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Related Questions
Which of the following do we need to know in order to calculate pH during an acid-base titration of a strong monoprotic acid with a strong monoprotic base? Select all that apply
a. the concentration of the acid
b. the concentration of the base titrant
c. the initial volume of the acid solution
d. the volume of the titrant used
Answers
Answer:
the volume of the titrant used
Explanation:
Acid-base titrations are usually depicted on special graphs referred to as titration curve. A titration curve is a graph that contains a plot of the volume of the titrant as the independent variable and the pH of the system as the dependent variable.
Hence, a titration curve is a graphical plot showing the pH of the analyte solution plotted against the volume of the titrant as the reaction is in progress. The titration curve is drawn by plotting data obtained during a titration, that is, volume of the titrant added (plotted on the x-axis) and pH of the system (plotted on the y-axis).
f the Ksp for HgBr2 is 2.8×10−14, and the mercury ion concentration in solution is 0.085 M, what does the bromide concentration need to be for a precipitate to occur?
Answers
Answer:
0.057 M
Explanation:
Step 1: Given data
Solubility product constant (Ksp) for HgBr₂: 2.8 × 10⁻⁴
Concentration of mercury (II) ion: 0.085 M
Step 2: Write the reaction for the solution of HgBr₂
HgBr₂(s) ⇄ Hg²⁺(aq) + 2 Br⁻
Step 3: Calculate the bromide concentration needed for a precipitate to occur
The Ksp is:
Ksp = 2.8 × 10⁻⁴ = [Hg²⁺] × [Br⁻]²
[Br⁻] = √(2.8 × 10⁻⁴/0.085) = 0.057 M
Please help me fast! Pleaseee
Answers
I think 2 answer is write
HELP ASAP 15 POINTS
Why was Dalton's theory of the atom incorrect?
A. Dalton theorized that atoms were indivisible but they are actually made of smaller parts.
B. Dalton theorized that had negative charges spread throughout them but they are actually in electron shells.
C. Dalton' theory was correct.
D. Dalton theorized that atoms were too small to see but they are not.
Answers
Answer:
Answer is A.
Explanation:
The indivisibility of an atom was proved wrong: an atom can be further subdivided into protons, neutrons and electrons. According to Dalton, the atoms of same element are similar in all respects. However, atoms of some elements vary in their masses and densities. These atoms of different masses are called isotopes. :)
balance the following reaction:
C₃H1₂ +
02
CO2 +
H20
Answers
Answer:
C₃H1₂ +
Explanation:
just took the exam
At standard temperature and pressure conditions, the volume of an ideal gas contained in a jar is 55.3 L. How many molecules are in the jar. This question is to be answered in scientific notation.(eg. 1.5 e5)
Answers
Answer:
1.49e24
Explanation:
Standars temperature and pressure are 273.15K and 1atm, respectively.
Using ideal gas law, we can find moles of an ideal gas if we know its pressure, temperature and volume as follows:
PV = nRT
PV / RT = n
Where P is pressure (1atm), V is volume (55.3L), R is gas constant (0.082atmL/molK), T is temperature (273.15K) and n moles of the ideal gas.
Replacing:
PV / RT = n
1atm*55.3L / 0.082atmL/molK*273.15K = n
2.47 moles = n
Now, the question is about the number of molecules in the jar. By definition, 1 mole = 6.022x10²³ molecules.
As we have 2.47 moles:
2.47 mol × (6.022x10²³ molecules / 1 mole) =
1.49x10²⁴ molecules that are in the jar
In scientific notation:
1.49e24A galvanic cell is powered by the following redox reaction:
2Zn2+(aq) + N2H4(aq) 4OH-zn2+ right arrow(aq) 2Zn(s) + N2(g) + 4H2O(I)
1. Write a balanced equation for the half-reaction that takes place at the cathode.
2. Write a balanced equation for the half-reaction that takes place at the anode.
3. Calculate the cell voltage under standard conditions.
Answers
What is the electron configuration for the transition metal ion in each of the following compounds?
