The composition of a liquid-phase reaction 2A - B was monitored spectrophotometrically. The following data was obtained: t/min 0 10 20 30 40 conc B/(mol/L) 0 0.089 0.153 0.200 0.230 0.312
1) Determine the order of the reaction. (6 pts.)
2) Find its rate constant. 19 pts.) Note: no unit is needed, just the numerical answer. Hint: convert your minutes to seconds.

Answers

Answer 1

Answer:

1) The order of the reaction is of FIRST ORDER

2)   Rate constant k = 5.667 × 10 ⁻⁴

Explanation:

From the given information:

The composition of a liquid-phase reaction 2A - B was monitored spectrophotometrically.

liquid-phase reaction 2A - B signifies that the reaction is of FIRST ORDER where the rate of this reaction is directly proportional to the concentration of A.

The following data was obtained:

t/min                    0         10         20          30             40          ∞

conc B/(mol/L)    0       0.089    0.153     0.200       0.230    0.312

For  a first order reaction:

[tex]K = \dfrac{1}{t} \ In ( \dfrac{C_{\infty} - C_o}{C_{\infty} - C_t})[/tex]

where :

K = proportionality  constant or the rate constant for the specific reaction rate

t = time of reaction

[tex]C_o[/tex] = initial concentration at time t

[tex]C _{\infty}[/tex] = final concentration at time t

[tex]C_t[/tex] = concentration at time t

To start with the value of t when t = 10 mins

[tex]K_1 = \dfrac{1}{10} \ In ( \dfrac{0.312 - 0}{0.312 - 0.089})[/tex]

[tex]K_1 = \dfrac{1}{10} \ In ( \dfrac{0.312 }{0.223})[/tex]

[tex]K_1 =0.03358 \ min^{-1}[/tex]

[tex]K_1 \simeq 0.034 \ min^{-1}[/tex]

When t = 20

[tex]K_2= \dfrac{1}{20} \ In ( \dfrac{0.312 - 0}{0.312 - 0.153})[/tex]

[tex]K_2= 0.05 \times \ In ( 1.9623)[/tex]

[tex]K_2=0.03371 \ min^{-1}[/tex]

[tex]K_2 \simeq 0.034 \ min^{-1}[/tex]

When t = 30

[tex]K_3= \dfrac{1}{30} \ In ( \dfrac{0.312 - 0}{0.312 - 0.200})[/tex]

[tex]K_3= 0.0333 \times \ In ( \dfrac{0.312}{0.112})[/tex]

[tex]K_3= 0.0333 \times \ 1.0245[/tex]

[tex]K_3 = 0.03412 \ min^{-1}[/tex]

[tex]K_3 = 0.034 \ min^{-1}[/tex]

When t = 40

[tex]K_4= \dfrac{1}{40} \ In ( \dfrac{0.312 - 0}{0.312 - 0.230})[/tex]

[tex]K_4=0.025 \times \ In ( \dfrac{0.312}{0.082})[/tex]

[tex]K_4=0.025 \times \ In ( 3.8048)[/tex]

[tex]K_4=0.03340 \ min^{-1}[/tex]

We can see that at the different time rates, the rate constant of [tex]k_1, k_2, k_3, and k_4[/tex] all have similar constant values

As such :

Rate constant k = 0.034 min⁻¹

Converting it to seconds ; we have :

60 seconds = 1 min

0.034 min⁻¹ =(0.034/60) seconds

= 5.667 × 10 ⁻⁴ seconds

Rate constant k = 5.667 × 10 ⁻⁴


Related Questions

The value of the equilibrium constant for a reaction is 2.65 x 10-6 at 35° Calculate the value of LaTeX: \DeltaΔG°rxn.

