A sample of 0.562 g of carbon is burned in oxygen in a bomb calorimeter, producing carbon dioxide. Assume both the reactants and products are under standard state conditions, and that the heat released is directly proportional to the enthalpy of combustion of graphite. The temperature of the calorimeter increases from 26.74 °C to 27.93 °C. What is the heat capacity of the calorimeter and its contents?

Answers

Answer 1

Answer:

The correct answer is 15.54 kJ per degree C.

Explanation:

The enthalpy change for one mole of a substance, which combines or burns with the oxygen under the standard conditions, that is, at 25 degree C and 1 bar pressure is known as the standard molar enthalpy of combustion. The amount of heat transferred can be calculated by using the formula, q = mcΔT -------------(i)

Here q is the amount of heat transferred, c is the specific heat, ΔT is the change in temperature, and m is the mass of the substance. As in case of bomb calorimeter, mass if considered constant, thus, for calorimeter the equation mentioned will become, q = cΔT ---- (ii)

The standard molar enthalpy of combustion for carbon is -393.5 kJ/mol, that is, -393.5 kJ per mole of heat is generated by burning one mole of carbon. The molecular mass of carbon is 12 gram per mole.  

Thus, the number of moles of carbon equivalent to 0.562 grams of carbon can be determined as,  

Number of moles of carbon = mass / molecular mas

= 0.562 grams / 12 gram per mole

= 0.047 mol

The heat generated by burning 0.562 grams or 0.047 mole will be,  

q = ΔH° × number of moles

= (-393.51 kJ/mol) × 0.047 mol

= -18.49 kJ, the negative sign shows that the heat is produced.  

To find heat capacity of calorimeter, put the value of q as -18.49 kJ, for ΔT as (27.93 °C - 26.74 °C) in the equation (ii)

18.49 kJ = c × (27.93 - 26.74)

c = 18.49 kJ/1.19 °C

c = 15.54 kJ/°C


Related Questions

HELP URGENT PLS!1!! In what direction and how many spaces must you move the decimal point to make the following conversion?

600 L to mL


left; 6 spaces
left; 6 spaces

left; 3 spaces
left; 3 spaces

right; 6 spaces
right; 6 spaces

right; 3 spaces

Answers

To convert from L to ml, we move three spaces to the right and the decimal place moves three places.

Our task here is to convert 600 L to mL. we have to remember that to convert from L to ml, we have to multiply the value in L by 1000

In other words, the value 1000 is known as the conversion factor.

When we do this, we move the decimal place three places to the right to have 600000.00mL

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7.95x10 converted to the number is

Answers

7.95 × 10

= 79.5

This is the answer

In a reversible reaction, the endothermic reaction absorbs ____________ the exothermic reaction releases.
A. None of these, endothermic reactions release energy
B. more energy than
C. the same amount of energy as
D. less energy than

Answers

Answer:

C. the same amount of energy as

Explanation:

Firstly, a chemical reaction can either absorb energy from its surroundings to occur or release energy into its surroundings as a product. The former and latter descriptions are called ENDOTHERMIC and EXOTHERMIC reactions respectively. An exothermic reaction is that which transfers energy, in form of heat, to its surroundings while an Endothermic reaction is that which absorbs energy (heat) from its surroundings.

However, a reversible reaction is that reaction in which the formation of products from reactants and reformation of the reactants from products occur simultaneously. Hence, the products of a reversible reaction can become the reactants and move in the opposite direction. For example:

Reversible reaction: A + B ⇆ C + D means;

A + B → C + D and;

C + D → A + B

In a case whereby the opposite reactions consist of an endothermic and exothermic reactions, the endothermic reaction absorbs the same amount of energy as the exothermic reaction releases.

According to the law of conservation of energy, no energy is lost during a reversible reaction. Hence, in order to achieve an equilibrium, the amount of energy absorbed by the endothermic reaction is the same as the amount of energy released in the opposite exothermic reaction.

What orbits around the nucleus

Answers

Answer:

Electrons orbit the nucleus.

Answer:

electrons

Explanation:Atoms are made up of protons and neutrons located within the nucleus, with electrons in orbitals surrounding the nucleus.