[Ni(H2O)6]Br2
[Cr(H2O)4(NO2)2]I
Answers
Answer:
1)Ni=1s2, 2s2, 2p6, 3s2, 3p6, 4s0, 3d10 called full-filled
2)Cr=1s2, 2s2, 2p6, 3s2, 3p6, 4s1, 3d5 called half-filled
NEED ANSWER FAST 50 POINTS
A mixture of copper sulfate and water is heated, leaving a residue of copper sulfate in the container. Which method was used to separate the mixture?
A. chromatography
B. evaporation
C. filtration
D. distillation
Answers
The method used to separate copper sulfate and water mixture was evaporation.
Explanation:
Chromatography is a separation technique used in labs. In this technique, there are two phases, the mobile phase, and the stationary phase. The phase in which the mixture is dissolved is termed as mobile phase and the phase which serves as a carrier through the system like, sheet, capillary, etc. is termed as mobile phase.Evaporation is a process in which the action of heat is employed to separate dissolved solids from liquid. Due to heat liquid gets evaporated leaving the solid behind.Filtration is a process in which insoluble particles are separated from the liquid by allowing them to pass through a porous substance such as filter paper. Distillation is a process used in the separation of the mixture of liquids with different boiling points.So, from this, we can conclude that the method used to separate copper sulfate and water mixture was evaporation.
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Answer:
Just did this on my test the answer is evaportion.
Explanation:
A piece of solid metal is put into an aqueous solution of . Write the net ionic equation for any single-replacement redox reaction. Assume that the oxidation state of in the resulting solution is 2 .
Answers
The question is incomplete,the complete question is as follows:
A piece of solid Fe metal is put into an aqueous solution of Cu(NO3)2. Write the net ionic equation for any single-replacement redox reaction that may be predicted. Assume that the oxidation state of in the resulted solution is 2 . (Use the lowest possible coefficients for the reaction. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed, leave it blank. If no reaction occurs, leave all boxes blank and click on Submit.)
Answer:
Fe(s) + Cu^2+(aq) => Fe^2+(aq) + Cu(s)
Explanation:
An ionic equation is a chemical equation which shows clear image of reactions of the electrolytes in aqueous solution.
Molecular reaction equation for the reaction between iron and copper II nitrate is as follows:
Fe(s) + Cu(NO3)2(aq) => Fe(NO3)2(aq) +Cu(s)
The net ionic equation for any single-replacement redox reaction is as follows:
Fe(s) + Cu^2+(aq) => Fe^2+(aq) + Cu(s)
A student is using a coffee-cup calorimeter to determine the enthalpy change of the endothermic reaction of two aqueous solutions. After both solutions are added to the cup, the student neglects to put the lid on the cup. This would cause the magnitude of the calculated ΔH° value to be: the answer is: too small, since the solution will absorb heat from the room. But why? Wouldn't depend on if the reaction releases or absorbs heat. Wouldn't it be too large because heat escapes the cup? I'm so confused
Answers
Answer:
Explanation:
In all calorimetric experiment , the calorimeter must be isolated from the surrounding . Otherwise the heat change in the experiment can not be determined with precision .
The reaction is endothermic . Hence, there is lowering of temperature due to absorption of heat in the reaction equal to ΔH°. The value of ΔH° can be calculated by measuring fall in the temperature of the content . The fall in the temperature will be less when heat is allowed to come from the surrounding . Less fall of temperature will result in less ΔH° to be calculated .
Hence in the given experiment , if the student neglects to put lid on the cup , the experiment will give less value of ΔH°.
Each energy sublevel contains __________ number of electrons. For example, sublevel D can hold up to _______ electrons. A. the same, 10 B. the same, 14 C. a different, 6 D. a different, 10
Answers
Answer:
Each energy sublevel contains a different number of electrons. For example, sublevel D can contain up to 10 electrons
Explanation:
The atoms are surrounded by propellers that within each propeller there is a certain number of electrons, these electrons jump from orbit to orbit according to the amount of energy they have. The four levels that make up the electronic cloud that surrounds an atom are: s p d f.