Answers

Answer:

234

Explanation:

Draw all constitutional isomers with the following molecular formula. (a) C3H7Cl (b) C4H10 (c) C5H12 (d) C4H10O (e) C3H6Cl2

Answers

Answer:

See explanation

Explanation:

For this question, we must bear in mind that in the isomers what must change is the structure of the molecule but the same condensed formula must be maintained. With this in mind we can have the following options for each of the molecules given by the problem:

(a) [tex]C_3H_7Cl[/tex]

  -) 1-Chloropropane

  -) 2-Chloropropane

 

(b) [tex]C_4H_1_0[/tex]

  -) butane

  -) isobutane

 

(c) [tex]C_5H_1_2[/tex]

  -) n-pentane

  -) isopentane

  -) neopentane

(d) [tex]C_4H_1_0O[/tex]

  -) butan 1-ol

  -) butan 2-ol

  -) 2-methylpropan-1-ol

  -) 2-methylpropan-2-ol

  -) 1-methoxypropane

  -) ethoxyethane

  -) 2-methoxypropane

 

(e) [tex]C_3H_6Cl_2[/tex]

  -) 1,1-dichloropropane

  -) 1,2-dichloropropane

  -) 1,3-dichloropropane

  -) 2,2-dichloropropane

See figure 1 to further explanations

I hope it helps!

Obtain a box of breakfast cereal and read the list of ingredients. What are four chemicals from the list

Answers

Options:

monoglycerides

cocamide DEA

folic acid

iron chromium ion

peroxide

lauryl glucoside

disodium phosphate

Answer and Explanation:

The added chemicals are:

monoglyceridesfolic acidirondisodium phophates

Monoglycerides are fats added for flavour. Folic cid and iron are vitamins added for nutritional value. disodium phosphate is a food additive for enhancing flavour.

The remaining ingredients are organic based.

Identify the following as physical (P) or chemical (C) changes.

Answers

holacomo es tu pregunta nola entiendo

lanation:

Answer:

Where are the questions you want us to identify for you

write each set in
(a) DESCRIPTION MEthod
b. ROSTER METHOD,
(c) rULE METHOD

1.whole number less than 15
2.vowels in the name figueroa
3.integers greater than -4
4.months having 30 days
5.consonants in the name Kenneth​

Answers

Answer:

it is b

Explanation:

because i took the thing

Why was 1990 an important year regarding air quality?
O The United States took first steps to keep the air clean.
O The United States created the Environmental Protection Agency.
Modifications and improvements were made to the Clean Air Act.
O Funding was established under the Clean Air Act to study air pollution.

Answers

Answer:

C. Modifications and improvements were made to the Clean Air Act.

Explanation:

The Clean Air act was originally established in 1970 and was concerned with the aim of protecting people and the environment in general from polluted air. Polluted air could cause different illnesses and environmental degradation.

The law was amended in 1990 in which modifications and improvements were made to the Clean Air Act. There was the need to reduce acid rain, toxic emissions which could deplete the ozone layer and cause varying respiratory illnesses in humans and to increase visibility.

1990 was an important year to to the United States regarding Air Quality because "Modifications and improvements were made to the Clean Air Act." (Option C)

How is this so?

In reality, 1990 was an important year for air quality due to the enactment of significant amendments to the Clean Air Act in the United States.

These amendments, signed into law in November 1990, introduced stricter regulations and requirements to combat air pollution.

The amendments addressed various pollutants, including sulfur dioxide, nitrogen oxides, and hazardous air pollutants, leading to improved air quality standards and a more comprehensive approach to protecting human health and the environment from the harmful effects of air pollution.

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why is it essential to know the water temperature in this experiment- to find the vapor pressure of the water

Answers

Answer:

Vapour pressure of a liquid varies with temperature

Explanation:

The vapour pressure of any liquid is directly proportional to the temperature of the liquid. This implies that, as the temperature of the liquid increases, the vapour pressure increases likewise and vice versa.

Since the vapour pressure of liquid varies with the temperature of the liquid, it is essential to know the water temperature in the experiment to determine the vapour pressure of water.

An aqueous KNO3 solution is made using 75.1 g of KNO3 diluted to a total solution volume of 1.95 L .Calculate the molarity of the solution. (assume a density of 1.05 g/mL for the solution)
Calculate the molality of the solution.
Calculate the mass percent of the solution.

