The density of toluene (C7H8) is 0.867 and that of thiophene (C4H4S) is 1.065 g/ml. A solution is made by dissolving 10.00g thiophene in 250.00ml of toluene. a)Calculate the molarity of the solution
b)Assuming the volume are addictive ,calculate the molarity of the solution
​

Answer:

Lithium is used in making electrochemical cells.

Answer:

ethyl 3-ethoxy-3-hydroxy-2-isopropyl-5-methyl hexanoate

Explanation:

In this case, we have a very strong base (sodium ethoxide). Therefore, this compound will remove a hydrogen from ethyl 3-methyl butanoate generating a carbanion.

This carbanion, can attack another ethyl 3-methyl butanoate molecule on the carbonyl group generating a new C-C bond and producing a negative charge in the oxygen.

Then the ethanol can protonate the molecule generating an "OH" group and the ethoxide.

See figure 1

I hope it helps!

Answer:

1.5g

Explanation:

Remember that Molarity = (#moles of solute)/(#liters of solution)

This problem informs us that the Molarity of the vinegar is 0.84 and that the solution is 15mL.

First let's get your SI units to the correct ones.

15mL (1L/1000mL) = 0.015L

Molarity = (#moles of solute)/(#liters of solution) ~

(Molarity)(#liters of solution) = #moles of solute

(0.84M)(.015L) = 0.0126moles of acetic acid per tablespoon

2 tablespoons a day = 0.0126moles*2 =  0.0252 moles of acetic acid.

Now that we have the # of moles of acetic acid we need to get our answer into grams. The molecular weight of HC2H3O2 is 60g/mole.

0.0252mole HC2H3O2 (60g HC2H3O2/1mole HC2H3O2) = 1.512g ~ 1.5g HC2H3O2.

Answer:

7.2 moles of titanium weigh 344.7 grams.

Explanation:

Molar mass of titanium = 47.88 g

[tex]1 \: mole \: of \: titanium = 47.88 \: grams \\ 7.2 \: moles \: of \: titanium = g[/tex]

solve for g

[tex]g = ( \frac{7.2 \times 47.88}{1} ) \\ g = 344.7 \: grams[/tex]

Answer:

[tex]\boxed {\boxed {\sf 344.7 \ g \ Ti}}[/tex]

Explanation:

We are asked to find the mass of 7.2 moles of titanium.

To convert from moles to grams, we use the molar mass. This value is the mass of 1 mole of a substance. They are equivalent to the atomic masses found on the Periodic Table, but the units are grams per moles instead of atomic mass units.

Look up titanium's molar mass on the Periodic Table.

Convert moles to grams using dimensional analysis. First, set up a ratio using the molar mass.

[tex]\frac {47.87 \ g \ Ti}{1 \ mol \ Ti}[/tex]

We are converting 7.2 moles to grams, so we multiply the ratio by this value.

[tex]7.2 \ mol \ Ti *\frac {47.87 \ g \ Ti}{1 \ mol \ Ti}[/tex]

The units of moles of titanium cancel.

[tex]7.2 *\frac {47.87 \ g \ Ti}{1 }[/tex]

The denominator of 1 can be ignored (a number over 1 is just the number).

[tex]7.2 *47.87 \ g \ Ti}[/tex]

[tex]344.664 \ g \ Ti[/tex]

We are asked to round to the nearest tenth. The 6 in the hundredth place tells us to round the 6 in the tenth place up to a 7.

[tex]344.7 \ g \ Ti[/tex]

There are approximately 344.7 grams of titanium in 7.2 moles of titanium.

Answer:

Electrical current drives nonspontaneous reactions in electrolytic cells.

Explanation:

Electrochemical cells are cells that produce electrical energy from chemical energy.

There are two types of electrochemical cells; voltaic cells and electrolytic cells.

A voltaic cell is an electrochemical cell in which electrical energy is produced from spontaneous chemical process while an electrolytic cell is an electrochemical cell where electrical energy is produced from nonspontaneous chemical processes. Current is needed to drive these nonspontaneous chemical processes in an electrolytic cell.