Answer in the correct significant figures: 35.6 + 56.27 *

Answers

Answer:

101.87

Explanation:

that's the answer

Can someone plz help me :<

Answers

Answer: cats r alliens because they r kind of like ufos they would usually wonder around rather u know it or not when they spy on us it could b with us sleep cooking anything so they r like aliens

Explanation:

Which of the following pairs of compounds have the same empirical formula?

a. acetylene, C2H2, and benzene, C6H6

b. ethane, C2H6, and butane, C4H10

c. nitrogen dioxide, NO2, and dinitrogen tetroxide, N2O4

d. diphenyl ether, C12H10O, and phenol, C6H5OH

Answers

Answer:

option a and c both are correct

Explanation:

please mark me as brainliest

The pairs of compounds have the same empirical formula are:

a. acetylene, C₂H₂, and benzene, C₆H₆ and

c .nitrogen dioxide, NO₂, and di nitrogen tetroxide, N₂O₄

What is empirical formula?

The empirical formula of a compound is defined as the formula that shows the ratio of elements present in the compound, but not the actual numbers of atoms found in the molecule.

In some cases, the empirical formula is the same as the molecular formula, which gives the actual number of atoms in a compound (e.g., H₂O).Otherwise, the molecular formula is a multiple of the empirical formula (e.g., CH₂O is the empirical formula for glucose, C₆H₁₂O₆).

Examples of empirical formulas:

Glucose has a molecular formula of C₆H₁₂O₆. It contains 2 moles of hydrogen for every mole of carbon and oxygen. The empirical formula for glucose is CH₂O.

The molecular formula of ribose is C₅H₁₀O₅, which can be reduced to the empirical formula CH₂O.

The pair with empirical formula is  acetylene, C₂H₂, and benzene, C₆H₆ and

nitrogen dioxide, NO₂, and di nitrogen tetroxide, N₂O₄

Thus, option (A) and (C) are correct.

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in the symbol 3p4 



a. the 3 represents the principal energy level

b. the p represents the principal energy level

c. the 4 represents the principal energy level

d. all of the above

help!

Answers

Answer:

a. the 3 represents the principal energy level

Explanation:

3 is the principal energy level. The p is the sublevel. 4 is the possible occupying electron.

What type of Nuclear decay is shown by the reaction below

Answers

Answer:

bete is your answer.

have a great day.

I think c ....is write answers

Calculate the heat when 100.0 mL of 0.500 M HCl is mixed with 300.0 mL of 0.100 M Ba(OH)2. Assuming that the temperature of both solutions was initially 25.0C and that the final mixture has a mass of 400.0 g and a specific heat capacity of 4.18 J/C g, calculate the final temperature of the mixture.

Answers

Answer:

26.8°C

Explanation:

For this reaction, the equation can be computed as follows:

[tex]2HCl_{(aq)}+ Ba (OH)_{2(aq)} \to BaCl_{2(aq)} + 2H_2O_{(l)} \ \ \ \ \ \ \Delta H= -118 \ kJ[/tex]

Now, Given that:

100.0 mL of 0.500 molarity (M) of HCl reacted with 300.0 mL of 0.100 molarity of Ba(OH)2.

The next process is to determine the number of moles of the solute:

For HCl:

no of mole  = [tex]\dfrac{0.500 \times 100}{1000}[/tex]

= 0.05 mol

For Ba(OH)2:

no of mole =[tex]\dfrac{0.100\times 300}{1000}[/tex]

= 0.03 mol

From the reaction, at the reactant side, we will see that two moles of HCl reacted with one mole of Ba(OH)2.

It implies that HCl is the limiting agent since it is in lesser quantity.

Similarly, the heat given out of the system is 118 kJ for each two moles of HCl with one mole of B(OH)2.

Hence, for 0.05 moles of HCl, the heat emitted out is:

[tex]= 0.05 mole \times ( \dfrac{118 \ kJ}{2 \mol})[/tex]

= 2.95 kJ

Let's recall from the question that:

the heat emitted was moved to the final mixture with mass =400g

the specific heat capacity = 4.18 J/°C g

Initial temperature = 25°C

Using the formula;

ΔH = mass × specific heat capacity × (T_f - T_i)

Then, replacing the values, we have:

2.95 kJ = 400 g ×  4.18 J/°C g × ( T_f - 25° C)

2950 J = 400 ×  4.18 J/°C × ( T_f - 25° C)

[tex]T_f = \dfrac{2950 \ J}{400 \times 4.18 \ J/^0 C}+25^0\ C[/tex]

[tex]\mathbf{ T_f = 26.8^0 \ C}[/tex]

Please help...

