Select True or False: Pi bonds are covalent bonds in which the electron density is concentrated above and below a plane containing the nuclei of the bonding atoms and occurs by sideways overlap of p orbitals.

Answers

Answer 1

Answer:

True

Explanation:

In pi bonds, the electron density concentrates itself between the atoms of the compound but are present on either side of the line joining the atoms. Electron density is found above and below the plane of the line joining the internuclear axis of the two atoms involved in the bond.

Pi bonds usually occur by sideways overlap of atomic orbitals and this leads to both double and triple bonds.


Related Questions

When the nuclide bismuth-210 undergoes alpha decay:
The name of the product nuclide is_____.
The symbol for the product nuclide is_____
Fill in the nuclide symbol for the missing particle in the following nuclear equation.
_____ rightarrow 4He+ 234Th
2 90
Write a balanced nuclear equation for the following:
The nuclide radium-226 undergoes alpha emission.

Answers

Explanation:

An atom undergoes alpha decay by losing a helium atom.

So when bismuth undergoes alpha decay, we have;

²¹⁰₈₃Bi --> ⁴₂He + X

Mass number;

210 = 4 + x

x = 206

Atomic number;

83 = 2 + x

x = 81

The element is Thallium. The symbol is Ti.

For the second part;

X --> ⁴₂He + ²³⁴₉₀Th

Mass number;

x = 4 + 234 = 238

Atomic Number;

x = 2 + 90 = 92

The balanced nuclear equation is;

²³⁸₉₂U --> ⁴₂He + ²³⁴₉₀Th

Which of the following are characteristics of ionic
compounds?

Answers

Answer:

Ionic compounds have high melting points.

Ionic compounds are hard and brittle.

Ionic compounds dissociate into ions when dissolved in water.

Solutions of ionic compounds and melted ionic compounds conduct electricity, but solid materials do not.

Explanation:

What would be the voltage (Ecell) of a voltaic cell comprised of Cd(s)/Cd2+(aq) and Zr(s)/Zr4+(aq) if the concentrations of the ions in solution were [Cd2+] = 0.5 M and [Zr4+] = 0.5 M at 298K?

Answers

Answer:

1.05 V

Explanation:

Since;

E°cell= E°cathode- E°anode

E°cathode= -0.40 V

E°anode= -1.45 V

E°cell= -0.40-(-1.45) = 1.05 V

Equation of the process;

2Zr(s) + 4Cd^2+(aq) ---->2Zr^4+(aq) + 4Cd(s)

n= 8 electrons transferred

From Nernst's equation;

Ecell = E°cell - 0.0592/n log Q

Ecell= E°cell - 0.0592/8 log [0.5]/[0.5]

Since log 1=0

Ecell= E°cell= 1.05 V

Determine what product will be produced at the negative electrode for the following reaction:
2KCl(aq) + 2H20(1) -> H2(g) + Cl2(g) + 2KOH(aq)
A. H2
B. Cl2
с. КОН
D. K

Answers

Answer:

Choice A. [tex]\rm H_{2}[/tex] would be produced at the negative electrode.

Explanation:

Ionic equation for this reaction:

[tex]2\, {\rm K^{+}} + 2\, {\rm Cl^{-}} + {2\, \rm H_{2} O} \to {\rm H_{2}} + {\rm Cl_{2}} + 2\, {\rm K^{+}} + {\rm 2\, OH^{-}}[/tex].

Net ionic equation:

[tex]2\, {\rm Cl^{-}} + 2\, \rm H_{2} O} \to {\rm H_{2}} + {\rm Cl_{2}} + 2\, {\rm OH^{-}}[/tex].

Half-equations:

[tex]2\, {\rm Cl^{-}} \to {\rm Cl_{2}} + 2\, {e^{-}}[/tex].

(Electrons travel from the solution to an electrode.)

[tex]2\, {\rm \overset{+1}{H}_{2} O} + 2\, {e^{-}} \to \overset{0}{\rm H}_{2} + 2\, {\rm O\overset{+1}{H}\!^{-}}[/tex].