When these electrons change orbit or level they release energy in the form of light, which is known as a photon.
For an ideal gas condition, what is the mass (g) of N2 if the pressure is 2.0 atm, the volume is 25 mL and the temperature is 290 Kelvin.
Answers
Answer:
THE MASS OF NITROGEN GAS IN THIS CONDITIONS IS 0.0589 g
Explanation:
In an ideal condition
PV = nRT or PV = MRT/ MM where:
M = mass = unknown
MM =molar mass = 28 g/mol
P = pressure = 2 atm
V = volume = 25 mL = 0.025 L
R = gas constant = 0.082 L atm/mol K
T = temperature = 290 K
n = number of moles
The gas in the question is nitrogen gas
Molar mass of nitrogen gas = 14 * 2 = 28 g/mol
Then equating the variables and solving for M, we have
M = PV MM/ RT
M = 2 * 0.025 * 28 / 0.082 * 290
M = 1.4 / 23.78
M = 0.0589 g
The mass of the nitrogen gas at ideal conditions of 2 atm, 25 mL volume and 290 K temperature is 0.0589 g
The insoluble salts below are put into 0.10 M hydrochloric acid solution. Do you expect their solubility to be more, less, or about the same as in a pure water solution?
1. Zinc sulfide
2. Silver chloride
3. Lead iodide
4. Silver hydroxide
Answers
Answer:
1. Zinc sulfide : about the same solubility, no common ion is found.
2. Silver chloride : less solubility due to the presence of chloride ions provided by the 0.10 M hydrochloric acid.
3. Lead iodide : about the same solubility, no common ion is found.
4. Silver hydroxide : about the same solubility, no common ion is found.
Explanation:
Hello,
In this case, we first must remember that adding a common ion (which is related with the dissolving solid) decreases the solubility of the insoluble solid due to the fact Le Chatelier's principle states the reaction will shift leftwards (reactants) to reestablish equilibrium, therefore, we have:
1. Zinc sulfide : about the same solubility, no common ion is found.
2. Silver chloride : less solubility due to the presence of chloride ions provided by the 0.10 M hydrochloric acid.
3. Lead iodide : about the same solubility, no common ion is found.
4. Silver hydroxide : about the same solubility, no common ion is found.
Best regards.
Using only sodium carbonate, Na2CO3, sodium bicarbonate, NaHCO3, and distilled water determine how you could prepare 50.0 mL of a 0.20 M solution that is buffered to a pH of 10.3. The total molarity of the ions should be 0.20 M. The Ka of the hydrogen carbonate ion, HCO3 - , is 4.7 x 10-11 .
Answers
Answer:
Weight 0.4326 g of sodium bicarbonate and 0.5141 g of sodium carbonate, dissolve it in distilled water and then bring the solution to a final volume of 50.0 mL using distilled water.
