react with HI by SN1 mechanism. Secondary ethers react with HI by a mixture of both mechanisms.

Dipentyl ether is a primary ether hence when treated with HI, the reaction with HI proceeds by SN2 mechanism as explained above.

Show the difference in the reactivity of Na,Ca,Mg,Al,Fe,Cu with H2O

Answers

Answer:

Explanation:

Na react with H2O to form NAOH

2 Na+2H2O....................2NAOH + H2

Ca react with water and form calcium hydroxide

Ca + 2H2O........................Ca(OH)2

Mg react with water and form Magnesium hydroxide

Mg +2H2O .........................Mg(OH)2 however this coating of mg(oh)2 prevent it from further reaction

 Fe react with water and form ferric hydride

3Fe +H2O.......................2 FeH +FeO

copper do not react with water

A student determines the volume of a cube to be 4.6 cm?
What is the percent error if the correct volume of the crystal is
4.3 cm??

Answers

Answer:

6.98%

Explanation:

% error= |experimental value - actual value|/actual value × 100

Experimental value= 4.6 cm

Actual value= 4.3 cm

% error = |4.6-4.3|/4.3 × 100

% error = 6.98%

Answer: 7%

Explanation:

g The large negative free energy of hydrolysis of Phosphoenolpyruvate is largely due to _______________ of the enol pyruvate.

Answers

Answer:

hello your question lacks some parts below are the missing option

A. hydrophobic interaction  

B.  nucleophilic attack  

C.  tautomerization  

D.  resonance

answer : Tautomerization ( C )

Explanation:

The large negative free energy of hydrolysis of Phosphoenolpyruvate is largely due to tautomerization of the enol pyruvate. tautomerism of enol takes place by transferring proton from in an intramolecular way.

one of the most common tautomerism is keto-enol which makes uses of either an acid or base as a catalyst

At STP how many liters of NH3 can be produced from the reaction of 2.00 mol of N2 with 2.00 mol of H2

Answers

Answer:

29.9L of NH₃ are produced

Explanation:

The reaction of H2 with N2 to produce NH3 is:

3 H2 + N2 → 2 NH3

For a complete reaction of 2.00 moles of H2 there are required:

2.00 moles H2 * (1 mole N2 / 3.00 moles H2) = 0.667 moles N2

The limiting reactant is hydrogen.

The volume of hydrogen using PV = nRT is (STP: 273.15K; 1atm):

V = nRT / P

V = 2.00mol * 0.082atmL/molK*273.15K / 1atm

V = 44.8L

As we know for the reaction, 3 moles of hydrogen produce 2 moles of NH3.

The moles of H2 produced are:

2mol H2* (2mol NH3 / 3mol H2) = 1.33 moles NH3 are produced

Under pressure and temperature constant (STP) you can apply The Avogadro's law that states:

V₁ / n₁ = V₂ / n₂

Where V is volume and n moles of 1, the first gas and 2, the second gas.

V₁ / n₁ = V₂ / n₂

44.8L / 2.00mol = V₂ / 1.33 moles

V₂ =

29.9L of NH₃ are produced

A sample of mass 6.814 grams is added to another sample weighing 0.08753 grams.
The subsequent mixture is then divided into exactly 3 equal parts. One of those parts has the yield multiplied by 7.6335 times; what is the final mass?

Answers

Answer:

17.5609g

Explanation:

According to the question, a sample of mass 6.814 grams is added to another sample weighing 0.08753 grams. That is weight of sample 1 + weight of sample 2;

6.814 + 0.08753 = 6.90153grams

Next, the subsequent mixture is then divided into exactly 3 equal parts i.e. 6.90153grams divided by 3

= 6.90153/3

= 2.30051grams.