(An electrode supply electrons to the solution to reduce some of the [tex]\rm H[/tex] atoms from [tex]\rm H_{2}O[/tex].)

In a DC circuit, electrons always enter the circuit from the negative terminal of the power supply and return to the power supply at the positive terminal.

The negative electrode is connected to the negative terminal of the power supply. Electrons from the power supply would flow into the solution through this electrode.  

This continuous supply of electrons at the negative electrode would drive a reduction half-reaction. In this question, that corresponds to the reduction of water: [tex]2\, {\rm \overset{+1}{H}_{2} O} + 2\, {\rm e^{-}} \to \overset{0}{\rm H}_{2} + 2\, {\rm O\overset{+1}{H}\!^{-}}[/tex]. Hence, [tex]\rm H_{2}[/tex] would be produced at the negative electrode.

How many unit cells share an atom that is located at the center of a cube edge of a unit cell?

Answers

Answer:

zero

Explanation:

In a unit cell, an atom that is located at the center of a cube edge is not involved in sharing unit cells because a central atom of a unit cell belongs to the entire cell and only to that unit cell of the lattice.

Hence, the center atom of a unit cell do not share any unit cell and the correct answer is "Zero".

How many moles of gold are equivalent to 1.204 × 1024 atoms? 0.2 0.5 2 5

Answers

Answer:

c

Explanation:

How many moles of gold are equivalent to 1.204 × 1024 atoms?

0.2

0.5

2

5

C) 2 Is the correct answer, I took the test and it was correct.

According to the concept of Avogadro's number, there are 2 moles of gold which are equivalent to 1.204×10²⁴ atoms.

What is Avogadro's number?

Avogadro's number is defined as a proportionality factor which relates number of constituent particles with the amount of substance which is present in the sample.

It has a SI unit of reciprocal mole whose numeric value is expressed in reciprocal mole which is a dimensionless number and is called as Avogadro's constant.It relates the volume of a substance with it's average volume occupied by one of it's particles .

According to the definitions, Avogadro's number depend on determined value of mass of one atom of those elements.It bridges the gap between macroscopic and microscopic world by relating amount of substance with number of particles.

Number of atoms can be calculated using Avogadro's number as follows: mass/molar mass×Avogadro's number.Number of moles=number of atoms/Avogadro's number=1.204×10²⁴ /6.023×10²³=1.999≅2

Thus, there are 2 moles of gold which are equivalent to 1.204×10²⁴ atoms.

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conversion of 35 mL to ML

Answers

Answer:

1000ml=1l

35ml. = ?

Explanation:

35×1/1000

0.035litres

PLEASE HELP!!
You are performing an experiment that involves the electrolysis of gold (I) bromide, also know as AuBr. You know that gold is less reactive than hydrogen. Which of the following would be the product of the reaction?
A. Hydrogen gas
B. Gold bromide
C. Oxygen gas
D. Pure gold

Answers

Answer:

D. Pure gold

Explanation:

Hello,

In this case, since gold, as a heavy metal, is said to be less reactive than hydrogen, when it undergoes electrolysis process when forming a salt, due to the action of the electric current, we can appreciate the formation of a layer of gold on the surface of the cathode via a reduction half-reaction from gold (I) to metallic gold:

[tex]Au^++1e^-\rightarrow Au^0[/tex]

Thereby, D. Pure gold is formed as the product of the reaction.

In contrast, more reactive metals than hydrogen such as sodium or potassium, will remain in solution so the hydrogen converted to hydrogen gas.

Best regards-

A graph of gas pressure versus the number of particles in a container is a straight line. Which other relationship will have a similar graph?​

Answers

Answer:

volume versus temperature, because they are also directly proportional.

Explanation:

Just took the test!

