Half-cells were made from a nickel rod dipping in nickel sulfate solution and a copper rod dipping in copper sulfate solution. The cells were combined to construct a voltaic electrochemical cell. Sketch the cell and label anode and cathode with charges, electrode material and electrolyte solutions, half-reactions and overall reaction, give direction of electron flow and movement of ions.

Answer:

ethyl 3-ethoxy-3-hydroxy-2-isopropyl-5-methyl hexanoate

Explanation:

In this case, we have a very strong base (sodium ethoxide). Therefore, this compound will remove a hydrogen from ethyl 3-methyl butanoate generating a carbanion.

This carbanion, can attack another ethyl 3-methyl butanoate molecule on the carbonyl group generating a new C-C bond and producing a negative charge in the oxygen.

Then the ethanol can protonate the molecule generating an "OH" group and the ethoxide.

See figure 1

I hope it helps!

Answer:

HClO 7.54

Explanation:

Hypochlorous acid (HClO) is a weakest acid because the pKa value of Hypochlorous acid is very high among the options given in the activity. pKa is a method which is used in order to identify the strength of an acid. The higher the value of pKa of a liquid, lower the strength of an acid while lower the value of pKa of chemical, higher the strength of an acid. In the options, HClO2  is a strong acid due to high lower pKa value.

Answer:

See explanation

Explanation:

First voltaic cell;

Zn(s)|Zn^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Zinc

Cathode;

Copper

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Zn(s) + Cu^2+(aq) -----> Zn^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.76) =1.1 V

Second voltaic cell;

Zn(s)|Zn^2+(aq)||Fe^2+(aq)|Fe(s)

Anode;

Zinc

Cathode;

Iron

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Fe^2+(aq) +2e -----> Fe(s)

Overall; Zn(s) + Fe^2+(aq) -----> Zn^2+(aq) + Fe(s)

E°cell = (-0.44) -(-0.76) = 0.32 V

Third voltaic cell;

Fe(s)|Fe^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Iron

Cathode;

Copper

Oxidation half equation;

Fe(s)------> Fe^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Fe(s) + Cu^2+(aq) -----> Fe^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.44) = 0.78 V

Fourth voltaic cell

Cu(s)|Cu^2+(aq)||I2(aq)|C(s)|I^-(aq)

Anode;

Copper

Cathode;

Graphite rod

Oxidation half equation;

Cu(s)------> Cu^2+(aq) + 2e

Reduction half equation;

I2(aq) +2e -----> 2I^-(aq)

Overall; Cu(s) + I2(aq) -----> Cu^2+(aq) + 2I^-(aq)

E°cell = 0.54 -0.34 = 0.20 V

Answer:

A double bond is formed when two pairs of electrons are shared between the two participating atoms. It is represented by two dashes (=). It is represented by two dashes (=). Double covalent bonds are much stronger than a single bond, but they are less stable

Explanation:

Answer:

A process that involves rearrangement

Explanation:

A chemical reaction is the process that involves rearrangement of the molecular or ironic structure of a substance, as a distinct from a change in physical form or a nuclear reaction.

Answer:

Explanation:

Chemistry

The chemical reaction H2(g) + ½ O2(g) → H2O(l) describes the formation of water from its elements.

The reaction between iron and sulfur to form iron(II) sulfide is another chemical reaction, represented by the chemical equation:

8 Fe + S8 → 8 FeS

Answer:

The answer it's A. transesterification

Answer:

anilinium ion > ammonium ion > amide > aniline > secondary amine

Explanation:

Acidity of amine derivatives can derived from their pKa values.

The rule of thumb for acidity with relation to pKa values is that:

As the pKa decreases the acid strength increases and the conjugate base decreases. Similarly, as the pKa increases, the acid strength decreases and the conjugate base increase.

Hence the stronger the acid , the  lower pKa value  and the weaker the acid , the stronger the pKa value.

So the pKa value for anilinium ion = 4.6

ammonium ion = 9.4

Amide = 15

Similarly, for aniline and secondary amine, in order to determine the derivative with the higher acidity, we will consider the electron withdrawing substituent group.

The more difficult the electron are being withdraw from the electron withdrawing substituent , the more acidic the compound.

In aniline , the stabilized benzene ring attached to NH₂ makes it a less electron withdrawing group compared to the straight chains structure found in secondary amine where electron are easily withdraw by nucleophilic substitution reactions.