Answer:

electrolytic cells generate electricity through a non-spontaneous reaction while voltaic cells absorb electricity to drive a spontaneous reaction.

Explanation:

Answer via Educere/ Founder's Education

Answer:

since mass percent is based on the proportions of elements in a compound, the mass of a sample does not matter

The mass percent or percentage by mass of a chemical compound is a constant.

Mass percent can be defined as percentage by mass and it is the concentration of a given amount (quantity) of element in a chemical compound or a component of a mixture.

The mass percent or percentage by mass of a chemical compound is a constant, regardless of the amount of substance that is present. Thus, all chemical compound always have a constant composition because mass percent is typically based on the proportions of the elements contained in a chemical compound.

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Answer:

hi

Explanation:

Answer:

[tex]pH=10.45[/tex]

Explanation:

Hello,

In this case, for the dissociation of the given base, we have:

[tex]base\rightleftharpoons OH^-+CA[/tex]

Whereas CA accounts for conjugated acid and OH⁻ for the conjugated base. In such a way, equilibrium expression is:

[tex]Kb=\frac{[OH^-][CA^+]}{[base]}[/tex]

And in terms of the reaction extent [tex]x[/tex] we can write:

[tex]1.6x10^{-6}=\frac{x*x}{0.05M-x}[/tex]

For which the roots are:

[tex]x_1=-0.000284M\\x_2=0.000282M[/tex]

For which clearly the result is the positive root which also equals the concentration of hydroxyl ions and we can compute the pOH:

[tex]pOH=-log([OH^-])=-log(0.000282)\\\\pOH=3.55[/tex]

And the pH:

[tex]pH=14-pOH=14-3.55\\\\pH=10.45[/tex]

Regards.

The pH of the solution is 10.45.

Let us represent codeine with the generic formula BH. We can set up the ICE table as follows;

              :B(aq) + H2O(l) ⇄ BH(aq)  + OH^-(aq)

I            0.05                        0                0

C           -x                            +x                +x

E        0.05 - x                      x                  x

We know that the Kb of codeine is 1.6 x 10^-6, Hence;

1.6 x 10^-6 = x^2/0.05 - x

1.6 x 10^-6 (0.05 - x ) =  x^2

8 x 10^-8 - 1.6 x 10^-6x =  x^2

x^2 +  1.6 x 10^-6x - 8 x 10^-8 = 0

x = 0.00028 M

The concentration of hydroxide ions = 0.00028 M

Given that pOH = - log[0.00028 M]

pOH = 3.55

pH + pOH = 14

pH = 14 - 3.55

pH = 10.45

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Answer:

A) dietary fiber isn't used by the body.

Explanation:

The food we eat contains certain nutritional contents that provides energy, measured in calories (CAL) to the body. A procedure called BOMB CALORIMETRY can be used to determine the energy contents of these foods. The energy-supplying macromolecules contained in food substances we eat are carbohydrate, protein, fats etc.

Bomb calorimetry uses the method of burning the food substance in a device called bomb calorimeter, and measure the caloric content of the burnt food. Bomb calorimetry measures all the present calories in a food substance, which can include dietary fibers. Due to this reason, it is considered a poor choice in determining the number of nutritional calories in a food substance.

Dietary fibers are indigestible carbohydrates that cannot be broken down and used by the body. They pass along the alimentary canal until they are egested. Hence, they are no source of nutrients to the body. Since bomb calorimetry measures all calories including dietary fibers, it is said to overestimate the caloric content of food substances.

Answer:

72.8 % (But verify explanation).