The second law of thermodynamics predicts that heat flow from a cooler object to a hotter object:________
a) will be spontaneous at high pressure
b) will be spontaneous at low pressure
c) will never be spontaneous at any pressure
d) will always be spontaneous

Answers

Answer:

c) will never be spontaneous at any pressure.

Explanation:

Hello,

In this case, we need to remember that the second law of thermodynamics states that heat flow is transferred from a hot object to a cold object only, never the other way around, therefore, the answer is c) will never be spontaneous at any pressure. This is supported by driving force that in this case is the temperature difference which must be negative for the hot object (it gets eventually cold) and positive for the cold object (it gets eventually hot) until they reach the equilibrium temperature.

Best regards.

All of the following are examples of allotropes of carbon EXCEPT Choose the one alternative that best completes the statement or answers the question. Choose the one alternative that best completes the statement or answers the question. diamond amorphous carbon quartz graphene all of the above

Answers

Answer:

quartz

Explanation:

The correct option would be quartz.

Allotropy is a phenomenon that describes the natural existence of the same element in different forms with different physical characteristics. Allotropes are therefore different forms of the same element.

Carbon as an element has several allotropes which include diamond, graphite, graphene, amorphous carbon, and fullerenes. Quartz is a crystalline solid that is composed of silicon dioxide and not carbon.

Hence, all the options are carbon allotropes except quartz.

20. Stoichiometry is based on
A. molecular weight.
B. temperature.
C. conservation of matter.
D. pressure.

Answers

Answer:

The correct option is (c)

Answer:

the law of conservation of mass

Chromium-51 is a radioisotope that is used to assess the lifetime of red blood cells The half-life of chromium-51 is 27.7 days. If you begin with 48.0 mg of this isotope, what mass remains after 47.9 days have passed?

Answers

Answer:

After 47.9 days, will remain 14.5mg of the isotope

Explanation:

The radioactive decay follows always first-order kinetics where its general law is:  

Ln[A] = -Kt + ln[A]₀

Where [A] is actual concentration of the atom, k is rate constant, t is time and [A]₀ is initial concentration.

We can find rate constant from half-life as follows:

[tex]t_{1/2} = \frac{ln2}{K}[/tex]

K = ln 2 / 27.7 days

K = 0.025 days⁻¹

Replacing, initial amount of isotope is 48.0mg = [A]₀ , K is 0.025 days⁻¹ and t = 47.9 days:

Ln[A] = -Kt + ln[A]₀

Ln[A] = -0.025 days⁻¹*47.9 days + ln (48.0mg)

ln [A] = 2.6726

[A] = e^ (2.6726)

[A] = 14.5mg

After 47.9 days, will remain 14.5mg of the isotope

Determine whether each phrase describes carboxylic acids or esters.a. Do not form hydrogen bonds amongst themselves and have higher vapor pressureb. Form hydrogen bonds amongst themselves and have lower vapor pressurec. Notable for their pleasant fragrancesd. Their reactions with base are kn. own as saponificationse. Usually have a sour odorf. Their reactions with base are known as neutralizations

Answers

Explanation:

a. Esters

b. Carboxylic acids

c. Esters (ethyl hexanoate smells like pineapple)

d. Carboxylic acids (produces a carboxylic salt)

For the given phrases the following description is better.

a. Esters

b. Carboxylic acids

c. Esters (ethyl hexanoate smells like pineapple)

d. Carboxylic acids (produces a carboxylic salt)

Esters and carboxylic acids:

An ester is a synthetic compound got from a corrosive in which somewhere around one - OH hydroxyl bunch is supplanted by an - O-alkyl (alkoxy) bunch, as in the replacement response of a carboxylic acid and a liquor.

Carboxylic acid is any of a class of natural mixtures in which a carbon (C) particle is clung to an oxygen (O) molecule by a twofold bond and to a hydroxyl bunch (―OH) by a solitary bond.