Thus, from highest acidity (lowest pKa value) to lowest acidity (highest pKa value).

the amine derivatives ranking is as follows:

anilinium ion > ammonium ion > amide > aniline > secondary amine

Mg gained mass because it went from being a single element (on the reactant side) to being a molecule (on the product side).

Mg element is gaining mass. Hence, option A is correct.

A chemical reaction is a representation of symbols of the elements to indicate the number of substances and moles of reactant and product.

Mg gained mass because it went from being a single element (on the reactant side) to being a molecule (on the product side).

Hence, option A is correct.

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Answer:

[tex]pH=2.28[/tex]

Explanation:

Hello,

In this case, for the acid dissociation of formic acid (HCOOH) we have:

[tex]HCOOH(aq)\rightarrow H^+(aq)+HCOO^-(aq)[/tex]

Whose equilibrium expression is:

[tex]Ka=\frac{[H^+][HCOO^-]}{[HCOOH]}[/tex]

That in terms of the reaction extent is:

[tex]1.8x10^{-4}=\frac{x*x}{0.16-x}[/tex]

Thus, solving for [tex]x[/tex] which is also equal to the concentration of hydrogen ions we obtain:

[tex]x=0.00528M[/tex]

[tex][H^+]=0.00528M[/tex]

Then, as the pH is computed as:

[tex]pH=-log([H^+])[/tex]

The pH turns out:

[tex]pH=-log(0.00528M)\\\\pH=2.28[/tex]

Regards.

Answer:

A) dietary fiber isn't used by the body.

Explanation:

The food we eat contains certain nutritional contents that provides energy, measured in calories (CAL) to the body. A procedure called BOMB CALORIMETRY can be used to determine the energy contents of these foods. The energy-supplying macromolecules contained in food substances we eat are carbohydrate, protein, fats etc.

Bomb calorimetry uses the method of burning the food substance in a device called bomb calorimeter, and measure the caloric content of the burnt food. Bomb calorimetry measures all the present calories in a food substance, which can include dietary fibers. Due to this reason, it is considered a poor choice in determining the number of nutritional calories in a food substance.

Dietary fibers are indigestible carbohydrates that cannot be broken down and used by the body. They pass along the alimentary canal until they are egested. Hence, they are no source of nutrients to the body. Since bomb calorimetry measures all calories including dietary fibers, it is said to overestimate the caloric content of food substances.

Answer:

ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 )

Explanation:

Isomers are compounds that have the same molecular formula but different structural formulas. Hence any pair of compounds that can be represented by exactly the same molecular formula are isomers of each other.

If we look at the pair of compounds; ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 ), one compound has molecular formula, C2H7ON while the other has a molecular formula, C2H5ON, hence they are not isomers of each other.

Answer:

Diferentes tipos de arcilla

ARCILLA DE LADRILLOS. Contiene muchas impurezas. ...

ARCILLA DE ALFARERO. Llamada también barro rojo y utilizada en alfarería y para modelar. ...

ARCILLA DE GRES. Es una arcilla con gran contenido de feldespato. ...

ARCILLAS “BALL CLAY” O DE BOLA. ...

CAOLIN. ...

ARCILLA REFRACTARIA. ...

BENTONITA.

Explanation:

Answer:

Coil method and the slab method.

Explanation:

A general exponential expression is something like:

A^n

This means that we need to multiply the number A by itself n times.

Using that we will get (-2)^6 = 64

With that definition, we can rewrite:

(-2)^6 = (-2)*(-2)*(-2)*(-2)*(-2)*(-2)

So we just need to solve the above expression.

Also, remember the rule of signs:

(-)*(-) = (+)

We will get:

(-2)*(-2)*(-2)*(-2)*(-2)*(-2) =  [(-2)*(-2)]*[(-2)*(-2)]*[(-2)*(-2)]

                                        =  4*4*4 = 16*4 = 64

Then we got:

(-2)^6 = 64

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Answer:

550mL of HCOOH 0.1M and 450mL of HCOONa 0.1M

Explanation:

It is possible to find the pH of a buffer by using H-H equation:

pH = pKa + log [A⁻]/[HA]

For the formic buffer (HCOOH/HCOONa):

pH = 3.74 + log [HCOONa]/[HCOOH]

As you need a buffer of pH 3.65:

pH = 3.74 + log [HCOONa]/[HCOOH]

3.65 = 3.74 + log [HCOONa]/[HCOOH]

Where  [HCOONa]/[HCOOH] can be taken as the moles of each specie.