Explanation:
The pH of a buffered solution can be calculated using the Henderson-Hasselbalch equation:
[tex] pH = pKa + log(\frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]}) [/tex]
We have that pH = 10.3 and the Ka is 4.7x10⁻¹¹, so:
[tex] 10.3 = -log(4.7 \cdot 10^{-11}) + log(\frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]}) [/tex]
[tex] \frac{[Na_{2}CO_{3}]}{[NaHCO_{3}]} = 0.94 [/tex] (1)
Also, we know that:
[tex] [Na_{2}CO_{3}] + [NaHCO_{3}] = 0.20 M [/tex] (2)
From equation (2) we have:
[tex] [Na_{2}CO_{3}] = 0.20 - [NaHCO_{3}] [/tex] (3)
By entering (3) into (1):
[tex] \frac{0.20 - [NaHCO_{3}]}{[NaHCO_{3}]} = 0.94 [/tex]
[tex] 0.94*[NaHCO_{3}] + [NaHCO_{3}] = 0.20 [/tex]
[tex] [NaHCO_{3}] = 0.103 M [/tex]
Hence, the [Na_{2}CO_{3}] is:
[tex] [Na_{2}CO_{3}] = 0.20 - [NaHCO_{3}] = 0.20 M - 0.103 M = 0.097 M [/tex]
Now, having the concentrations and knowing the volume of the buffer solution we can find the mass of the sodium carbonate and the sodium bicarbonate, as follows:
[tex]m_{Na_{2}CO_{3}} = C*V*M = 0.097 mol/L*0.050 L*105.99 g/mol = 0.5141 g[/tex]
[tex]m_{NaHCO_{3}} = C*V*M = 0.103 mol/L*0.050 L*84.007 g/mol = 0.4326 g[/tex]
Therefore, to prepare 50.0 mL of a 0.20 M solution that is buffered to a pH of 10.3 we need to weight 0.4326 g of sodium bicarbonate and 0.5141 g of sodium carbonate, dissolve it in distilled water and then bring the solution to a final volume of 50.0 mL using distilled water.
I hope it helps you!
a sample of oxygen occupied 568 ml. when the pressure increased to 911.6 mm Hg. at constant temperature, what volume did the gas initially occupy when the pressure was 248.71 mm Hg?
a 2082
b 155.0
c 2114
d 399.2
Answers
Answer:
[tex]\boxed {\boxed {\sf A. \ 2082 \ mL}}[/tex]
Explanation:
We are asked to find the initial volume of a gas given a change in pressure. Since the temperature remains constant, we are only concerned with volume and pressure. We will use Boyle's Law, which states the volume of a gas is inversely proportional to the pressure. The formula for this law is:
[tex]P_1V_1= P_2V_2[/tex]
The pressure was initially 248.71 millimeters of mercury, but the volume is unknown.
[tex]248.71 \ mm \ Hg * V_1 = P_2V_2[/tex]
The pressure is increased to 911.6 millimeters of mercury and the volume is 568 milliliters.
[tex]248.71 \ mm \ Hg * V_1 = 911.6 \ mm \ Hg * 568 \ mL[/tex]
We are solving for the initial volume, so we must isolate the variable V₁. It is being multiplied by 248.71 millimeters of mercury. The inverse operation of multiplication is division, so we divide both sides by 248.71 mm Hg.
[tex]\frac {248.71 \ mm \ Hg * V_1 } {248.71 \ mm \ Hg}= \frac{911.6 \ mm \ Hg * 568 \ mL }{248.71 \ mm \ Hg}[/tex]
[tex]V_1 = \frac{911.6 \ mm \ Hg * 568 \ mL }{248.71 \ mm \ Hg}[/tex]
The units of millimeters of mercury (mm Hg) cancel.
[tex]V_1 = \frac{911.6 * 568 \ mL }{248.71 }[/tex]
[tex]V_1 = \frac {517788.8} {248.71 } \ mL[/tex]
[tex]V_1 = 2081.897793 \ mL[/tex]
Let's round to the nearest whole number. The 8 in the tenths place tells us to round the 1 up to a 2.
[tex]V_1= 2082 \ mL[/tex]
The gas initially occupied a volume of 2082 milliliters and choice A is correct.