One of the equal parts is 2.30051grams, which is then multiplied by 7.6335 times I.e. 2.30051 × 7.6335 = 17.5609grams

Therefore, the final mass is 17.5609grams

For the reaction2 C4H10 (g) + 13 O2 (g) → 8 CO2 (g) + 10 H2O (g)ΔH° is -125 kJ/mol and ΔS° is +253 J/K ∙ mol. This reaction is ____.A. spontaneous only at low temperatureB. spontaneous only at high temperatureC. spontaneous at all temperaturesD. nonspontaneous at all temperaturesE. unable to determine without more information

Answers

Answer:

C. spontaneous at all temperatures

Explanation:

The spontaneity of  reaction is determined by the sign of the  gibbs free energy.

A negative sign denotes that the reaction is spontaneous, positive sign means the reaction is not spontaneous.

From the question;

ΔS° = +253 J/K

ΔH° = -125 kJ/mol

ΔG = ΔH°  - TΔS°

From the data given, the condition in which we can obtain a negative value of G, is at any value of T.

For any value of T, G would always be a negative value.

This means the correct option is option C.

Barry Bonds hit 62 homeruns in one season. Given there are 4 bases and each base is
90 feet apart, how many kilometers did he run?

Answers

Answer:

6.803136 KM

Explanation:

I multiplied 90 by 4 to get 360 feet, or the distance of each homerun. 360 times 62 gave me 22,320.

22,320 converted to KM is 6.803136 Km

you may want to round it up, but I would use the precise answer.

Barry Bonds is a former American baseball player that played in various leagues and seasons. In 62 home runs and 4 bases, he ran around 6.803136 Kilometers.

What is the unitary method?

The unitary method is the mathematical technique to estimate the values of units from a single value by multiplication and division. It uses the cross multiplication application to find the other values.

Given,

Number of bases = 4

Distance between each base = 90 feet apart

Number of home runs in one season = 62

By using the cross multiplication and unitary method the distance can be calculated as:

1 base = 90 feet apart

4 base = X feet

Solving for X as:

X = 90 × 4

= 360 feet

If one homerun = 360 feet

Then, 62 homerun = X feet

X is calculated as:

X = 360 × 62

= 22,320 feet

The units from feet to km are converted as:

1 feet = 0.0003048 km

Then, 22,320 feet = 6.803136 km

Therefore, Barry Bonds ran 6.803136 km.

Learn more about the unitary method, here:

https://brainly.com/question/22056199

#SPJ2

Which of the following is the best example of one
way carbon progresses through the carbon
cycle?
A. Humans take in carbon dioxide and give off
carbon dioxide through respiration.
B. Marine organisms transform carbohydrates from
the atmosphere into carbon gas.
C. Fungi take in carbohydrates as nutrients and
release oxygen into the atmosphere.
D. Plants take in carbon dioxide and turn it into
carbohydrates during photosynthesis.

Answers

Answer:

D. Plants take in carbon dioxide and turn it into

carbohydrates during photosynthesis.

Explanation:

Why is Hydrogen Peroxide lethal to drink if it is only composed of one more molecule of oxygen than water?

Answers

Answer: Hydrogen peroxide is a clear, odorless, and colorless liquid consisting of hydrogen and oxygen. It’s available in dilutions ranging from 3–90%, some of which are sometimes used as an alternative health remedy.

Advocates suggest that drinking a few drops of hydrogen peroxide diluted in water may help treat a range of illnesses, including diabetes and even some forms of cancer.

However, medical professionals warn against the dangers of this practice.

This article takes a look at the latest evidence to determine whether the benefits of drinking hydrogen peroxide outweigh its potential risks.

Explanation:

If you have ingested small amounts of 3% hydrogen peroxide, call your local poison control helpline for assistance. If you have swallowed larger amounts or higher concentrations, seek immediate medical assistance from an emergency room.

The bottom line

Hydrogen peroxide is touted as an alternative health remedy for a range of health conditions.

However, there’s no scientific evidence that drinking it yields any benefits. Plus, doing so is linked to dangerous side effects, including breathing problems, severe gut damage, and in some cases, death.