Explanation:

Hello,

In this case, with the following obtained results, the percent error is computed as follows:

Volume of vinegar= 7.0 mL

Volume of NaOH= (7+6.6+6.4)/3= 6.7 mL

Used concentration of NaOH= 1.5M

Concentration of acetic acid= (concentration of NaOH*volume of NaOH)/volume of vinegar= (6.7mL*1.5M)/7.0M= 1.44M

Assuming we have 100 mL (0.100L) of vinegar, moles of acetic acid in vinegar = 1.44M x 0.100 L= 0.144 mol

Mass of acetic acid in 100g of vinegar = 0.144 mol x 60.0g/mol= 8.64 g

% of acetic acid in vinegar=8.64 %

% error in percentage of acetic acid = [(8.64% - 5.0%)/5.0] x 100=72.8 %

Clearly, this result depend on your own measurements, anyway, you can change any value wherever you need it.

Regards.

Answer:

550mL of HCOOH 0.1M and 450mL of HCOONa 0.1M

Explanation:

It is possible to find the pH of a buffer by using H-H equation:

pH = pKa + log [A⁻]/[HA]

For the formic buffer (HCOOH/HCOONa):

pH = 3.74 + log [HCOONa]/[HCOOH]

As you need a buffer of pH 3.65:

pH = 3.74 + log [HCOONa]/[HCOOH]

3.65 = 3.74 + log [HCOONa]/[HCOOH]

Where  [HCOONa]/[HCOOH] can be taken as the moles of each specie.

As molarity of both solutions is 0.10M (0.10mol / L) and you need 1L of solution, total moles of the buffer are:

Replacing (2) in (1):

0.81283 = 0.10 - [HCOOH]  /[HCOOH]

0.81283[HCOOH] = 0.10 - [HCOOH]

1.81283[HCOOH] = 0.10

And moles of HCOONa are:

[HCOONa] = 0.1 mol - 0.055mol =

As concentration of the solutions is 0.1M, the volume you need to add of both solutions is:

HCOOH = 0.055 mol ₓ (1L / 0.1mol) = 0.55L = 550mL of HCOOH 0.1M

HCOONa = 0.045 mol ₓ (1L / 0.1mol) = 0.45L = 450mL of HCOONa 0.1M

The number should be considered like 550mL of HCOOH 0.1M and 450mL of HCOONa 0.1M.

Here we used the H-H equation:

pH = pKa + log [A⁻]/[HA]

Now

For the formic buffer (HCOOH/HCOONa):

So,

pH = 3.74 + log [HCOONa]/[HCOOH]

Now

need a buffer of pH 3.65:

So,

pH = 3.74 + log [HCOONa]/[HCOOH]

3.65 = 3.74 + log [HCOONa]/[HCOOH]

0.81283 = [HCOONa]/[HCOOH] (1)

here  [HCOONa]/[HCOOH] can be considered as the moles of each specie.

Now the total moles should be

0.10 moles = [HCOONa] + [HCOOH] (2)

Now

0.81283 = 0.10 - [HCOOH]  /[HCOOH]

0.81283[HCOOH] = 0.10 - [HCOOH]

1.81283[HCOOH] = 0.10

[HCOOH] = 0.055 moles

And moles of HCOONa should be

[HCOONa] = 0.1 mol - 0.055mol =

[HCOONa] = 0.045 moles

Now

HCOOH = 0.055 mol ₓ (1L / 0.1mol) = 0.55L = 550mL of HCOOH 0.1M

HCOONa = 0.045 mol ₓ (1L / 0.1mol) = 0.45L = 450mL of HCOONa 0.1M

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Answer:

Heat of vaporization refers to condensation and heat of fusion refers to melting.

Explanation:

Heat of vaporization or heat of evaporation, is defined as the energy required to convert liquid substance into a gas which creates condensation. As a gas condenses to a liquid, heat is released.

Heat of fusion refers to melting because heat of fusion is defined as the energy required to change any amount of substance when it melts.

Hence, the correct answer is "Heat of vaporization refers to condensation and heat of fusion refers to melting.".

Answer:

A process that involves rearrangement

Explanation:

A chemical reaction is the process that involves rearrangement of the molecular or ironic structure of a substance, as a distinct from a change in physical form or a nuclear reaction.

Answer:

Explanation:

Chemistry

The chemical reaction H2(g) + ½ O2(g) → H2O(l) describes the formation of water from its elements.