A student ran the following reaction in the laboratory at 242 K: 2NOBr(g) 2NO(g) Br2(g) When she introduced 0.143 moles of NOBr(g) into a 1.00 liter container, she found the equilibrium concentration of NOBr(g) to be 0.108 M. Calculate the equilibrium constant, Kc, she obtained for this reaction. Kc
Answers
Answer:
1.84 × 10⁻³
Explanation:
Step 1: Write the balanced equation
2 NOBr(g) ⇄ 2 NO(g) + Br₂(g)
Step 2: Calculate the initial concentration of NOBr
0.143 moles of NOBr(g) are introduced into a 1.00 liter container. The molarity is:
M = 0.143 mol / 1.00 L = 0.143 M
Step 3: Make an ICE chart
2 NOBr(g) ⇄ 2 NO(g) + Br₂(g)
I 0.143 0 0
C -2x +2x +x
E 0.143-2x 2x x
Step 4: Find the value of x
The equilibrium concentration of NOBr(g) was 0.108 M. Then,
0.143-2x = 0.108
x = 0.0175
Step 5: Calculate the concentrations at equilibrium
[NOBr] = 0.108 M
[NO] = 2x = 0.0350 M
[Br₂] = x = 0.0175 M
Step 6: Calculate the equilibrium constant (Kc)
Kc = [0.0350]² × [0.0175] / [0.108]²
Kc = 1.84 × 10⁻³
What is the formula for tin (II) chlorate decahydrate?
Answers
Answer:
The formula is:
Sn(ClO3)2
Tin(II) Chlorate is also called stannous chlorate and is a white-colored solid. Hydrates are the addition of water molecules. Tin (II) chlorate decahydrate is represented by Sn(ClO₃)₂ . 10 H₂O.
What are hydrates?Hydrates are the chemical compounds used to represent the water molecule (H₂O) in a compound. The water molecules are added to the compound formula as a crystalline structure.
The element tin is represented by the symbol Sn and chlorate is represented as (ClO₃)₂. The formula also has decahydrate which means it has ten molecules of water that can be represented by 10 H₂O.
The stock nomenclature is used to give the formula for the compound. The overall formula of the compound after adding the individual symbol will give, Sn(ClO₃)₂. 10 H₂O.
Therefore, Sn(ClO₃)₂ . 10 H₂O is a formula for tin (II) chlorate decahydrate.
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1. Draw the condensed structural formula of sodium benzoate showing all charges, atoms including any lone pairs in the side chain functional group, and all sigma and pi bonds.
2. Draw the condensed structural formula of benzoic acid showing all atoms including any lone pairs in the side chain functional group, and all sigma and pi bonds. Indicate the acidic hydrogen.
3. Draw the condensed structural formula of tetrahydrofuran (THF) showing all heteroatoms plus their lone pairs and all sigma and pi bonds.
Answers
The structures are shown in the image attached.
A structural formula is the representation of the molecule in which all atoms and bonds in the molecule are shown.
Since the question requires that all the lone pairs, formal charges and sigma and pi bonds should be shown, then the simple condensed structural formula becomes insufficient in this case.
I have attached images of the structural formula of sodium benzoate (image 1), benzoic acid (image 2) and tetrahydrofuran (image 3).
All the formal charges, lone pairs as well as sigma and pi bonds are fully shown.
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Arrange the following in order of increasing boiling point: CH4, CH3CH3, CH3CH2Cl, CH3CH2OH. Rank from lowest to highest. To rank items as equivalent, overlap them.
Answers
Answer:
In order from lowest to highest:
Methane < Ethane < Chloroethene < Methanol
i.e: CH4 < CH3CH3 < CH3CH2OH < CH3CH2Cl
Explanation:
Compounds with stronger molecular fore have higher boiling points, thus making the molecules more difficult to pull apart. The presence of chains also increases the molecular dispersion. The dipole force of ethanol makes it have a very high boiling point.
I'm positive this explanation would suffice. Best of luck.
The order of increasing boiling points of the substances listed is; CH4 < CH3CH3 < CH3CH2Cl < CH3CH2OH.
Intermolecular interactions occur between molecules. The boiling point and melting points of substances depends on the nature and magnitude of intermolecular interaction between the molecules of the substance.
The order of increasing boiling points of the substances listed is as follows; CH4 < CH3CH3 < CH3CH2Cl < CH3CH2OH. CH3CH2OH has the highest boiling point due to intermolecular hydrogen bonds in the molecule. Though CH4 and CH3CH3 are both alkanes, CH3CH3 has a higher molecular mass and consequently greater dispersion forces and a higher boiling point.
