Wine goes bad soon after opening because the ethanol dissolved in it reacts with oxygen gas to form water and aqueous acetic acid , the main ingredient in vinegar. Calculate the moles of oxygen needed to produce of acetic acid. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.

Answer:

Choice A. [tex]\rm H_{2}[/tex] would be produced at the negative electrode.

Explanation:

Ionic equation for this reaction:

[tex]2\, {\rm K^{+}} + 2\, {\rm Cl^{-}} + {2\, \rm H_{2} O} \to {\rm H_{2}} + {\rm Cl_{2}} + 2\, {\rm K^{+}} + {\rm 2\, OH^{-}}[/tex].

Net ionic equation:

[tex]2\, {\rm Cl^{-}} + 2\, \rm H_{2} O} \to {\rm H_{2}} + {\rm Cl_{2}} + 2\, {\rm OH^{-}}[/tex].

Half-equations:

[tex]2\, {\rm Cl^{-}} \to {\rm Cl_{2}} + 2\, {e^{-}}[/tex].

(Electrons travel from the solution to an electrode.)

[tex]2\, {\rm \overset{+1}{H}_{2} O} + 2\, {e^{-}} \to \overset{0}{\rm H}_{2} + 2\, {\rm O\overset{+1}{H}\!^{-}}[/tex].

(An electrode supply electrons to the solution to reduce some of the [tex]\rm H[/tex] atoms from [tex]\rm H_{2}O[/tex].)

In a DC circuit, electrons always enter the circuit from the negative terminal of the power supply and return to the power supply at the positive terminal.

The negative electrode is connected to the negative terminal of the power supply. Electrons from the power supply would flow into the solution through this electrode.  

This continuous supply of electrons at the negative electrode would drive a reduction half-reaction. In this question, that corresponds to the reduction of water: [tex]2\, {\rm \overset{+1}{H}_{2} O} + 2\, {\rm e^{-}} \to \overset{0}{\rm H}_{2} + 2\, {\rm O\overset{+1}{H}\!^{-}}[/tex]. Hence, [tex]\rm H_{2}[/tex] would be produced at the negative electrode.

Answer:

pH of solution B is 5

Explanation:

A weak acid, HA, is in equilibrium with water as follows:

HA(aq) + H₂O(l) ⇄ A⁻(aq) + H₃O⁺(aq)

Where Ka (10^-pKa = 1x10⁻⁹) is:

Ka = 1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

Where concentrations of this species are equilibrium concentrations

As initial concentration of HA is 0.1M, the equilibrium concentrations of the species are:

[HA] = 0.1M - X

[A⁻] = X

[H₃O⁺] = X

Where X is the amount of HA that reacts until reach the equilibrium, X is reaction coordinate.

Replacing in Ka expression:

1x10⁻⁹ = [A⁻] [H₃O⁺] / [HA]

1x10⁻⁹ = [X] [X] / [0.1 - X]

1x10⁻¹⁰ - 1x10⁻⁹X = X²

1x10⁻¹⁰ - 1x10⁻⁹X - X² = 0

Solving for X:

X = -0.00001 → False solution, there is no negative concentrations.

X = 1x10⁻⁵ → Right solution.

As [H₃O⁺] = X

[H₃O⁺] = 1x10⁻⁵M

And pH = -log[H₃O⁺]

pH = 5

Answer:

c

Explanation:

How many moles of gold are equivalent to 1.204 × 1024 atoms?

0.2

0.5

2

5

C) 2 Is the correct answer, I took the test and it was correct.

According to the concept of Avogadro's number, there are 2 moles of gold which are equivalent to 1.204×10²⁴ atoms.

Avogadro's number is defined as a proportionality factor which relates number of constituent particles with the amount of substance which is present in the sample.

It has a SI unit of reciprocal mole whose numeric value is expressed in reciprocal mole which is a dimensionless number and is called as Avogadro's constant.It relates the volume of a substance with it's average volume occupied by one of it's particles .

According to the definitions, Avogadro's number depend on determined value of mass of one atom of those elements.It bridges the gap between macroscopic and microscopic world by relating amount of substance with number of particles.

Number of atoms can be calculated using Avogadro's number as follows: mass/molar mass×Avogadro's number.Number of moles=number of atoms/Avogadro's number=1.204×10²⁴ /6.023×10²³=1.999≅2

Thus, there are 2 moles of gold which are equivalent to 1.204×10²⁴ atoms.

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Answer:

zero

Explanation:

In a unit cell, an atom that is located at the center of a cube edge is not involved in sharing unit cells because a central atom of a unit cell belongs to the entire cell and only to that unit cell of the lattice.