Draw a diagram showing the bonding in:

a) Tetrachloromethane [CCI4]

Answers

Answer:

here u go! ................

Answer:

Hope this is ok :))

Explanation:

2 Write the molecular formula of the compounds given below: Sodium hydrogen carbonate b) calcium hydroxide ) silver nitrate d) ammonium sulphate ) Magnesium carbonate f) Ferric oxidea​

Answers

[tex]\\ \rm\Rrightarrow Sodium\:Hydrogen\:carbonate=NaHCO_3[/tex]

[tex]\\ \rm\Rrightarrow Calcium\:Hydroxide=Ca(OH)_2[/tex]

[tex]\\ \rm\Rrightarrow Silver\:Nitrate=Ag(NO_3)_2[/tex]

[tex]\\ \rm\Rrightarrow Ammonium\:Sulphate=(NH_4)_2SO_4[/tex]

[tex]\\ \rm\Rrightarrow Ferric\:oxide=Fe_2O_3[/tex]

why there are two chloride ions for every calcium ion

Answers

Answer:

The valency of calcium is +2

Explanation:

Calcium is in group two. The members of group two are divalent metals that loose two electrons to form M^2+.

Since they form M^2+, they form ionic bonds with two uninegative ions. Chlorine is in group 17. This implies that its valency is -1 and it accepts one electron when it participates in an ionic bond.

Hence it will take two chlorine atoms to receive two electrons from one calcium atom in an ionic bond making the ratio of calcium to chlorine in the compound 2:1.

Atoms contain positive and negative charges. Why is the overall charge on an atom neutral?

A. Atoms contain the same amount of protons and electrons, and their charges cancel out.
B. The nucleus of an atom contains neutrons, which keep the positive and negative charges balanced.
C. Atoms are all negatively charged because electrons are on the outside of the atom.
D. Atoms contain the same amount protons and neutrons, and their charges cancel out.

Answers

Answer:

Atoms contain the same amount protons and neutrons, and their charges cancel out.

Explanation:

Answer via Educere/ Founder's Education

Atoms contain positive and negative charges, the overall charge on an atom neutral because Atoms contain the same amount of protons and electrons, and their charges cancel out.Hence, Option (A) is correct

What is an Atom ?

An atom is the smallest unit of ordinary matter that forms a chemical element.

Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms.

Atoms are extremely small, typically around 100 picometers across.

An atom consists of a positively charged nucleus, surrounded by one or more negatively charged particles called electrons.

The positive charges equal the negative charges, so the atom has no overall charge; it is electrically neutral.Hence, Option (A) is correct

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In an electrochemical cell, equilibrium is the point at which:

A. None of these
B. both electrodes have an equal number of electrons.
C. ion concentrations are no longer changing and the voltage is 0.
D. Equilibrium cannot be reached in a voltaic cell because electrons only flow in one direction.

Answers

Answer:

C. ion concentrations are no longer changing and the voltage is 0.

Explanation:

Electrochemical cells are a device that generates current from redox reactions. In the cell, the equilibrium is reached when the voltage drops to 0. Thus, option C is correct.

What is an electrochemical cell?

An electrochemical cell is a voltaic device that uses chemical energy to generate electrical energy and vice versa. It is of two types electrolytic and galvanic cells depending on the energy it produces.

The electrochemical cell comprises two electrodes namely an anode and cathode, a salt bridge or the porous barrier, and an external connection.

The connection shows the voltage that indicates the equilibrium. When the current flow stops and the voltage reaches zero, the electrochemical cell is said to be in equilibrium.

Therefore, no change in the ionic concentrations and zero voltage indicates equilibrium.

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A student is worried about determining if a chemical is radioactive. Which
section of the SDS would the student refer to?
Product Information
Fire Fighting Methods
Physical and Chemical Properties
Hazards Identification

Answers

Answer:

Hazards Identification

Explanation:

A safety data sheet, SDS, is an informational document provided by the manufacturer or importer of a hazardous chemical detailing the chemical, physical, health, and environmental health hazards associated with the chemical as well as safety precautions in handling the chemical.

Some of the sections in the SDS include:

Product Information: It identifies the chemical as well as its recommended uses. The contact information of the manufacturer is also provided.

Fire fighting methods: It gives measures and guidelines necessary for fighting a fire caused by the chemical.