For these reasons, drinking any concentration or amount of hydrogen peroxide is not recommended.

A pool is 59.8 m long and 26.6 m wide. If the average depth of water is 3.70 ft, what is the mass (in kg) of water in the pool? Enter your answer in scientific notation. The density of water is 1.0 g/mL.

Answers

Given :

Length , l = 59.8 m.

Breadth , b  = 26.6 m.

Depth , d = 3.7 ft .

Density of water , [tex]\rho=1\ g/ml=1000\ kg/m^3[/tex] .

To Find :

Mass of water in pool .

Solution :

First we will covert depth into m from ft .

[tex]1\ ft =0.3\ m[/tex]

For ,

[tex]3.7\ ft=0.3\times 3.7\ m\\3.7\ ft=1.11\ m[/tex]

So , volume of pool is :

[tex]V=59.8\times 26.6\times 1.11\ m^3\\\\V=1765.65\ m^3[/tex]

We know , density is given by :

[tex]\rho=\dfrac{m}{V}[/tex]

So , [tex]m=\rho V[/tex]

Putting given values in above equation :

[tex]m=1000\times 1765.65\ kg\\\\m=1.77\times 10^6\ kg[/tex]

Hence , this is the required solution.

The value of mass in kg is [tex]1.76\times10^{6} \ kg[/tex].

Length , l = 59.8 m.

Breadth , b  = 26.6 m.

Depth , d = 3.7 ft  

Covert depth into m from ft.[tex]1ft=0.3m[/tex]

[tex]3.7ft=0.3\times3.7\\=1.11m[/tex]

Volume of pool is as follows:-

[tex]Volume=59.8\times26.6\times1.11\\=1765.65\ m^{3}\\=1765.65\times1000\ L=1765650 L[/tex]

Density:-

It is defined as mass per unit volume.

[tex]Density=\frac{Mass}{Volume}[/tex]

Substitute 1.0 kg/L for density and 1765650 L for volume for the calculation of mass as follows:-

[tex]m=1kg/L \times1765650\ L\\\\=1.76\times10^{6} \ kg[/tex]

To know more about:-

brainly.com/question/25038476  

 

The quantity, 1,385 mg is equivalent to in scientific notation

Answers

Answer:

The answer is 1385 x10∧ -3

Explanation:

Scientific notation is a quick way to represent a number using notation in exponential form or powers of base ten.

This notation allows us to express too large or small numbers easily.

For example:

500 is written as 5x10∧2; Where the power 2 represents the number of 0's that follow 5.

0.0093 is written as 9.3x10∧-3; Where the power -3 represents the number of times the comma was moved to the right.

A block of aluminum occupies a volume of 0.015 L and has a mass of 40.5 g. What is its density

Answers

Answer:

Density = 2700 g/L

Explanation:

Density of a substance can be found by using the formula

[tex]Density = \frac{mass}{volume} [/tex]

From the question

volume = 0.015 L

mass = 40.5 g

Substitute the values into the above formula and solve for the Density

That's

[tex]Density = \frac{40.5}{0.015} [/tex]

We have the final answer as

Density = 2700 g/L

Hope this helps you

A 1.000 g sample of nitrogen combined with a 0.0720 g sample of hydrogen to form N2H2. What compound is formed if 1.000 g of nitrogen combines with 0.2160 g of hydrogen?
N2H6 NH3 NH4+ N4H4

Answers

Answer:

N₂H₆

Explanation:

A 1.000 g sample of nitrogen combined with a 0.0720 g sample of hydrogen to form N₂H₂ .

1.000 g of nitrogen combines with 0.2160 g of hydrogen in the next compound .

In this compound the component of nitrogen remains the same but the component of hydrogen becomes .2160 / .0720 = 3 times .

Hence component of hydrogen in the new compound will change from

H2 to H6 .

Hence the chemical formula of new compound will be

N₂H₆ .