Hence, the center atom of a unit cell do not share any unit cell and the correct answer is "Zero".

Answer:

1000ml=1l

35ml. = ?

Explanation:

35×1/1000

0.035litres

Answer:

B. 1-amino-2-methylpentan-2-ol

Explanation:

In this case, the first step, we have the attack of the nucleophile cyanide ([tex] CN^-[/tex] produced by sodium cyanide to the carbon on the carbonyl group (C=O) producing a negative charge in the oxygen.

Then HCl protonates the molecule to produce a cyanohydrin. This cyanohydrin can be reduced by the action of hydrogen gas ([tex]H_2[/tex]) in the presence of a catalyst ([tex]Pd[/tex]), producing an amino group. With this in mind, the final molecule is: 1-amino-2-methylpentan-2-ol.

See figure 1 to further explanations

I hope it helps!

Answer:

B) geminal diol

Explanation:

Hello,

In this case, considering the attached picture, you can see that the substance resulting from the hydrolysis of an aldehyde or a ketone is a geminal diol since the two hydroxyl groups are in the same carbon. Such hydrolysis could be carried out in either acidic or basic conditions depending upon the equilibrium constant.

Regards.

Answer:

C. Aluminum Nitrate (Al(NO3)3)

Explanation:

This is because, when Aluminium nitrate dissolves in water, it dissociates to form four ions ( one aluminium ion and three nitrate ions ). Since colligative property depends on number of particles or ions present ( roult's law ), this will create much effect.

[tex]Al(NO _{3} )_{3(aq)} → Al {}^{3 + } _{(aq)} + 3NO {}^{ - } _{(aq)}[/tex]

Answer:

aluminum nitrate (Al(NO3)3)

it has the greatest effect on collimation properties .

Explanation:

(c) is correct option

Answer:

pH = 8.72

Explanation:

This is like a titration of a weak acid and a strong base, in this case, we are at the equivalence point plus we have the same mmoles of acid and base. We have completely neutralized the acid.

CH₃COOH      +     OH⁻        ⇄    CH₃COO⁻   +   H₂O

0.1M . 15 mL      0.1M . 15 mL

We only have (0.1M . 15 mL) mmoles of acetate ion. → 1.5 mmoles

As this compound acts like a base, we propose this equilibrium:

CH₃COO⁻   +  H₂O  ⇄  CH₃COOH      +     OH⁻   Kb

We need to work with Kb and we know, that Kw = Ka. Kb so, Kb = Kw/Ka

Kb = 1×10⁻¹⁴ /1×10 ⁻⁵ = 5.55×10⁻¹⁰

Concentration of CH₃COO⁻ → 1.5 mmol / 30mL (volumes of the solutions are additive) = 0.05M

So: [CH₃COOH] . [OH⁻] / [CH₃COO⁻] = Kb

x²/ 0.05-x = 5.55×10⁻¹⁰

We can avoid the quadractic equation because Kb is so small

[OH⁻] = √(5.55×10⁻¹⁰ . 0.05) = 5.27×10⁻⁶

pOH = - log [OH⁻]  → 5.28

pH = 14 - pOH = 8.72

The pH of a solution made by mixing 15.00 mL of 0.10 M acetic acid should be 8.72.

Since the following equation should be used.

CH₃COOH      +     OH⁻        ⇄    CH₃COO⁻   +   H₂O

0.1M . 15 mL      0.1M . 15 mL

Now

(0.1M . 15 mL) mmoles of acetate ion. → 1.5 mmoles

So,

CH₃COO⁻   +  H₂O  ⇄  CH₃COOH      +     OH⁻   Kb

Now

Kw = Ka. Kb

Kb = Kw/Ka

And,

Kb = 1×10⁻¹⁴ /1×10 ⁻⁵

= 5.55×10⁻¹⁰

Now

[CH₃COOH] . [OH⁻] / [CH₃COO⁻] = Kb

x²/ 0.05-x = 5.55×10⁻¹⁰

Now

[OH⁻] = √(5.55×10⁻¹⁰ . 0.05) = 5.27×10⁻⁶

pOH = - log [OH⁻]  → 5.28

pH = 14 - pOH

= 8.72

Hence, The pH of a solution made by mixing 15.00 mL of 0.10 M acetic acid should be 8.72.