Physical and chemical properties: states the physical and chemical properties of the chemical substance such as:  appearance, odor, pH, melting/freezing point, boiling point and boiling range, flammability, etc.

Hazards identification: states the hazards of the chemical and the necessary warnings regarding the hazards. Some of the information provided include: hazard classification of the chemical (for example flammable liquid, oxidizing gases,explosives, etc), signal word, hazard statement (for example radioactive), pictograms, precautionary statements, etc.

From the above information provided, the student should refer to the hazards identification section.

in h-atom if x is radius of first bohrs orbit de broglie wavelength of an atom in 3rd orbit is a.3πx b.6πx c.9x/2 d.x/2
please I need complete explanation fast ​

Answers

Answer:

can you type question properly.

You are given two aqueous solutions with different ionic solutes (Solution A and Solution B). What if you are told that Solution A has a greater concentration than Solution B by mass percent, but Solution B has a greater concentration than Solution A in terms of molality? Is this possible? If not, explain why not. If it is possible, provide example solutes for A and B and justify your answer with calculations.

Answers

Answer:

Yes, it is possible. Let us consider an example of two solutions, that is, solution A having 20 percent mass RbCl (rubidium chloride) and solution B is having 15 percent by mass NaCl or sodium chloride.  

It is found that solution A is having more concentration in comparison to solution B in terms of mass percent. The formula for mass percent is,  

% by mass = mass of solute/mass of solution * 100

Now the formula for molality is,  

Molality = weight of solute/molecular weight of solute * 1000/ weight of solvent in grams

Now molality of solution A is,  

m = 20/121 * 1000/80 (molecular weight of RbCl is 121 grams per mole)

m = 2.07

Now the molality of solution B is,  

m = 15/58.5 * 1000/85

m = 3.02

Therefore, in terms of molality, the solution B is having greater concentration (3.02) in comparison to solution A (2.07).

a sample of element X contains 90% X-35 atoms,8.0%X-37 atoms, and 2.0% X-38 atoms. The average atomic mass will be closest to which value?

Answers

Answer:

35.2.

Explanation

R.A.M= Mass of isotopes divide by 100 percent

Use Charles's Law to solve the following problem. A sample of air has a volume of 550.0 mL at 106 °C. At what temperature will its volume be 700.0 mL at constant pressure?

a
482 K

b
63 °C

c
505 K

d
119 °C

Answers

Answer:

im not sure but i think its c

505 K

A sample of gas has a volume of 20 cm³.The pressure is changed to 90 kPa at constant temperature,while the volume increases to 75 cm³.What was the original pressure of the gas?​

Answers

Answer:

337.5kPa ~ 338kPa

Explanation:

Using the ideal gas law PV=nRT we have the following definitions from the problem:

V(initial) = 20cm³

P(initial) = ?kPa

V(final) = 75cm³

P(final) = 90kPa

Since we know that the number of moles of the sample did not change, nor did the temperature, nor does the ideal gas constant (R) we can rewrite this equation to state:

P(initial)V(initial) = nRT =P(final)V(final) ~  P(initial)V(initial) = P(final)V(final)

Rearranging this equation as we are solving for the initial pressure we find that:

P(initial) = (P(final)V(final))/V(initial)

P(initial) = ((90kPa)(75cm³))/20cm³

P(initial) = 337.5kPa ~ 338kPA

the density is 5.4 g/mL and the volume is 12.9 mL.

Answers

Answer:

69.66 g

Explanation:

We have the following from the question;

Density of the substance = 5.4 g/ml

Volume of substance = 12.9 ml

Mass of substance= the unknown

Since we have both density and volume of the substance, the question must be for us to obtain the mass of the substance, hence;

Density= mass/volume

Mass= Density × volume

Mass = 5.4 g/ml × 12.9 ml

Mass= 69.66 g

What evidence demonstrates that chlorine in the stratosphere is primarily from man-made chemicals rather than from natural sources such as volcanoes?

Answers

Answer:

The evidence that demonstrated that the Chlorine in the stratosphere is believed to come primarily from CFCs ( Chlorofluorocarbons) rather than from natural sources such as volcanoes was due to the study conducted in which the amount of chlorine in the stratosphere over the past 20 years was measured and it was discovered that there was an increase over the years. This also corresponded with a rise in CFCs over the same period which shows that the chlorine in the stratosphere was from man made chemicals such as chlorofluorocarbons.