Which aqueous solution has the highest boiling point?a. 0.20 M NaClb. 0.10 M CaCl2c. 0.1 M Ga2(SO4)3d. 0.2 M C6H12O6

Answers

Answer:

c. 0.1 M Ga₂(SO₄)₃

Explanation:

The boiling point increasing of a solvent due the addition of a solute follows the formula:

ΔT = K*m*i

Where K is boiling point increasing constant (Depends of the solute), m is molality = molarity when solvent is water, and i is Van't Hoff factor.

That means the option with the higher m*i will be the solution with the highest boiling point:

a. NaCl has i = 2 (NaCl dissociates in Na⁺ and Cl⁻ ions).

m* i = 0.20*2 = 0.4

b. CaCl₂; i = 3. 3 ions.

m*i= 0.10M * 3 = 0.3

c. Ga₂(SO₄)₃ dissolves in 5 ions. i = 5

m*i = 0.10M*55 = 0.5

d. C₆H₁₂O₆ has i = 1:

m*i = 0.2M*1 = 0.2

The solution with highest boiling point is:

c. 0.1 M Ga₂(SO₄)₃

A student filled the graduated cylinder up to the 9.6 mL mark, but incorrectly recorded the volume as 10.0 mL. How would this affect the density? Explain.

Answers

Answer:

0.4 ml will be affect the density.

Explanation:

Given that,

A student filled the graduated cylinder up to the 9.6 mL mark.

Recorded volume = 10.0 mL

We know that,

Density :

Density is equal to the mass divided by volume.

In mathematically,

[tex]\rho=\dfrac{m}{V}[/tex]

Where, m = mass

V = volume

Affect the density :

Affect the density is equal to the change in volume.

We need to calculate the affect the density

Using formula of affect the density

[tex]\rho=V'-V[/tex]

Put the value into the formula

[tex]\rho=10.0-9.6[/tex]

[tex]\rho=0.4\ ml[/tex]

Hence, 0.4 ml will be affect the density.

What volume (mL) of a 0.3428 M HCl(aq) solution is required to completely neutralize 23.55 mL of a 0.2350 M Ba(OH)2(aq) solution

Answers

Answer:

32.29 mL

Explanation:

We'll begin by writing the balanced equation for the reaction. This is given below:

2HCl(aq)+ Ba(OH)2(aq) —> BaCl2(aq) + 2H2O

From the balanced equation above, the following were obtained:

Mole ratio of the acid (nA) = 2

Mole ratio of the base (nB) = 1

Next, data were obtained from. This include the following:

Molarity of acid, HCl (Ma) = 0.3428 M

Volume of acid, HCl (Va) =.?

Molarity of base, Ba(OH)2 (Mb) = 0.2350 M

Volume of base, Ba(OH)2 (Vb) = 23.55 mL

Finally, we shall determine the volume of the acid, HCl required for the reaction as follow:

MaVa /MbVb = nA/nB

0.3428 × Va / 0.2350 × 23.55 = 2/1

Cross multiply

0.3428 × Va = 0.2350 × 23.55 × 2

Divide both side by 0.3428

Va = (0.2350 × 23.55 × 2) / 0.3428

Va = 32.29 mL

Therefore, the volume of acid, HCl required for the reaction is 32.29 mL

Which of the following correctly describes a mixture? (4 points) a The particles are chemically bonded together, and they retain their individual physical and chemical properties. b The particles are not chemically bonded, and they can only combine in certain set ratios. c The particles do not retain their individual chemical properties, and they can only be separated by chemical means. d The particles have no set ratio for how to combine, and they can be separated by physical means.

Answers

Answer:

the answer is B the particles are not chemically bonded, they can only be combined in a certain set ratios

Explanation:

How does the amount of sunlight affect the number of eggs laid by a chicken?