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How many equivalent resonance structures can be drawn for the molecule of SO3 without having to violate the octet rule on the sulfur atom
Answers
Answer:
3
Explanation:
Resonance is a valence bond concept put forward by Linus Pauling to explain the fact that the observed properties of a molecule may be as a result of the fact that its actual structure lie somewhere between a given number of structural extremes called canonical structures or resonance structures.
There are three resonance structures for SO3 that obey the octet rule. All the S-O bonds in SO3 are equivalent in these resonance structures.
Seven equivalent resonance structures for the molecular of SO3 can be drawn without breaking the octet rule.
We can arrive at this answer because:
The octet rule is a rule that states that an atom must reach stability when it has eight electrons in the valence layer.This means that in bonds that cause the donation or sharing of electrons between atoms, each atom has eight electrons in the valence layer.In chemistry, resonance is a term that refers to structures created to represent the donation or sharing of electrons between the atoms of a molecule.These structures can be arranged in different ways, as long as they respect the octet rule.In an SO3 molecule, electrons are shared between atoms. This sharing can be done with seven resonance structures.
These structures are shown in the figure below.
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1.Q= {n: 7 <n<31}, list the members of the set Q
Answers
Q={x:x[tex]\epsilon[/tex]n,7<n<31}
[tex]\\ \sf\longmapsto Q=\left\{8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30\right\}[/tex]
You can write it like this too
[tex]\\ \sf\longmapsto Q=\left\{8,9......30,31\right\}[/tex]
Oxide is a combination of oxygen and another element. So is Water an oxide?
Answers
Answer:
Yah, it's a neutral oxide
Explanation:
[tex]{ \bf{2H_{2(g)} +O_{2(g)} \: →2H _{2}O _{(l)} }}[/tex]
what are the benefits of chemistry to the economy
Answers
Answer:
The role of Chemistry in the field of Economics is as a driving force in all industries, from basic materials for industrial machinery to industrial raw materials.
Solution of the Schrödinger wave equation for the hydrogen atom results in a set of functions (orbitals) that describe the behavior of the electron. Each function is characterized by 3 quantum numbers: n, l, and ml. If the value of n = 3 ... The quantum number l can have values from ? to ? . ... The total number of orbitals possible at the n = 3 energy level is ? . If the value of l = 3 ... The quantum number ml can have values from to ? . ... The total number of orbitals possible at the l = 3 sublevel is ?? .
Answers
Answer:
1) The quantum number l can have values from
2 to 0
2)The total number of orbitals possible at the n = 3 energy level is 3'2=9
3) If the value of l = 3 ... The quantum number ml can have values from 3 to -3
The quantum number l determines the shape of the orbital. In this case, if the value of n is 3, then the quantum number l can have values from 0 to (3-1), which is 2.
The total number of orbitals possible at the n = 3 energy level can be determined using the formula 2l + 1. So, for l = 0, there is 1 orbital. For l = 1, there are 3 orbitals. And for l = 2, there are 5 orbitals. Therefore, the total number of orbitals possible at the n = 3 energy level is 1 + 3 + 5 = 9.
On the other hand, the quantum number ml represents the magnetic quantum number. It specifies the orientation of the orbital in space. The value of ml ranges from -l to +l. So, if the value of l is 3, then the quantum number ml can have values from -3 to +3.
The total number of orbitals possible at the l = 3 sublevel can be determined using the formula 2ml + 1. So, for ml = -3, there is 1 orbital. For ml = -2, there is 3 orbitals. For ml = -1, there is 5 orbitals. For ml = 0, there is 7 orbitals. For ml = 1, there is 5 orbitals. For ml = 2, there is 3 orbitals. And for ml = 3, there is 1 orbital.
Therefore, the total number of orbitals possible at the l = 3 sublevel is 1 + 3 + 5 + 7 + 5 + 3 + 1 = 25.