Find more information about esters here:

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Pentanone was treated with excess sodium cyanide in HCl (aq) followed by hydrogen gas has over Pd. This produced:________
A. 2-amino-1-hexanol
B. 1-amino-2-methylpentan-2-ol
C. 1-cyano-1-pentanol
D. 2-aminomethylpentan-1-ol

Answers

Answer:

B. 1-amino-2-methylpentan-2-ol

Explanation:

In this case, the first step, we have the attack of the nucleophile cyanide ([tex] CN^-[/tex] produced by sodium cyanide to the carbon on the carbonyl group (C=O) producing a negative charge in the oxygen.

Then HCl protonates the molecule to produce a cyanohydrin. This cyanohydrin can be reduced by the action of hydrogen gas ([tex]H_2[/tex]) in the presence of a catalyst ([tex]Pd[/tex]), producing an amino group. With this in mind, the final molecule is: 1-amino-2-methylpentan-2-ol.

See figure 1 to further explanations

I hope it helps!

Which solution has the greatest buffer capacity? Select the correct answer below: 1 mole of acid and 1 mole of base in a 1.0 L solution

Answers

Answer:

The answer is

Explanation:

1 mole of acid.

Hope this helps....

Have a nice day!!!!

A buffer that is 1 M in acid and base will have the greatest capacity of buffer, and therefore the greatest buffer capacity.

What do you mean by the buffer solution ?

A weak acid and the conjugate base of the weak acid, or a weak base and the conjugate acid of the weak base, are combined to form the buffer solution, a water-based solvent solution.

In a biological system, a buffer's keep intracellular and extracellular pH levels within a relatively small range and to withstand pH fluctuations brought on by both internal and external factors.

A buffer is a substance that can withstand a pH shift when acidic or basic substances are added. It may balance out little quantities of additional acid or base, keeping the pH stable.

Thus, 1 M in acid and base solution has the greatest buffer capacity.

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Which of the following has the greatest effect on colligative properties?

A. Calcium chloride (CaCl2)
B. Sodium chloride (NaCl)
C. Aluminum Nitrate (Al(NO3)3)
D. Epsom salt (MgSO4)

Answers

Answer:

C. Aluminum Nitrate (Al(NO3)3)

Explanation:

This is because, when Aluminium nitrate dissolves in water, it dissociates to form four ions ( one aluminium ion and three nitrate ions ). Since colligative property depends on number of particles or ions present ( roult's law ), this will create much effect.

[tex]Al(NO _{3} )_{3(aq)} → Al {}^{3 + } _{(aq)} + 3NO {}^{ - } _{(aq)}[/tex]

Answer:

aluminum nitrate (Al(NO3)3)

it has the greatest effect on collimation properties .

Explanation:

(c) is correct option

what is ammonium nitrate

Answers

Answer:

Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.

. You have two solutions, both with a concentration of 0.1M. Solution A contains a weak acid with a pKa of 5. ThepH of solution A is 3. Solution B contains a weak acid with a pKa of 9. The pH of solution B is:

Answers

Answer:

pH of solution B is 5

Explanation:

A weak acid, HA, is in equilibrium with water as follows:

HA(aq) + H₂O(l) ⇄ A⁻(aq) + H₃O⁺(aq)

Where Ka (10^-pKa = 1x10⁻⁹) is:

Ka = 1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

Where concentrations of this species are equilibrium concentrations

As initial concentration of HA is 0.1M, the equilibrium concentrations of the species are:

[HA] = 0.1M - X

[A⁻] = X

[H₃O⁺] = X

Where X is the amount of HA that reacts until reach the equilibrium, X is reaction coordinate.

Replacing in Ka expression:

1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

1x10⁻⁹ = [X] [X] / [0.1 - X]

1x10⁻¹⁰ - 1x10⁻⁹X = X²

1x10⁻¹⁰ - 1x10⁻⁹X - X² = 0

Solving for X:

X = -0.00001 → False solution, there is no negative concentrations.

X = 1x10⁻⁵ → Right solution.