As molarity of both solutions is 0.10M (0.10mol / L) and you need 1L of solution, total moles of the buffer are:

Replacing (2) in (1):

0.81283 = 0.10 - [HCOOH]  /[HCOOH]

0.81283[HCOOH] = 0.10 - [HCOOH]

1.81283[HCOOH] = 0.10

And moles of HCOONa are:

[HCOONa] = 0.1 mol - 0.055mol =

As concentration of the solutions is 0.1M, the volume you need to add of both solutions is:

HCOOH = 0.055 mol ₓ (1L / 0.1mol) = 0.55L = 550mL of HCOOH 0.1M

HCOONa = 0.045 mol ₓ (1L / 0.1mol) = 0.45L = 450mL of HCOONa 0.1M

The number should be considered like 550mL of HCOOH 0.1M and 450mL of HCOONa 0.1M.

Here we used the H-H equation:

pH = pKa + log [A⁻]/[HA]

Now

For the formic buffer (HCOOH/HCOONa):

So,

pH = 3.74 + log [HCOONa]/[HCOOH]

Now

need a buffer of pH 3.65:

So,

pH = 3.74 + log [HCOONa]/[HCOOH]

3.65 = 3.74 + log [HCOONa]/[HCOOH]

0.81283 = [HCOONa]/[HCOOH] (1)

here  [HCOONa]/[HCOOH] can be considered as the moles of each specie.

Now the total moles should be

0.10 moles = [HCOONa] + [HCOOH] (2)

Now

0.81283 = 0.10 - [HCOOH]  /[HCOOH]

0.81283[HCOOH] = 0.10 - [HCOOH]

1.81283[HCOOH] = 0.10

[HCOOH] = 0.055 moles

And moles of HCOONa should be

[HCOONa] = 0.1 mol - 0.055mol =

[HCOONa] = 0.045 moles

Now

HCOOH = 0.055 mol ₓ (1L / 0.1mol) = 0.55L = 550mL of HCOOH 0.1M

HCOONa = 0.045 mol ₓ (1L / 0.1mol) = 0.45L = 450mL of HCOONa 0.1M

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Answer:

since mass percent is based on the proportions of elements in a compound, the mass of a sample does not matter

The mass percent or percentage by mass of a chemical compound is a constant.

Mass percent can be defined as percentage by mass and it is the concentration of a given amount (quantity) of element in a chemical compound or a component of a mixture.

The mass percent or percentage by mass of a chemical compound is a constant, regardless of the amount of substance that is present. Thus, all chemical compound always have a constant composition because mass percent is typically based on the proportions of the elements contained in a chemical compound.

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Answer:

Due to the resonance structures

Explanation:

In the question:

"Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus"

We have to take into account the structure of the amino acid arginine. In which, we have the amino and the carboxylic groups in the right and the guanidine group in the left.

In this group, we have a central carbon with three nitrogen atoms around and a double bond with the nitrogen on the top. This nitrogen on the top will accept the proton because the structure produced will have a positive charge on this nitrogen. Then, the double bond with the carbon can be delocalized into the nitrogen producing a positive charge in the carbon.

In this structure (the carbocation), we can have several resonance structures. In the blue option, we can produce a double bond with the nitrogen on the right. In the purple option, we can produce a double bond with the nitrogen on the left.

In conclusion, if the nitrogen in the top on the guanidine group accepts an hydrogen atom and we will have several resonance structures that can stabilize the molecule. Due to this, the nitrogen in the top its the best option to accept hydrogens.

See figure 1

I hope it helps!

Answer:

That involve the complete transfer of an electron from one atom of an element to another

Answer:

12-crown-4

Explanation:

We must recall that any structural moiety in organic chemistry having the R-O-R unit is an ether. If the oxygen form a ring in which they are sandwiched in between carbon atoms, the compound is known as a crown ether. The name emanates from the close resemblance of the compound to an actual crown.

If we want to name the crown ether, we first count the number of carbon atoms present and the number of oxygen atoms present. The correct name is now, total number of carbon + oxygen atoms -crown- number of oxygen atoms, in this case; 12-crown-4, hence the answer.