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The respiration rate of a goldfish is measured. The goldfish is then placed in cold water and the respiration rate is measured again. What is the INDEPENDENT variable?
Answers
Answer:
Temperature of the water
Explanation:
In every study, there must be independent and dependent variables. An independent variable is the variable that is changed in order to obtain a response. In this case, the temperature of the water is being changed, the response in this experiment is the respiration rate of the goldfish.
Thus the respiration rate of the goldfish is the dependent variable because it is controlled by the temperature of the water and changes accordingly.
Summarily, the independent variable is the temperature of the water while the dependent variable is the respiration rate of the goldfish.
1.40 m3 is how many mL
Answers
[tex] \LARGE{ \boxed{ \rm{ \pink{Solution:}}}}[/tex]
We know, 1 m³ of space can hold 1000 l of the substance.
⇛ 1 m³ = 1000 l----(1)
And, 1 l is 1000 times more than 1 ml
⇛ 1 l = 1000 ml------(2)
So, From (1) and (2),
⇛ 1 m³ = 1000 × 1000 ml
⇛ 1m³ = 1000000 ml
We had to find,
⇛ 1.40 m³ = 1.40 × 1000000 ml
⇛ 1.40 m³ = 140/100 × 1000000 ml
⇛ 1.40 m³ = 1400000 ml
⇛ 1.40 m³ = 14,00,000 ml / 14 × 10⁵ ml / 1.4 × 10⁶ ml
☃️ So, 1.40 m³ = 14 × 10⁵ ml / 1.4 × 10⁶ ml.
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Why is the r.a.m. Value used?
Answers
Answer:
The r.a.m. value is used to determine how many isotopes an element has.
Explanation:
what is the colour before and after when bromine reacts with chlorine ??
Answers
ANSWER
I need great answers
EXPLANATION
please rate my answer as great
Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na 2CrO 4 are added to 250 mL of 0.12 M AgNO 3? [K sp(Ag 2CrO 4) = 1.1 × 10 –12] What is the concentration of the silver ion remaining in solution?
Answers
Answer:
A precipitate will form.
[Ag⁺] = 2.8x10⁻⁵M
Explanation:
When Ag⁺ and CrO₄²⁻ are in solution, Ag₂CrO₄(s) is produced thus:
Ag₂CrO₄(s) ⇄ 2 Ag⁺(aq) + CrO₄²⁻(aq)
Ksp is defined as:
Ksp = 1.1x10⁻¹² = [Ag⁺]² [CrO₄²⁻]
Where the concentrations [] are in equilibrium
Reaction quotient, Q, is defined as:
Q = [Ag⁺]² [CrO₄²⁻]
Where the concentrations [] are the actual concentrations
If Q < Ksp, no precipitate will form, if Q >= Ksp, a precipitate will form,
The actual concentrations are -Where 500mL is the total volume of the solution-:
[Ag⁺] = [AgNO₃] = 0.12M ₓ (250mL / 500mL) = 0.06M
[CrO₄²⁻] = [Na₂CrO₄] = 0.33M × (250mL / 500mL) = 0.165M
And Q = [0.06M]² [0.165M] = 5.94x10⁻⁴
As Q > Ksp; a precipitate will form
In equilibrium, some Ag⁺ and some CrO₄⁻ reacts decreasing its concentration until the system reaches equilibrium. Equilibrium concentrations will be:
[Ag⁺] = 0.06M - 2X
[CrO₄²⁻] = 0.165M - X
Where X is defined as the reaction coordinate
Replacing in Ksp expression:
1.1x10⁻¹² = [0.06M - 2X]² [0.165M - X]
Solving for X:
X = 0.165M → False solution. Produce negative concentrations.
X = 0.0299986M
Replacing, equilibrium concentrations are:
[Ag⁺] = 0.06M - 2(0.0299986M)
[CrO₄²⁻] = 0.165M - 0.0299986M
[Ag⁺] = 2.8x10⁻⁵M[CrO₄²⁻] = 0.135M