Answer:
1. Exothermic 2. Exothermic 3. Endothermic 4. Endothermic 5. Exothermic.
Explanation:
1. An A-A and a C-C bond results in 2 A-C bonds which are lower than the A-A and C-C bonds so this reaction is exothermic.
2. A B-B bond and a C-C bond results in 2 B-C bonds which are lower than the first 2 bonds so this reaction is also exothermic.
3. There is no bond for single A, a single B-C bond results in a A-B bond and a C molecule. A-B bond is stronger than the B-C bond so the reaction absorbed energy along the way. This shows that it is endothermic.
4. An A-A bond and a B-B bond results in 2 A-B bonds which are stronger than the first two bonds so this reaction is also endothermic.
5. An A-B bond and a C molecule result in an A-C bond and a B molecule. A-C bond is weaker than the A-B bond so there is energy released. This reaction is exothermic.
I hope this answer helps.
Q 11.20: What is the product of the reaction between t-BuCl and MeOH? A : t-BuOH B : MeOCl C : t-BuOMe D : (CH3)2CCH2
Answer:
C : t-BuOMe
Explanation:
The tert -butanol is a tertiary alcohol and when chloride ion attacks the carbocation, it forms t-BuCl.
The reaction of tert-butyl chloride or t-BuCl ((CH3)3C−Cl) with methanol and MeOH (CH3−OH) gives the product tert-Butyl methyl ether or t-BuOMe (CH3)3C−OCH3:
(CH3)3C−Cl + CH3−OH => (CH3)3C−OCH3 + HCl
Hence, the correct asnwer is C : t-BuOMe
To calculate changes in concentration for a system not at equilibrium, the first step is to determine the direction the reaction will proceed. To do so, we calculate Q and compare it to the equilibrium concentration, K. We can then determine that a reaction will shift to the right if:__________
Answer:
We can then determine that a reaction will shift to the right if Q<K
Explanation:
Comparing Q with K allows to find out the status and evolution of the system:
If the reaction quotient is equal to the equilibrium constant, Qc = Kc, the system has reached chemical equilibrium. If the reaction quotient is greater than the equilibrium constant, Qc> Kc, the system is not in equilibrium and will evolve spontaneously, decreasing the value of Qc until it equals the equilibrium constant. In this way, the concentrations of the products will decrease and the concentrations of the reagents will increase. In other words, the reverse reaction is favored to achieve equilibrium. Then the system will evolve to the left (ie products will be consumed and more reagents will be formed).If the reaction quotient is less than the equilibrium constant, Qc <Kc, the system is not in equilibrium and will evolve spontaneously increasing the value of Qc until it equals the equilibrium constant. This implies that the concentrations of the products will increase and those of the reagents will decrease. In other words, to achieve balance, direct reaction is favored. Then the reaction will shift to the right, that is, reagents will be consumed and more products will be formed.In this case, we can then determine that a reaction will shift to the right if Q<K
Explain why it is not advisable to add water to acid when
mixing them
Answer:
Consequence
you form an extremely concentrated solution of acid initially.and the solution may boil very violently, splashing concentrated acid. I hope this helped! :)Half-cells were made from a nickel rod dipping in nickel sulfate solution and a copper rod dipping in copper sulfate solution. The cells were combined to construct a voltaic electrochemical cell. Sketch the cell and label anode and cathode with charges, electrode material and electrolyte solutions, half-reactions and overall reaction, give direction of electron flow and movement of ions.
Answer:
Check the Attachment.
Half-reactions:
Anode: (OXIDATION) Ni --> Ni2+ + 2e-
Cathode: (REDUCTION) Cu2+ +2e- --> Cu
Overall reaction: Ni + Cu2+ --> Ni2+ + Cu
Explanation:
Overall, reaction is basically Anode + Cathode, where electrons on both sides cancel out (if not, you need to multiply the equation in a way you can cancel them out).
Hope this helps.
Which part of an atom is mostly empty space?
A. nucleus
B. proton cloud
C. electron cloud
D. neutron
Answer:
C. Electron cloud
the electron is around 1/2000 times the size of the proton.
If you imagine the proton a a marble in the middle of a football field, the electrons will revolve around the last row
Amino acids can be synthesized by reductive amination. Draw the structure of the organic compound that you would use to synthesize serine.
Answer:
Following are the answer to this question:
Explanation:
For the reductive amination of its carbonyl group, amino acids could be synthesized by reducing ammunition, which can be synthesized in the given attachment file:
please find the attachment:
What happens during the fourth stage of technological design that is not necessary during the sixth or seventh stages of scientific investigation?
A design is remodeled after analysis and tested again.
An initial design is implemented and analyzed to gather data.
Conclusions are made and communicated to others.
Criteria are stated to help judge the success of the process.