Chlorine in the stratosphere is primarily from man-made chemicals rather than from natural sources such as volcanoes is evident as follows;

Discussion;

Most of the chlorine in the stratosphere is there as a result of human activities, as the figure below illustrates.

Many compounds containing chlorine are released at the ground.

Volcanoes can emit large quantities of hydrogen chloride, but this gas is rapidly converted to hydrochloric acid, which dissolves in rain water, ice, and snow and does not reach the stratosphere.

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Can a window pane be considered a mineral?

Answers

Answer:

Explanation:

The glass (which does not crystallize even though it is accepted) of a window is NOT a mineral, since it is neither a substance of natural origin (although it is manufactured from natural components) nor does it have a defined crystalline structure, that is, the atoms they are not arranged in an orderly and regular way along axes and planes forming flat faces that keep a symmetry.

Remember that a mineral is defined as a solid, inorganic, homogeneous substance, of natural origin, with a crystalline structure and a determined and well-defined chemical composition within narrow margins and that has regular and characteristic physical properties.

Explanation: No, glass is not a mineral. ... Definable chemical composition: SiO2 *Actually, most industrially-produced glass is not pure silica, but having impurities is still a definable chemical composition so this part of the definition is ok. Orderly arrangement of atoms in a lattice: NO.

Scientists have changed the model of the atom as they have gathered new evidence. One of the atomic models is shown below. A purple ball in the center surrounded by overlapping concentric black ovals, each with a small green ball on each of the 6 ovals. What experimental evidence led to the development of this atomic model from the one before it? A few of the positive particles aimed at a gold foil seemed to bounce back. The colors of light emitted from heated atoms had very specific energies. Experiments with water vapor showed that elements combine in specific proportions. Cathode rays were bent in the same way whenever a magnet was brought near them.

Answers

Answer:

A few of the positive particles aimed at a gold foil seemed to bounce back.

Explanation:

Rutherford's experiment took the search for the structure of the atom a step further. In this experiment, a narrow beam of alpha particles emitted from a source was used to bombard a thin gold foil.

The scattering of the alpha particles was detected by a movable ZnS screen. It was found that most of the alpha particles followed a straight path through the gold foil but some were scattered through large angles and some even scattered backwards.

Following this experiment, Rutherford decided on his planetary model of the atom in which the nucleus is at the core of the atom with electrons moving round the nucleus in orbits. Rutherford was awarded a Nobel prize for this work.

Answer:

a

Explanation:

edge 2020

What are the standard temperature and pressure conditions enthalpy is usually measured under

Answers

Answer:

temperature must be 273 Kelvin (0°C)

pressure must be 1 atm

PLEASE HELP!! What direction do you predict the addition of a base to the solution containing bromophenol blue will drive the equilibrium? Explain your prediction in terms of Le Châtelier's principle.

Answers

Answer:

Below is the clarification of that same particular question.

Explanation:

Le Chatlier's theory states that whenever an equilibrium mechanism is disrupted by environmental influences, the program responds by changing the supplies information of its constituents in a somewhat way that the disturbance is invalidated and reaches a stable equilibrium during that disrupted stage, with concentrations of stability differently than ever before.Bromothymol blue seems to be a phenolic subs lone which always allows it to act throughout aqueous solutions as an acidic solution. Being such an acid (weak), it should not add to rapid, as well as introduces a balance with its accompanying but mostly disconnected form.

For that kind of weak diprotic predictor, the standard economic statement can indeed be published as:

    ⇒  [tex]H_2In_(aq)\rightleftharpoons In^{2-} +2H^+[/tex]

It could be conclusively proven from either the theory of Le Charlier whereby, that whenever a strong acid becomes applied, the full disorientation of one or the other, through equilibrium formation, induces an increase throughout the medium's proton concentrations.Likewise, it absorbs the protons throughout the media to split water that whenever a solution is added. So, particle concentration throughout the medium is decreasing. To accommodate for this transition, the equilibrium reacts by moving to the correct i.e. causing further dissociation of the optimistic predictor into their dianion through protons, thereby attempting to nullify that perturbation.

Question number 4..​

Answers

Answer:

I think it's 7089 because that's my answer to your questions

What is the product of the reaction of pentanoic acid with ethanol in the presence of a strong acid?