Answers

Answer:

- [tex]M=0.38M[/tex]

- [tex]\\ \% m=3.67\%[/tex]

Explanation:

Hello,

In this case, since the molar mass of potassium nitrate is 101.1 g/mol, we can compute the molarity as follows:

[tex]M=\frac{75.1g*\frac{1mol}{101.1g} }{1.95L} \\\\M=0.38M[/tex]

Moreover, as the mass percent is computed as:

[tex]\% m=\frac{m_{KNO_3}}{m_{solution}} *100\%[/tex]

Thus, by using the given density of the solution, we obtain:

[tex]\% m=\frac{75.1g}{1.95L*\frac{1000mL}{1L}*\frac{1.05g}{1mL} } *100\%\\\\ \% m=3.67\%[/tex]

Regards.

Draw two cyclic constitutional isomers of cis-1-chloro-2-methylcyclobutane with the same size ring. In cases where there is only one cyclic constitutional isomer, just draw one structure.

Answers

Answer:

The drawings are in the figure attached below.

Explanation:

"Constitutional isomers" is a term used in chemistry to refer to chemical compounds that have the same constitution and molecular formula distributed in a different structure. That is, the compound has the same atoms, but when built in a three-dimensional image, these atoms occupy different places within the same structure.

an alligator is 213.4 cm long. how long is he in feet?

Answers

Answer:

7.00ft

Explanation:

The alligator is 7.00 ft✨

Calculate the density of an object with a mass of 3.8 g, that when placed in a 10.0 mL graduated cylinder with an initial volume of 4.5 mL rises to a final volume of 8.6 mL. *

Answers

Answer : The density of an object is 0.93 g/mL

Explanation : Given,

Mass of an object = 3.8 g

Initial volume = 4.5 mL

Final volume = 8.6 mL

First we have to calculate the volume of an object.

Volume of an object = Final volume - Initial volume

Volume of an object = 8.6 mL - 4.5 mL

Volume of an object = 4.1 mL

Now we have to calculate the density of an object.

Formula used:

[tex]\text{Density}=\frac{\text{Mass of an object}}{\text{Volume of an object}}[/tex]

Now putting all the given values in this formula, we get:

[tex]\text{Density}=\frac{3.8g}{4.1mL}[/tex]

[tex]\text{Density}=0.93g/mL[/tex]

Therefore, the density of an object is 0.93 g/mL

Given the following balanced chemical reaction:
3A2+B2 2A3B
If 12 moles of Az are reacted with excess B2, how many moles of A3B will be produced?

Answers

Answer:

Explanation:

according to balance chemical equation

  3 A2 moles produced 2 moles of A3B

so 12 moles A2 will produced moles of A3B= 12*2/3=24/3= 8

therefore 12 moles of A2 produced 8 moles of A3B

A balanced chemical reaction is an equation that has the same number of stoichiometry coefficients on both sides. When 12 moles of A₂ react, then 8 moles of A₃B are produced.

What are excess reagents?

Excess reagents are the reactants that are present in more quantity than the other reactant and are left in reaction after completion.

The balanced chemical equation:

3A₂ + B₂ → 2A₃B

From reaction: 3 moles of A₂ molecule are needed to produce 2 moles of A₃B. So, 12 moles of A₂ will produce:

(12 × 2) ÷ 3 = 8 moles

Therefore, 8 moles of A₃B will be produced from 12 moles of A₂.

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Determine the density of a 23.4g block that when placed in 25.00mL of water that causes the water to rise to a level of 28.70mL?

Answers

Answer:

Explanation:

Density is the ratio of mass to volume. The SI unit of density is kg/m³. Given that the mass of the block = 23.4 g = 0.0234 kg

The volume of block = change in water level = volume of water rise after block is placed - volume of water = 28.7 ml - 25 ml = 3.7 ml

Volume of block = 3.7 ml = 0.0037 l

1000 l = 1 m³

0.0037 l = 0.0037/1000 m³ = 3.7 × 10⁻6 m³

Density = mass / volume

Density = 0.0234 kg / 3.7 × 10⁻6 m³ = 6324 kg/m³

What are the different forms of energy involved in stretching and releasing a rubber band? What other processes are similar?