As [H₃O⁺] = X

[H₃O⁺] = 1x10⁻⁵M

And pH = -log[H₃O⁺]

pH = 5

pH of solution B is 5

What is a chemical formula, and what does it tell you?

Answers

Explanation:

chemical formula tells you the specific elements included in the compound and the number of atoms of each. The letters in a chemical formula are the symbols for the specific elements. So for example, H means hydrogen.

Explanation:

A chemical formula is a way of presenting information about the chemical properties of atoms that contribute a particular chemical compound or molecule, using chemical elements.

What is Entropy?

A. The opposite of Enthalpy
B. The temperature at which a reaction is feasible.
C. A measure of disorder.
D. Free energy used for a reaction.

Answers

Answer:

C. A measure of disorder :)

Using these metal ion/metal standard reduction potentials Cd2+(aq)|Cd(s) Zn2+(aq)|Zn(s) Ni2+(aq)|Ni(s) Cu2+(aq)/Cu(s) -0.40 V -0.76 V ‑0.25 V +0.34 V Calculate the standard cell potential for the cell whose reaction is Ni2+(aq) + Zn(s) →Zn2+(aq)+ Ni(s)

Answers

Answer: The standard cell potential for the cell is +0.51 V

Explanation:

Given : [tex]E^0_{Ni^{2+}/Ni}=-0.25V[/tex]

[tex]E^0_{Zn^{2+}/Zn}=-0.76V[/tex]

The given reaction is:

[tex]Ni^{2+}(aq)+Zn(s)\rightarrow Zn^{2+}(aq)+Ni(s)[/tex]

As nickel is undergoing reduction, it acts as cathode and Zinc is undergoing oxidation, so it acts as anode.

[tex]E^0_{cell}=E^0_{cathode}-E^0_{anode}[/tex]

where both [tex]E^0[/tex]  are standard reduction potentials.

Thus putting the values we get:

[tex]E^0_{cell}=-0.25-(-0.76)[/tex]

[tex]E^0_{cell}=0.51V[/tex]

Thus the standard cell potential for the cell is +0.51 V

The equilibrium constant K changes with changes in
the temperature.​

Answers

Answer:Equilibrium constants are changed if you change the temperature of the system. Kc or Kp are constant at constant temperature, but they vary as the temperature changes. You can see that as the temperature increases, the value of Kp falls.

Calculate the molality of a solution containing 141.5 g of glycine (NH2CH2COOH) dissolved in 4.456 kg of H2O

Answers

Answer:

0.423 m.

Explanation:

The following data were obtained from the question:

Mass of glycine (NH2CH2COOH) = 141.5 g

Mass of water = 4.456 kg

Molality =.?

Next, we shall determine the number of mole in 141.5 g of glycine (NH2CH2COOH.

This is illustrated below:

Mass of glycine (NH2CH2COOH) = 141.5 g

Molar mass of glycine (NH2CH2COOH) = 14 + (2x1) + 12 + (2x1) + 12 + 16 + 16 + 1 = 75 g/mol

Mole of glycine (NH2CH2COOH) =.?

Mole = mass /Molar mass

Mole of glycine (NH2CH2COOH) = 141.5/75

Mole of glycine (NH2CH2COOH) = 1.887 moles

Finally, we shall determine the molality of the solution as follow:

Molality is simply defined as the mole of solute per kilogram of water. Mathematically it is expressed as:

Molality = mole / mass (kg) of water

With the above formula, we can obtain the molality of the solution as follow:

Mole of glycine (NH2CH2COOH) = 1.887 moles

Mass of water = 4.456 kg

Molality =.?

Molality = mole /mass (kg) of water

Molality =1.887/4.456

Molality = 0.423 m

Therefore, the molality of the solution is 0.423 m

Calculate the silver ion concentration in a saturated solution of silver(I) sulfate (K sp = 1.4 × 10 –5). 1.5 × 10–2 M 1.4 × 10–5 M 3.0 × 10–2 M 2.4 × 10–2 M None of the above.