The reaction between iron and sulfur to form iron(II) sulfide is another chemical reaction, represented by the chemical equation:

8 Fe + S8 → 8 FeS

Answer:

ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 )

Explanation:

Isomers are compounds that have the same molecular formula but different structural formulas. Hence any pair of compounds that can be represented by exactly the same molecular formula are isomers of each other.

If we look at the pair of compounds; ethanolamine ( H2N-CH2-CH2-OH ) and acetamide ( CH3-CO-NH2 ), one compound has molecular formula, C2H7ON while the other has a molecular formula, C2H5ON, hence they are not isomers of each other.

Answer:

anilinium ion > ammonium ion > amide > aniline > secondary amine

Explanation:

Acidity of amine derivatives can derived from their pKa values.

The rule of thumb for acidity with relation to pKa values is that:

As the pKa decreases the acid strength increases and the conjugate base decreases. Similarly, as the pKa increases, the acid strength decreases and the conjugate base increase.

Hence the stronger the acid , the  lower pKa value  and the weaker the acid , the stronger the pKa value.

So the pKa value for anilinium ion = 4.6

ammonium ion = 9.4

Amide = 15

Similarly, for aniline and secondary amine, in order to determine the derivative with the higher acidity, we will consider the electron withdrawing substituent group.

The more difficult the electron are being withdraw from the electron withdrawing substituent , the more acidic the compound.

In aniline , the stabilized benzene ring attached to NH₂ makes it a less electron withdrawing group compared to the straight chains structure found in secondary amine where electron are easily withdraw by nucleophilic substitution reactions.

Thus, from highest acidity (lowest pKa value) to lowest acidity (highest pKa value).

the amine derivatives ranking is as follows:

anilinium ion > ammonium ion > amide > aniline > secondary amine

Answer:

[tex]pH=2.28[/tex]

Explanation:

Hello,

In this case, for the acid dissociation of formic acid (HCOOH) we have:

[tex]HCOOH(aq)\rightarrow H^+(aq)+HCOO^-(aq)[/tex]

Whose equilibrium expression is:

[tex]Ka=\frac{[H^+][HCOO^-]}{[HCOOH]}[/tex]

That in terms of the reaction extent is:

[tex]1.8x10^{-4}=\frac{x*x}{0.16-x}[/tex]

Thus, solving for [tex]x[/tex] which is also equal to the concentration of hydrogen ions we obtain:

[tex]x=0.00528M[/tex]

[tex][H^+]=0.00528M[/tex]

Then, as the pH is computed as:

[tex]pH=-log([H^+])[/tex]

The pH turns out:

[tex]pH=-log(0.00528M)\\\\pH=2.28[/tex]

Regards.

Answer:

HClO 7.54

Explanation:

Hypochlorous acid (HClO) is a weakest acid because the pKa value of Hypochlorous acid is very high among the options given in the activity. pKa is a method which is used in order to identify the strength of an acid. The higher the value of pKa of a liquid, lower the strength of an acid while lower the value of pKa of chemical, higher the strength of an acid. In the options, HClO2  is a strong acid due to high lower pKa value.

Answer:

Oxidation half equation;

3Cd(s) -------> 3Cd^2+(aq) + 6e

Reduction half equation;

2In^3+(aq) + 6e -----> 2In(s)

Explanation:

Since the reduction potentials of Indium and Cadmium are -0.34 V and - 0.40 V respectively, we can see that cadmium will be oxidized while indium will the reduced.

We arrived at this conclusion by examining the reduction potential of both species. The specie with more negative reduction potential is oxidized in the process.

Oxidation half equation;

3Cd(s) -------> 3Cd^2+(aq) + 6e

Reduction half equation;

2In^3+(aq) + 6e -----> 2In(s)

Answer:

That involve the complete transfer of an electron from one atom of an element to another

Answer:

89%.

Explanation:

We'll begin by writing the balanced equation for the reaction. This is given below:

2Li + 2H2O —> 2LiOH + H2

Next, we shall determine the masses of Li and H2O that reacted and the mass of LiOH produced from the balanced equation.