Answers

Answer:

the answer is elastic potential energy to kinetic energy

Explanation:

A stretched rubber band contains potential energy (specifically called elastic potential energy because the material involved is elastic), which when released, the rubber band tries to return back to it's original shape and size. During the process of this return, the elastic potential energy is immediately converted to kinetic energy.

NOTE: Potential energy can be defined as the energy stored/present in a body at rest. It is usually as a result of the body's position or state. The potential energy stored in an elastic material is called elastic potential energy.

Kinetic energy can simply be described as the energy present in an object that is in motion.

One major process that is similar to the processes above is the mechanical energy, which is the energy involved in an object that has the ability to do work which in this case is a drawn elastic rubber that has the ability to "return" to it's initial state.

Describe the energy inputs and outputs for the campfire. Use the law of conservation of energy to construct a valid qualitative equation that includes all the input and output energies involved.

Answers

I did some fire simulation work recently where a small paper fire (think like half a ream of printer paper) was putting out 4000 watts, or about 5 horsepower. A large roaring campfire is going to be a few multiples of that depending on size, of course.

Convert 0.049 kg sulfur (S) to g of sulfur (S).

Answers

Answer:

The answer is

49 g of Sulphur

Explanation:

To convert kilograms to grams we use the conversion

1 kg = 1000 g

From the question

If 1kg = 1000 g

Then 0.049 kg = 0.049 × 1000

We have the final answer as

49 g

Hope this helps you

=====================================

A balloon has a volume of 4100 cm? What is the volume in liters?

Answers

The answer is 0.0041

A balloon has a volume of 4100 cm. The volume in liters is 4100000.

What are liters and cubic meters?

Liters and cubic meters are the measurement unit of liquid. They are used to write the value of the measurements. There are seven basic units of measurement. The values are liters, kg, meters, grams, milliliters, etc.

A liter is a measurement unit for volume in the metric system. One liter equals 0.001 cubic meters. 1 liter equals 1000 ml. Cubic meters is the SI unit of volume. It is a volume of a cube with a length of 1 cm.

To calculate the value of cubic meters. The calculation of all dimensions is done. The dimensions include length, breadth, and height. A cubic decimeter occupies a volume of 10 cm × 10 cm × 10 cm.

Thus, the volume in liters is 4100000.

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How does the strength of the bar magnet affect the current in the pickup coil?

Answers

Answer:

The induction of current increases in the coil.

Explanation:

The strength of the bar magnet affect the current in the pickup coil because the magnetic field produced by the bar magnet interfere with the field of he coil. By moving the bar magnet in and out of the coil so induction of electric current will be occurs in the soil. If a bar magnet with more strength is moving in the coil then more current will be induced inside the coil.

Several groups of students are attempting to determine the density of a lead weight by various methods. Their data is shown in
the table. A handbook lists the density of lead as 11.3 g/mL.
Group 1
Group 2
Group 3
Measured density (g/mL), trial 1
11.5
11.5
10.9
Measured density (g/mL), trial 2
11.3
11.4
11.3
Measured density (g/mL), trial 3
11.1
11.4
11.1
Average density (g/mL)
11.3
11.4
11.1
Which group was most accurate?
Which group was most precise?
O Group 2
O Group 3
O Group 1
O Group 3
O Group 2
O Group 1

Answers

Answer:

accurate: Group 1precise: Group 2

Explanation:

Accuracy is a measure of how close a measured value is to the true value. Here, we assume the handbook value (11.3) to be the true value. Group 1 arrived at this number, so must be considered to have made the most accurate measurement.

__

Usually, precision refers to the value of the least significant digit of the measurement. Here, all measurements were made to 3 significant digits, with the least digit being tenths. On that basis, no group can claim better precision than any other.

Another way to consider precision is to look at the variation in measured values. Group 2's values were the most consistent, having a range of 0.1 g/mL. Group 1's values had a range of 0.4 g/mL (from 11.1 to 11.5), and Group 3's values also ranged over 0.4 g/mL (from 10.9 to 11.3).

Because Group 2 had the most consistent readings, we award them the title of most precise.