Answers

Answer:

3.0x10⁻²M

Explanation:

Silver sulfate, Ag₂SO₄, has a product constant solubility equilbrium of:

Ag₂SO₄(s) ⇄ 2Ag⁺ + SO₄²⁻

When an excess of silver sulfate is added, some Ag₂SO₄ will react producing Ag⁺ and SO₄²⁻ until reach the equilbrium determined for the formula:

ksp = 1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

Assuming the Ag₂SO₄ that react until reach equilibrium is X, we can replace in Ksp expression:

1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

1.4x10⁻⁵ = [2X]² [X]

1.4x10⁻⁵ = 4X³

3.5x10⁻⁶ = X³

0.015 = X

As [Ag⁺] is 2X:

[Ag⁺] = 0.030 = 3.0x10⁻²M

The answer is:

3.0x10⁻²M

9. In order to determine the melting point of tetradecanol, it was important that _____. the thermometer was attached to the capillary tube the water was frozen the capillary tube was immersed in the water without the thermometer

Answers

To record the melting point of tetradecanol, it is important the temperature is increase by little degrees after each trial.

The thermometer attached to the capillary tube was immersed in water without thermometer.

Usually heating curve describes the temperature change for a sample which passes through different states of matter.

The temperature than decreases and the solution in beaker cools down. To determine the melting point, it is important to keep the temperature consistent.

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The combination of a carbonyl group and a hydroxyl group on the same carbon atom is called a ________ group.

a. carbamate group
b. carbonate
c. carboxlate
d. carboxyl

Answers

Answer:

d. carboxyl

Explanation:

The presence of carbonyl group (>C=O)) and a hydroxyl group ( (−OH) on the same carbon atom is called a "carboxyl" group. A carboxyl group is represented as COOH and acts as the functional group part of carboxylic acids.

For example:

Formic acid or Methanoic acid (H-COOH)  Butanoic acid (C3H7-COOH)

Hence, the correct option is "d. carboxyl ".

In the Lewis structure of AB4 where B is more electronegative than A. Both are main group elements where A has 8 valence electrons and each B has 7 valence electrons.

Required:
a. What is the total number of valence electrons?
b. How many lone pairs are in the molecule?

Answers

Answer:

1. 36

2. Two

Explanation:

The Lewis structure shows the valence electrons present in a compound. Usually the valence electrons are shown as dot structures around the symbol of the elements involved in the compound.

For a compound AB4 where B is more electronegative than A and A has 8 electrons in its valence shell, there will be thirty six valence electrons on the outermost shell of the molecule.

There are six electron pair domains present in the molecule, four bond pairs and two lone pairs. The molecule is in a square planar geometry.

Answer: a- 36 valence electrons

b- 14 lone pairs

Explanation:

Valence is equal to A + 4B = 8 + 4(7)

With 4 bonds between A and the 4 B, that is 36 valence minus 8 electrons in those pairs = 28. 28 is 14 lone pairs.

Janet observes that bubbles rise inside water when water is heated. Which of the following best names and explains the change that causes bubbles to rise?

Answers

Answer:

Boiling

Explanation:

When a liquid is heated, the vapor pressure rises steadily. When water attains a temperature of 100°C or 212°F its vapor pressure is now equal to the atmospheric pressure at sea level, this is what we mean by boiling.

When this occurs, water continues to evaporate untill the vapor pressure inside the bubbles becomes high enough to stop water bubbles from collapsing again from the pressure of the water around it so the bubbles rise and break the surface.

What will be formed when 2,2,3-trimethylcyclohexanone reacts with hydroxylamine?

Answers

Answer:

Following are the solution to this equation:

Explanation:

In the given-question, an attachment file of the choices was missing, which can be attached in the question and its solution can be defined as follows:

In the given question "Option (iii)" is correct, which is defined in the attachment file.

When 2,2,3-trimethylcyclohexanone reacts with hydroxylamine it will produce the 2,2,3-trimethylcyclohexanoxime.

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