This is illustrated below:

Molar mass of Li = 7 g/mol

Mass of Li from the balanced equation = 2 x 7 = 14 g

Molar mass of H2O = (2x1) + 16 = 18 g/mol

Mass of H2O from the balanced equation = 2 x 18 = 36 g

Molar mass of LiOH = 7 + 16 + 1 = 24 g/mol

Mass of LiOH from the balanced equation = 2 x 24 = 48 g

Summary:

From the balanced equation above,

14 g of Li reacted with 36 g of H2O to produce 48 g of LiOH.

Next, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

14 g of Li reacted with 36 g of H2O.

Therefore, 7.4 g of Li will react with = (7.4 x 36)/14 = 19.03 g of H2O.

From the calculation made above, we can see that it will take a higher amount i.e 19.03 g than what was given i.e 10.2 g of H2O to react completely with 7.4 g of Li.

Therefore, H2O is the limiting reactant and Li is the excess reactant.

Next, we shall determine the theoretical yield of LiOH.

In this case we shall use the limiting reactant.

The limiting reactant is H2O and the theoretical yield of LiOH can be obtained as follow:

From the balanced equation above,

36 g of H2O reacted to produce 48 g of LiOH.

Therefore, 10.2 g of H2O will react to produce = (10.2 x 48)/36 = 13.6 g of LiOH.

Therefore, the theoretical yield of LiOH is 13.6 g

Finally, we shall determine the percentage yield of LiOH. This can be obtained as follow:

Actual yield = 12.1 g

Theoretical yield = 13.6 g

Percentage yield =..?

Percentage yield = Actual yield /Theoretical yield x 100

Percentage yield = 12.1/ 13.6 x 100

Percentage yield = 89%

Therefore, the percentage yield LiOH is 89%.

Answer:

See explanation

Explanation:

First voltaic cell;

Zn(s)|Zn^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Zinc

Cathode;

Copper

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Zn(s) + Cu^2+(aq) -----> Zn^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.76) =1.1 V

Second voltaic cell;

Zn(s)|Zn^2+(aq)||Fe^2+(aq)|Fe(s)

Anode;

Zinc

Cathode;

Iron

Oxidation half equation;

Zn(s)------> Zn^2+(aq) + 2e

Reduction half equation;

Fe^2+(aq) +2e -----> Fe(s)

Overall; Zn(s) + Fe^2+(aq) -----> Zn^2+(aq) + Fe(s)

E°cell = (-0.44) -(-0.76) = 0.32 V

Third voltaic cell;

Fe(s)|Fe^2+(aq)||Cu^2+(aq)|Cu(s)

Anode;

Iron

Cathode;

Copper

Oxidation half equation;

Fe(s)------> Fe^2+(aq) + 2e

Reduction half equation;

Cu^2+(aq) +2e -----> Cu(s)

Overall; Fe(s) + Cu^2+(aq) -----> Fe^2+(aq) + Cu(s)

E°cell = 0.34 -(-0.44) = 0.78 V

Fourth voltaic cell

Cu(s)|Cu^2+(aq)||I2(aq)|C(s)|I^-(aq)

Anode;

Copper

Cathode;

Graphite rod

Oxidation half equation;

Cu(s)------> Cu^2+(aq) + 2e

Reduction half equation;

I2(aq) +2e -----> 2I^-(aq)

Overall; Cu(s) + I2(aq) -----> Cu^2+(aq) + 2I^-(aq)

E°cell = 0.54 -0.34 = 0.20 V

Answer:

The answer is the photo attached

Explanation:

Answer:

Due to the resonance structures

Explanation:

In the question:

"Explain why, when the guanidino group of arginine is protonated, the double-bonded nitrogen is the nitrogen that accepts the proton. There is a scheme of a reversible reaction, where one equivalent of the reactant reacts with two equivalents of H plus"

We have to take into account the structure of the amino acid arginine. In which, we have the amino and the carboxylic groups in the right and the guanidine group in the left.