Answer:

accurate: Group 1

precise: Group 2

Explanation:

Accuracy is a measure of how close a measured value is to the true value. Here, we assume the handbook value (11.3) to be the true value. Group 1 arrived at this number, so must be considered to have made the most accurate measurement.

7. Experimental value of acceleration due to gravity is found to be
9.842 m/s². The accepted value of acceleration due to gravity is
9.81 m/s2. What is the percent error in calculation?
a 0.326 %
b 0.316 %
C 0.981 %
d 0.613 %

Answers

Answer : The correct option is, (a) 0.326 %

Explanation :

To calculate the percentage error, we use the equation:

[tex]\%\text{ error}=\frac{|\text{ Experimental value - Accepted value}|}{\text{ Accepted value}}\times 100[/tex]

We are given:

Experimental value = 9.842 m/s²

Accepted value = 9.81 m/s²

Now put all the given values in above equation, we get:

[tex]\%\text{ error}=\frac{|9.842 m/s^2- 9.81m/s^2|}{9.81m/s^2}\times 100[/tex]

[tex]\%\text{ error}=0.326\%[/tex]

Therefore, the percent error in calculation is 0.326 %

The density of a nickel coin was determined by laboratory measurement to be 728 g/mL. A nickel has a mass of 5.040 grams. What is the volume of the nickel?
0.6923 mL
0.692 ml
оооо
36.3 mL
1.43 mL

Answers

Answer:

The answer is 0.6923 mL

Explanation:

The density of a substance can be found by using the formula

[tex]Density = \frac{mass}{volume} [/tex]

Making volume the subject we have

[tex]volume = \frac{mass}{Density} [/tex]

From the question

Density = 728 g/mL

mass of nickel = 5.040 g

Substitute the values into the above formula and solve for the volume

That's

[tex]volume = \frac{5.040}{728} \\ = 0.692307[/tex]

We have the final answer as

Volume of nickel = 0.6923 mL

Hope this helps you

Answer:

The answer would be 0.6923 mL :)

Determine what the spin state of each complex will be using the spectrochemical series along with your chemical intuition. Please explain any complexes that may be difficult to determine. You may assume any 6-coordinate complex has octahedral symmetry and any 4-coordinate complex has tetrahedral symmetry.
a. VCI3(H20)3
b. Fe(NH3)23

Answers

Answer:

A) high spin complex

B) low spin complex

Explanation:

A) VCI3(H20)3 is a high spin complex and this is because the complex has a weak field ligands all . this weak field ligands makes it impossible for pairing to take place

B) Fe(NH3)23 is a low spin complex and this is because the complex is made up of strong field ligands, this strong field ligands makes it possible for paring to take place

note : Ligands in which its donor atoms are ; Nitrogen,phosphorous or carbon are considered strong ligands

Balance the chemical equation below using the smallest possible whole number stoichiometric coefficients NH3(g) + O2(g) + CH4(g) → HCN (aq) + H2O(1)

Answers

Answer:

[tex]2NH_{3 (g)} + 3O_{2 (g)} +2CH_{4 (g)} --> 2HCN_{(aq)} + 6H_{2}O_{(l)}[/tex]

Explanation:

Heat is added to a substance, but its temperature does not rise. Which one of the following statements provides the best explanation for this observation? (a) the substance must be a gas. (b) the substance must be a non-perfect solid. (c) the substance undergoes a change of phase. (d) the substance has unusual thermal properties. (e) the substance must be cooler than its environment.

Answers

Answer:

C

Explanation:

Heat is added to a substance, but its temperature does not rise

because

(c) the substance undergoes a change of phase.

Does heat change during a phase change?

Heat, which is energy, either comes into the material during a change of phase or heat comes out of the material during this change.

What are the four-phase changes of heat?

Melting, Condensation, Vaporization & Sublimation

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In the image, balls that look alike represent the same type of atom. Based on this information, what do the images below represent? A. molecules of compounds B. molecules of elements C. molecules of mixtures D. molecules of water

Answers

Answer:

B Is The Correct Answer

In the image, balls that look alike represent the same type of atom. Based on this information, the images below represent  molecules of elements. Therefore, option B is correct.