Answer:

12-crown-4

Explanation:

Answer:

7.2 moles of titanium weigh 344.7 grams.

Explanation:

Molar mass of titanium = 47.88 g

[tex]1 \: mole \: of \: titanium = 47.88 \: grams \\ 7.2 \: moles \: of \: titanium = g[/tex]

solve for g

[tex]g = ( \frac{7.2 \times 47.88}{1} ) \\ g = 344.7 \: grams[/tex]

Answer:

[tex]\boxed {\boxed {\sf 344.7 \ g \ Ti}}[/tex]

Explanation:

We are asked to find the mass of 7.2 moles of titanium.

To convert from moles to grams, we use the molar mass. This value is the mass of 1 mole of a substance. They are equivalent to the atomic masses found on the Periodic Table, but the units are grams per moles instead of atomic mass units.

Look up titanium's molar mass on the Periodic Table.

Convert moles to grams using dimensional analysis. First, set up a ratio using the molar mass.

[tex]\frac {47.87 \ g \ Ti}{1 \ mol \ Ti}[/tex]

We are converting 7.2 moles to grams, so we multiply the ratio by this value.

[tex]7.2 \ mol \ Ti *\frac {47.87 \ g \ Ti}{1 \ mol \ Ti}[/tex]

The units of moles of titanium cancel.

[tex]7.2 *\frac {47.87 \ g \ Ti}{1 }[/tex]

The denominator of 1 can be ignored (a number over 1 is just the number).

[tex]7.2 *47.87 \ g \ Ti}[/tex]

[tex]344.664 \ g \ Ti[/tex]

We are asked to round to the nearest tenth. The 6 in the hundredth place tells us to round the 6 in the tenth place up to a 7.

[tex]344.7 \ g \ Ti[/tex]

There are approximately 344.7 grams of titanium in 7.2 moles of titanium.

Answer:

Volume : 1.25 L

Explanation:

We are given here that the volume ( V[tex]_1[/tex] ) = 1.50 Liters, the initial moles ( held at 25 °C ) = 3.00 mol, and the final moles ( n[tex]_2[/tex] ) = 3.00 - 0.5 = 2.5 mol. The final mol is calculated given that 0.50 mol of gas are released from the prior 3.00 moles of gas.

Volume ( V[tex]_1[/tex] ) = 1.50 L,

Initial moles ( n[tex]_1[/tex] ) = 3.00 mol,

Final Volume ( n[tex]_2[/tex] ) = 3.00 - 0.5 = 2.5 mol

Applying the combined gas law, we can calculate the final volume ( V[tex]_2[/tex] ).

P[tex]_1[/tex]V[tex]_1[/tex] / n[tex]_1[/tex]T[tex]_1[/tex] = P[tex]_2[/tex]V[tex]_2[/tex] / n[tex]_2[/tex]T[tex]_2[/tex] - we know that the pressure and temperature are constant, and therefore we can apply the following formula,

V[tex]_1[/tex] / n[tex]_1[/tex] = V[tex]_2[/tex] / n[tex]_2[/tex] - isolate V[tex]_2[/tex],

V[tex]_2[/tex] = V[tex]_1[/tex] n[tex]_2[/tex] / n[tex]_1[/tex] = 1.50 L [tex]*[/tex] 2.5 mol / 3.00 mol = ( 1.5 [tex]*[/tex] 2.5 / 3 ) L = 1.25 L

The volume of the balloon will be 1.25 L.

Answer:

Electrical current drives nonspontaneous reactions in electrolytic cells.

Explanation:

Electrochemical cells are cells that produce electrical energy from chemical energy.

There are two types of electrochemical cells; voltaic cells and electrolytic cells.

A voltaic cell is an electrochemical cell in which electrical energy is produced from spontaneous chemical process while an electrolytic cell is an electrochemical cell where electrical energy is produced from nonspontaneous chemical processes. Current is needed to drive these nonspontaneous chemical processes in an electrolytic cell.

Answer:

electrolytic cells generate electricity through a non-spontaneous reaction while voltaic cells absorb electricity to drive a spontaneous reaction.

Explanation:

Answer via Educere/ Founder's Education

Answer:

Heat of vaporization refers to condensation and heat of fusion refers to melting.