Answers

Answer:

ethylpentanoate

Explanation:

Alkanoic acids react with alkanols in the presence of mineral acids to yield an ester and water. This is the organic analogue of the inorganic neutralization reaction. The reaction his commonly called esterification. It is an acid catalysed reaction.

The reaction of pentanoic acid and ethanol in the presence of a string acid is shown below;

CH3CH2CH2CH2COOH(aq) + CH3CH2OH(aq) ----> CH3CH2CH2CH2COOCH2CH3(aq) + H2O(l)

The name of the compound formed is ethylpentanoate.

describe an activity to separate the mixture of sand and water​

Answers

Answer:

Sedimentation and decantation

Explanation:

Sedimentation and decantation: Mixture is kept undisturbed for some time. After some time, sand being heavier and insoluble in water, settles down at the bottom of container. Now, water is poured into another container to separate it from sand.

Answer:

evaporation or destillation

Explanation:

When sand is added to water it either hangs in the water or forms a layer at the bottom of the container. Sand therefore does not dissolve in water and is insoluble. It is easy to separate sand and water by filtering the mixture. Salt can be separated from a solution through evaporation.

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I will give brainlist The Cooke family has worked for various General Motors's divisions for over four decades. Bennett Cooke works at the Cadillac division. Rondella Cooke works at the Buick division. Their son Tyrone works at the Corvette plant, and their daughter Niome works at the Saturn plant. The Cooke family could tell you that GM is departmentalized by: In a survey of adults in a certain country conducted during a period of economic uncertainty, % thought that wages paid to workers in industry were too low. The margin of error was percentage points with % confidence. For parts (a) through (d) below, which represent a reasonable interpretation of the survey results? For those that are not reasonable, explain the flaw. As part of the review of your _________, you should delete material that wanders. Identify each of the highlighted materials as an element, a compound, or a mixture, and explain your reasoning. All slings shall be manufactured under ASME B30.9 guidelines and must have an affixed permanent identification tag that includes:_______a. Name or trademark of the manufacturerb. WLL for given type of hitch and configurationc. Type of materiald. All of the above How much energy has your body used, in joules, if your healthdevice indicates that 450 Calories were burned during your workout? How manyCalories are in a dinner containing 3.5 x 100 joules Slide 1.1) Find the area of the metal sheet below that is requiredto make this square-shaped traffic sign. Show all work onpaper.+7x-3 The break-even point is a.the maximum possible operating loss. b.where the total sales line intersects the total costs line on a cost-volume-profit chart. c.the total fixed costs. d.the maximum possible operating income. In your discussion post explain what history is, and how you view history. Do you think history is an important topic to learn about? Why or why not? The result of adding 14 to twice a number is the same as subtracting 8 from four times that number. Find that number. With her new company, Annika has a two-year assignment living in a large city. The company will reimburse most of her expenses. Annika is using the Quantitative Reasoning Process to build a budget. Calculate Annika's estimated living expenses for the next two years using the following: Rent: $1,200 per month, Gym membership: $400 per year with a monthly fee of $35, Renters' insurance: $75 every 6 months, Groceries: $390 per month, and Eating out & entertaining: $250 per week. Assume 52 weeks in 1 year and 12 months in 1 year. (Round your answer to the nearest whole dollar) Find the endpoint/midpoint.Please hurry A chamber contains equal molar amounts of He, Ne, Ar, and Kr. If the total chamber pressure is 1 atm, then the partial pressure (in atm) of Kr is: predict meaning of dimension Raul and his friends each way 1/20 of a ton are standing on a truck scale . The total weight shown by the scale is 3/4 of a ton . How can I find the total number of people on the scale when Raul and his friends are weighed? What community do you live in?Name two places in your community?What is your favorite place to visit in your community and why? 0000000000[How didthe Habeas Corpus Act of 1679 limit the power of the monarchy?O It prevented monarchs from instituting religious law.O It prevented monarchs from conducting their own trials. It prevented monarchs from influencing the courts.O It prevented monarchs from having opponents arrested. Abraham Lincoln wrote the Emancipation Proclamation:________ a) because he considered emancipation to be "a military necessity, absolutely essential to the preservation of the Union." b) as a personal moral statement regarding why slaves should be free. as a response to the constant lobbying of abolitionists pressing him to free the slaves. c) as a way to appease the entire northern population and their cries for freedom for all slaves. what's the square footage of 12'3" * 18'4"