What is an element ?

A chemical element is a species of atoms, including the pure substance made entirely of that species, that have a specific number of protons in their nuclei. Chemical elements, in contrast to chemical compounds, cannot be reduced by any chemical process into simpler molecules.

A substance that cannot be converted into another substance is said to be an element. Each type of atom that makes up an element is unique! According to atomic number, elements are listed in the periodic table.

The three categories of elements are metal, non-metal, and metalloid. Metals like sodium, calcium, caesium, and other elements on the extreme left of the periodic table are examples of this. The non-metals, such as carbon, chlorine, and oxygen, are often referred to as the elements on the right side.

Thus, option B is correct.

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How many molecules of table sugar are contained in a 2 pound bag of sugar

Answers

Answer:

1.59 × 10²⁴ molecules

Explanation:

Step 1: Convert the mass to grams

We will use the relationship 1 lb = 453.59 g.

2 lb × (453.59 g/1 lb) = 907.18 g

Step 2: Calculate the moles corresponding to 907.18 grams of sucrose (table sugar)

The molar mass of sucrose is 342.3 g/mol.

907.18 g × (1 mol/342.3 g) = 2.65 mol

Step 3: Calculate the molecules in 2.65 moles of sucrose

We will use Avogadro's number: there are 6.02 × 10²³ molecules of sucrose in 1 mole of sucrose.

2.65 mol × (6.02 × 10²³ molecules/1 mol) = 1.59 × 10²⁴ molecules

Write an equation to show how perchloric acid, HClO4, reacts with water. Include states of matter in your answer. Click in the answer box to open the symbol palette.

Answers

Answer:

HClO4(aq) + H2O(l) ⇄ H3O+(aq) + ClO4-(aq)

Explanation:

When an acid dissolves in water, it will produce hydronium ion, H3O+ as the only positive ion.

perchloric acid, HClO4, being an acid will react with water, H2O to produce hydronium ion, H3O+ as shown below:

HClO4(aq) + H2O(l) ⇄ H3O+(aq) + ClO4-(aq)

A certain chemical reaction releases 15.6/kJg of heat for each gram of reactant consumed. How can you calculate the heat produced by the consumption of 1.5kg of reactant? the math up. But don't do any of it. Just leave your answer as a math expression.

Answers

Answer:

The chemical reaction releases 23400 kilojoules due to 1.5 kg-reactant.

Explanation:

Given the amount of energy released due to reactant consumption, total energy ([tex]Q[/tex]), measured in kilojoules, is determined by the following expression:

[tex]Q = m\cdot L[/tex]

Where:

[tex]m[/tex] - Mass of reactant, measured in kilograms.

[tex]L[/tex] - Released heat ratio, measured in kilojoules per gram.

Given that [tex]m = 1500\,g[/tex] and [tex]L = 15.6\,\frac{kJ}{g}[/tex], the total energy released by chemical reaction is:

[tex]Q =(1500\,g)\cdot \left(15.6\,\frac{kJ}{g} \right)[/tex]

[tex]Q = 23400\,kJ[/tex]

The chemical reaction releases 23400 kilojoules due to 1.5 kg-reactant.

Calculate how much 95% ethyl alcohol will be required to dissolve 0.3g of sulfanilamide at 78�C. Use the values 78 deg C: 180 mg/ml and 0 deg C: 10 mg/ml

Answers

Answer:

1.67mL of 95% ethyl alcohol are required to dissolve completely the sulfanilamide

Explanation:

Solubility is defined as the amount of substance that a determined amount of solvent can dissolve

As you can see, 95% ethyl alcohol at 78°C can dissolve 180mg of sulfanilamide per mililiter. That means solubility is 180mg/mL = 0.180g/mL.

As you want to dissolve 0.3g, you require:

0.3g * (1mL / 0.180g) =

1.67mL of 95% ethyl alcohol are required to dissolve completely the sulfanilamide

Your science teacher gives you three liquids to pour into a jar. After pouring all of them into the jar, the liquids layer as seen in the image. What property of matter prevents the three liquids from mixing together?

Answers

Answer:

density

Explanation:

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