Explanation:

Heat of vaporization or heat of evaporation, is defined as the energy required to convert liquid substance into a gas which creates condensation. As a gas condenses to a liquid, heat is released.

Heat of fusion refers to melting because heat of fusion is defined as the energy required to change any amount of substance when it melts.

Hence, the correct answer is "Heat of vaporization refers to condensation and heat of fusion refers to melting.".

Answer:

hi

Explanation:

Answer:

The answer is the photo attached

Explanation:

Answer:

Lithium is used in making electrochemical cells.

Answer:

1.5g

Explanation:

Remember that Molarity = (#moles of solute)/(#liters of solution)

This problem informs us that the Molarity of the vinegar is 0.84 and that the solution is 15mL.

First let's get your SI units to the correct ones.

15mL (1L/1000mL) = 0.015L

Molarity = (#moles of solute)/(#liters of solution) ~

(Molarity)(#liters of solution) = #moles of solute

(0.84M)(.015L) = 0.0126moles of acetic acid per tablespoon

2 tablespoons a day = 0.0126moles*2 =  0.0252 moles of acetic acid.

Now that we have the # of moles of acetic acid we need to get our answer into grams. The molecular weight of HC2H3O2 is 60g/mole.

0.0252mole HC2H3O2 (60g HC2H3O2/1mole HC2H3O2) = 1.512g ~ 1.5g HC2H3O2.

Answer:

Oxidation half equation;

3Cd(s) -------> 3Cd^2+(aq) + 6e

Reduction half equation;

2In^3+(aq) + 6e -----> 2In(s)

Explanation:

Since the reduction potentials of Indium and Cadmium are -0.34 V and - 0.40 V respectively, we can see that cadmium will be oxidized while indium will the reduced.

We arrived at this conclusion by examining the reduction potential of both species. The specie with more negative reduction potential is oxidized in the process.

Oxidation half equation;

3Cd(s) -------> 3Cd^2+(aq) + 6e

Reduction half equation;

2In^3+(aq) + 6e -----> 2In(s)

Answer: [tex]\Delta G^{0}[/tex] = 168.12 kJ

Explanation: Gibbs Free Energy, at any time, is defined as the enthalpy of the system minus product of temperature and entropy of the reaction, i.e.:

[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]

Enthalpy is defined as internal heat existent in the system. It is calculated as:

[tex]\Delta H^{0} = \Sigma H^{0}_{product} - \Sigma H^{0}_{reagent}[/tex]

Using Enthalpy Formation Table:

[tex]\Delta H^{0} = [3*(-299.9)+(-524.7)] - (-1277)[/tex]

[tex]\Delta H^{0} = 62,6 kJ[/tex]

Entropy is the degree of disorder in the system. It is found by:

[tex]\Delta S^{0} = \Sigma S^{0}_{products} - \Sigma S^{0}_{reagents}[/tex]

Calculating:

[tex]\Delta S^{0} = (-321.7) + 3(-10.8) - 0[/tex]

[tex]\Delta S^{0} = -354.1J[/tex]

And so, Gibbs Free energy will be:

[tex]\Delta G^{0} = \Delta H^{0} - T.\Delta S^{0}[/tex]

[tex]\Delta G^{0} = 62600 - [298.(-354.1)][/tex]

[tex]\Delta G^{0} = 168121.8 J[/tex]

Rounding to the nearest kJ:

[tex]\Delta G^{0}[/tex] = 168.12 kJ

The amount, in grams, of Al that reacted with excess HCl if 3.86 L of hydrogen gas were collected at STP in the reaction would be 3.099 grams.

From the equation of the reaction, the mole ratio of Al that reacts with that of hydrogen gas that forms is 2:3.

At STP, 1 mole of any gas is equivalent to 22.4 Liters of the gas.

But only 3.86 L of hydrogen was formed in the reaction.

The equivalent mole of 3.86 L hydrogen at STP would be:

      3.86 x 1/22.4 = 0.1723 moles

From the mole ratio, the equivalent mole of Al that will produce 0.1723 moles of hydrogen gas would be:

          0.1723 x 2/3 = 0.1149 moles

Recall that: mass = mole x molar mass

Mass of 0.1149 moles Al = 0.1149 x 26.98

                                        = 3.099 grams

Thus, the amount of Al that reacted with excess HCl is 3.099 grams.

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