In this group, we have a central carbon with three nitrogen atoms around and a double bond with the nitrogen on the top. This nitrogen on the top will accept the proton because the structure produced will have a positive charge on this nitrogen. Then, the double bond with the carbon can be delocalized into the nitrogen producing a positive charge in the carbon.

In this structure (the carbocation), we can have several resonance structures. In the blue option, we can produce a double bond with the nitrogen on the right. In the purple option, we can produce a double bond with the nitrogen on the left.

In conclusion, if the nitrogen in the top on the guanidine group accepts an hydrogen atom and we will have several resonance structures that can stabilize the molecule. Due to this, the nitrogen in the top its the best option to accept hydrogens.

See figure 1

I hope it helps!

Answer:

The amount of moles of gaseous boron trifluoride, BF₃, contained in a 4.3421 L bulb at 787.9 K if the pressure is 1,218 atm is 0.082 moles

Explanation:

An ideal gas is a theoretical gas that is considered to be made up of point particles that move randomly and do not interact with each other. Gases in general are ideal when they are at high temperatures and low pressures.

The pressure, P, the temperature, T, and the volume, V, of an ideal gas, are related by a simple formula called the ideal gas law:  

P*V = n*R*T

where P is the gas pressure, V is the volume that occupies, T is its temperature, R is the ideal gas constant, and n is the number of moles of the gas.

In this case:

Replacing:

1.218 atm* 4.3421 L= n*0.082 [tex]\frac{atm*L}{mol*K}[/tex] *787.9 K

Solving:

[tex]n=\frac{1.218 atm* 4.3421 L}{0.082 \frac{atm*L}{mol*K}*787.9 K}[/tex]

n= 0.082 moles

The amount of moles of gaseous boron trifluoride, BF₃, contained in a 4.3421 L bulb at 787.9 K if the pressure is 1,218 atm is 0.082 moles

Answer:

A double bond is formed when two pairs of electrons are shared between the two participating atoms. It is represented by two dashes (=). It is represented by two dashes (=). Double covalent bonds are much stronger than a single bond, but they are less stable

Explanation:

The amount, in grams, of Al that reacted with excess HCl if 3.86 L of hydrogen gas were collected at STP in the reaction would be 3.099 grams.

From the equation of the reaction, the mole ratio of Al that reacts with that of hydrogen gas that forms is 2:3.

At STP, 1 mole of any gas is equivalent to 22.4 Liters of the gas.

But only 3.86 L of hydrogen was formed in the reaction.

The equivalent mole of 3.86 L hydrogen at STP would be:

      3.86 x 1/22.4 = 0.1723 moles

From the mole ratio, the equivalent mole of Al that will produce 0.1723 moles of hydrogen gas would be:

          0.1723 x 2/3 = 0.1149 moles

Recall that: mass = mole x molar mass

Mass of 0.1149 moles Al = 0.1149 x 26.98

                                        = 3.099 grams

Thus, the amount of Al that reacted with excess HCl is 3.099 grams.

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Answer:

0.44

Explanation:

We know that the pH of any acid solution is given by the negative logarithm of its hydrogen ion concentration. Hence, if I can obtain the hydrogen ion concentration of any acid, I can obtain its pH.

For the acid, HNO3, [H^+] = [NO3^-]= 0.36 M

pH= -log [H^+]

pH= - log[0.36]

pH= 0.44

A general exponential expression is something like:

A^n

This means that we need to multiply the number A by itself n times.

Using that we will get (-2)^6 = 64

With that definition, we can rewrite:

(-2)^6 = (-2)*(-2)*(-2)*(-2)*(-2)*(-2)

So we just need to solve the above expression.

Also, remember the rule of signs:

(-)*(-) = (+)

We will get:

(-2)*(-2)*(-2)*(-2)*(-2)*(-2) =  [(-2)*(-2)]*[(-2)*(-2)]*[(-2)*(-2)]

                                        =  4*4*4 = 16*4 = 64

Then we got:

(-2)^6 = 64

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Answer:

The answer it's A. transesterification