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Answer: 32 electrons

Explanation:

Answer:

[tex]m_{H_3PO_4}=31.5gH_3PO_4[/tex]

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

[tex]P_2O_5(s)+3H_2O(l)\rightarrow 2H_3PO_4(aq)[/tex]

Thus, since the diphosphorus pentoxide to water molar ratio is 1:3 and we are given the mass of both of them, for the calculation of the maximum mass phosphoric acid that is yielded, one could first identify the limiting reactant, for which we compute the available moles of diphosphorus pentoxide (molar mass 142 g/mol):

[tex]n_{P_2O_5}=22.8gP_2O_5*\frac{1molP_2O_5}{142gP_2O_5}=0.161molP_2O_5[/tex]

And the moles of diphosphorus pentoxide that are consumed by 13.5 g of water (molar mass 18 g/mol):

[tex]n_{P_2O_5}^{consumed}=13.5gH_2O*\frac{1molH_2O}{18gH_2O}*\frac{1molP_2O_5}{3molH_2O} =0.25molP_2O_5[/tex]

Hence, since less moles of diphosphorus pentoxide are available, we sum up it is the limiting reactant, therefore, the maximum mass of phosphoric acid (molar mass 98 g/mol) is computed by considering the 1:2 molar ratio between them as follows:

[tex]m_{H_3PO_4}=0.161molP_2O_5*\frac{2molH_3PO_4}{1molP_2O_5} *\frac{98gH_3PO_4}{1molH_3PO_4} \\\\m_{H_3PO_4}=31.5gH_3PO_4[/tex]

Regards.

Answer:

D. Pure gold

Explanation:

Hello,

In this case, since gold, as a heavy metal, is said to be less reactive than hydrogen, when it undergoes electrolysis process when forming a salt, due to the action of the electric current, we can appreciate the formation of a layer of gold on the surface of the cathode via a reduction half-reaction from gold (I) to metallic gold:

[tex]Au^++1e^-\rightarrow Au^0[/tex]

Thereby, D. Pure gold is formed as the product of the reaction.

In contrast, more reactive metals than hydrogen such as sodium or potassium, will remain in solution so the hydrogen converted to hydrogen gas.

Best regards-

Answer:

Neutral

Explanation:

pKa of acid = -log Ka

                   = -log (1.8 x 10^-5)

                  = 4.74

pKb of base = -log Kb

                      = 4.74

pKa of acid = pKb of base

salt pH formula   : pH = 7 + 1/2 [pKa -pKb ]

here pKa = pKb

so pH = 7

the salt it is CH3COONH4 exactly neutral solution .

If a salt is formed by combining NH₃ (Kb=1.8×10⁻⁵) and CH₃COOH (Ka=1.8×10⁻⁵), an aqueous solution of this salt would be neutral.

pH of any solution tells about the acidity or basicity or neutral nature of the solution.

pH of any solution is directly proportional to the acid dissociation constant value (Ka) and base dissociation constant (Kb). In the question it is given that,

Value of Kb for NH₃ = 1.8×10⁻⁵

Value of Ka for CH₃COOH =  1.8×10⁻⁵

Ka & Kb values for the base and acid is same means it dissociates with same extent. So the aqueous solution of this acid and base is a neutral in nature as they have same number of acid and base ions in it.

Hence resultant solution will be a neutral solution .

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Answer:

1.05 V

Explanation:

Since;

E°cell= E°cathode- E°anode

E°cathode= -0.40 V

E°anode= -1.45 V

E°cell= -0.40-(-1.45) = 1.05 V

Equation of the process;

2Zr(s) + 4Cd^2+(aq) ---->2Zr^4+(aq) + 4Cd(s)

n= 8 electrons transferred

From Nernst's equation;

Ecell = E°cell - 0.0592/n log Q

Ecell= E°cell - 0.0592/8 log [0.5]/[0.5]

Since log 1=0

Ecell= E°cell= 1.05 V

Answer:

After 47.9 days, will remain 14.5mg of the isotope

Explanation:

The radioactive decay follows always first-order kinetics where its general law is:  

Ln[A] = -Kt + ln[A]₀

Where [A] is actual concentration of the atom, k is rate constant, t is time and [A]₀ is initial concentration.

We can find rate constant from half-life as follows:

[tex]t_{1/2} = \frac{ln2}{K}[/tex]

K = ln 2 / 27.7 days

K = 0.025 days⁻¹

Replacing, initial amount of isotope is 48.0mg = [A]₀ , K is 0.025 days⁻¹ and t = 47.9 days:

Ln[A] = -Kt + ln[A]₀

Ln[A] = -0.025 days⁻¹*47.9 days + ln (48.0mg)

ln [A] = 2.6726

[A] = e^ (2.6726)

[A] = 14.5mg

Explanation:

b. Bromo cyclopentane + HBr

Answer:

Following are the solution to this equation:

Explanation:

In the given-question, an attachment file of the choices was missing, which can be attached in the question and its solution can be defined as follows:

In the given question "Option (iii)" is correct, which is defined in the attachment file.