Answers

Explanation:

The amount of daylight hours affects a chicken's reproductive cycle. Hens will begin laying when the amount of daylight reaches 14 hours per day during early spring. Maximum egg laying will occur when the day length reaches 16 hours per day

Which one of these salts will form a neutral solution on dissolving in water? KNO2 NaCN NaCl NH4NO3 FeCl3

Answers

Answer:

NaCl

Explanation:

Salts whose ion cannot hydrolyse form neutral solutions; not having alkaline nor acidic properties.

All the other salts would dissociate to form solution or strong acid ad weak bases or vice versa, which then determines their alkalinity or acidity: all except sodium chloride, NaCl.

I hope this explanation was helpful and clear.

John had seen people sprinkle salt on ice in the winter. The salt appeared to melt the ice. He decided to sprinkle salt on a larger block of ice. Then he added food coloring so he better could see the results. How did creativity help John in this experiment? A. It helped him use materials in a new way to help him gather data. B. It helped him reason through the results of his experiments. C. It helped him follow the steps of the procedure precisely. D. It helped him remember something from his past.

Answers

The correct answer is A.  It helped him use materials in a new way to help him gather data.

Explanation:

The use of food coloring in this experiment makes it easier to observe how salt affects ice and if this helps ice to melt. This implies by adding food coloring John can better observe the phenomenon he is studying and gather precisely data about this phenomenon, which would also help him to draw accurate conclusions. In this context, the use of food coloring shows creativity because he is using this material as an alternative way and this use would help him in the stage of gathering data (option A), which is the stage that follows after implementing experiments.

Answer:

A

Explanation:

Just got it right on my quiz!! I hope this helps! <3

Select the single best answer. When 2-heptyne was treated with aqueous sulfuric acid containing mercury(II) sulfate, two products, each having the molecular formula C7H14O, were obtained in approximately equal amounts. What are these two compounds

Answers

Answer:

heptan-3-one and heptan-2-one

Explanation:

In this case, we must remember what the products of this reaction are. An alkyne in the presence of HgSO4 and H2SO4 will produce a ketone. But, in the triple bond, we have two carbons, therefore the carbonyl group can be placed on any of the carbons of the triple bond.

In figure 1 we have the general reaction. At C = O it can be added to the carbon on the left (red carbon) or the carbon on the right (blue carbon).

Following this logic, for 2-heptyne the carbonyl group can be added to carbon 2 producing heptan-2-one. Similarly, the carbonyl group can be added to carbon 3 producing heptan-3-one. (See figure 2)

g The chemicals above are dissolved in water to make a solution. Which ones will conduct electricity

Answers

Answer:

This question is incomplete

Explanation:

Although, the question above is incomplete, however the correct option can be deduced from the explanation below.

Compounds/chemicals that dissolve in water to conduct electricity are Ionic/electrovalent compounds. Ionic compounds/salts are compounds that are held together by ionic/electrovalent bond. These compounds dissociate in water to form ions; the dissociated ions formed are the carriers of electric charges hence enabling the salt solution conduct electricity. Examples of these electrovalent/ionic compounds include NaCl, CaCl₂, CsF and MgO.

NOTE: Identify the ionic/electrovalent compounds in the options (from the completed question) to get your answer.

Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction entropy of the following chemical reaction:
S8 + 24F2------ 8S + F6
Round your answer to zero decimal places.J/K

Answers

Answer:

[tex]\Delta _rS\°=-2965.27J/K[/tex]

Explanation:

Hello,

In this case, for the considered reaction, the standard reaction entropy is computed considering the standard entropy of each product and reactant and their stoichiometric coefficients as shown below:

[tex]\Delta _rS\°=8*S\°_{SF_6}-S\°_{S_8}-24*S\°_{F_2}[/tex]

Thus, considering the ALEKS Data tab, we obtain:

[tex]\Delta _rS\°=8*(291.52J/K)-(430.23J/K)-24*(202.8J/K)\\\\\Delta _rS\°=-2965.27J/K[/tex]

Regards.

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