When 2,2,3-trimethylcyclohexanone reacts with hydroxylamine it will produce the 2,2,3-trimethylcyclohexanoxime.

Answer:

Boiling

Explanation:

When a liquid is heated, the vapor pressure rises steadily. When water attains a temperature of 100°C or 212°F its vapor pressure is now equal to the atmospheric pressure at sea level, this is what we mean by boiling.

When this occurs, water continues to evaporate untill the vapor pressure inside the bubbles becomes high enough to stop water bubbles from collapsing again from the pressure of the water around it so the bubbles rise and break the surface.

Answer:

d. carboxyl

Explanation:

The presence of carbonyl group (>C=O)) and a hydroxyl group ( (−OH) on the same carbon atom is called a "carboxyl" group. A carboxyl group is represented as COOH and acts as the functional group part of carboxylic acids.

For example:

Hence, the correct option is "d. carboxyl ".

Answer:

The answer is

Explanation:

1 mole of acid.

Hope this helps....

Have a nice day!!!!

A buffer that is 1 M in acid and base will have the greatest capacity of buffer, and therefore the greatest buffer capacity.

A weak acid and the conjugate base of the weak acid, or a weak base and the conjugate acid of the weak base, are combined to form the buffer solution, a water-based solvent solution.

In a biological system, a buffer's keep intracellular and extracellular pH levels within a relatively small range and to withstand pH fluctuations brought on by both internal and external factors.

A buffer is a substance that can withstand a pH shift when acidic or basic substances are added. It may balance out little quantities of additional acid or base, keeping the pH stable.

Thus, 1 M in acid and base solution has the greatest buffer capacity.

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Answer:

The correct option is (c)

Answer:

the law of conservation of mass

Answer:

3.0x10⁻²M

Explanation:

Silver sulfate, Ag₂SO₄, has a product constant solubility equilbrium of:

Ag₂SO₄(s) ⇄ 2Ag⁺ + SO₄²⁻

When an excess of silver sulfate is added, some Ag₂SO₄ will react producing Ag⁺ and SO₄²⁻ until reach the equilbrium determined for the formula:

ksp = 1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

Assuming the Ag₂SO₄ that react until reach equilibrium is X, we can replace in Ksp expression:

1.4x10⁻⁵ = [Ag⁺]² [SO₄²⁻]

1.4x10⁻⁵ = [2X]² [X]

1.4x10⁻⁵ = 4X³

3.5x10⁻⁶ = X³

0.015 = X

As [Ag⁺] is 2X:

[Ag⁺] = 0.030 = 3.0x10⁻²M

The answer is:

Answer:

quartz

Explanation:

The correct option would be quartz.

Allotropy is a phenomenon that describes the natural existence of the same element in different forms with different physical characteristics. Allotropes are therefore different forms of the same element.

Carbon as an element has several allotropes which include diamond, graphite, graphene, amorphous carbon, and fullerenes. Quartz is a crystalline solid that is composed of silicon dioxide and not carbon.

Hence, all the options are carbon allotropes except quartz.

Answer:

Ammonium nitrate is a chemical compound with the chemical formula NH₄NO₃. It is a white crystalline solid consisting of ions of ammonium and nitrate.

Answer: 8 for both

Explanation:

Answer:

c) will never be spontaneous at any pressure.

Explanation:

Hello,

In this case, we need to remember that the second law of thermodynamics states that heat flow is transferred from a hot object to a cold object only, never the other way around, therefore, the answer is c) will never be spontaneous at any pressure. This is supported by driving force that in this case is the temperature difference which must be negative for the hot object (it gets eventually cold) and positive for the cold object (it gets eventually hot) until they reach the equilibrium temperature.

Best regards.

Explanation:

An atom undergoes alpha decay by losing a helium atom.

So when bismuth undergoes alpha decay, we have;

²¹⁰₈₃Bi --> ⁴₂He + X

Mass number;

210 = 4 + x

x = 206

Atomic number;

83 = 2 + x

x = 81

The element is Thallium. The symbol is Ti.

For the second part;

X --> ⁴₂He + ²³⁴₉₀Th

Mass number;

x = 4 + 234 = 238

Atomic Number;

x = 2 + 90 = 92

The balanced nuclear equation is;

²³⁸₉₂U --> ⁴₂He + ²³⁴₉₀Th

To record the melting point of tetradecanol, it is important the temperature is increase by little degrees after each trial.

The thermometer attached to the capillary tube was immersed in water without thermometer.

Usually heating curve describes the temperature change for a sample which passes through different states of matter.

The temperature than decreases and the solution in beaker cools down. To determine the melting point, it is important to keep the temperature consistent.

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