Answer:
a design is remodeled after analysis and tested again
Explanation:
explain chlorination of methane
Answer:
Methane and chlorine
If a mixture of methane and chlorine is exposed to a flame, it explodes - producing carbon and hydrogen chloride. This is not a very useful reaction! The reaction we are going to explore is a more gentle one between methane and chlorine in the presence of ultraviolet light - typically sunlight. This is a good example of a photochemical reaction - a reaction brought about by light.
CH4+Cl2+energy→CH3Cl+HCl(3.4.2)
The organic product is chloromethane. One of the hydrogen atoms in the methane has been replaced by a chlorine atom, so this is a substitution reaction. However, the reaction doesn't stop there, and all the hydrogens in the methane can in turn be replaced by chlorine atoms.
Substitution reactions happen in which hydrogen atoms in the methane are replaced one at a time by chlorine atoms. You end up with a mixture of chloromethane, dichloromethane, trichloromethane and tetrachloromethane.
I hope this help you!:)
Explanation:
After balancing the following reaction under acidic conditions, how many mole equivalents of water are required and on which side of the reaction do they appear?
MnO41- (aq) + Cl1- (aq) → Mn2+ (aq) + Cl2 (g)
a. 2 moles of H2O on the reactant side
b. 2 moles of H2O on the product side
c. 4 moles of H2O on the product side
d. 8 moles of H2O on the product side
e. 10 moles of H2O on the reactant side
Answer:
d. 8 moles of H2O on the product side
Explanation:
Hello,
In this case, we need to balance the given redox reaction in acidic media as shown below:
[tex]MnO_4^{1-} (aq) + Cl^{1-} (aq) \rightarrow Mn^{2+} (aq) + Cl_2 (g)\\\\(Mn^{7+}O^{2-}_4)^{1-} (aq) + Cl^{1-} (aq) \rightarrow Mn^{2+} (aq) + Cl_2 (g)\\\\\\\\(Mn^{7+}O^{2-}_4)^{1-} (aq)+8H^++5e^- \rightarrow Mn^{2+}+4H_2O\\\\2Cl^{1-}\rightarrow Cl_2^0+2e^-\\\\2*[(Mn^{7+}O^{2-}_4)^{1-} (aq)+8H^++5e^- \rightarrow Mn^{2+}+4H_2O]\\\\5*[2Cl^{1-}\rightarrow Cl_2^0+2e^-]\\\\\\\\2(Mn^{7+}O^{2-}_4)^{1-} (aq)+16H^++10e^- \rightarrow 2Mn^{2+}+8H_2O\\\\10Cl^{1-}\rightarrow 5Cl_2^0+10e^-\\[/tex]
Then, we add the half reactions:
[tex]2(Mn^{7+}O^{2-}_4)^{1-} (aq)+16H^++10Cl^{1-} \rightarrow 2Mn^{2+}+8H_2O+5Cl_2^0[/tex]
Thereby, we can see d. 8 moles of H2O on the product side.
Best regards.
How many grams of sodium chloride are required to make 2.00 L of a solution with a concentration of 0.100 M?
Answer:
Mass = 11.688g
Explanation:
Volume = 2.00L
Molar concentration = 0.100M
Mass = ?
These quantities are relatted by the following equation;
Conc = Number of moles / volume
Number of moles = Conc * Volume = 2 * 0.100 = 0.2 mol
Number of moles = Mass / Molar mass
Mass = Number of moles * Molar mass
Mass = 0.2mol * 58.44g/mol
Mass = 11.688g
Any process with a negative change in enthalpy and a positive change in entropy will be:_______.
a. spontaneous
b. nonspontaneous
c. spontaneous at high temperatures
d. spontanteous at low temperatures
Answer:
a. spontaneous
Explanation:
Hello,
In this case, since the Gibbs free energy is a metric that allows us to know whether a chemical reaction is spontaneous (Gibbs free energy less than 0) or nonspontaneous (Gibbs free energy greater than 0) we can mathematically define it as:
[tex]\Delta G=\Delta H-T\Delta S[/tex]
Thus, if the enthalpy is negative and the entropy is negative, the subtraction become always negative, for which the Gibbs free energy is negative as well, therefore, based on the aforementioned, any process with a negative change in enthalpy and a positive change in entropy will be: a. spontaneous.
Best regards.
A nitrogen ion has a mass of 14 and a charge of +2. Which subatomic particles does it contain? (1 point)
O 2 protons, 6 neutrons, and 6 electrons
O 7 protons, 7 neutrons, and 5 electrons
O 4 protons, 4 neutrons, and 6 electrons
o 7 protons, 7 neutrons, and 9 electrons
Answer:
7 protons, 7 neutrons, and 5 electrons
Explanation:
the formula for atomic weight=no.of protons + no. of electrons this shortens the options into b or d and second part says that the ion has charge +2 which means it has lost two electrons. so no. of electrons=no.of electrons in nitrogen atom - 2=5.
Nitrogen ion with a charge of +2 has 7 protons, 7 neutrons, and 5 electrons
Explanation:
To obtain the right answer to the question, we must determine the number of proton, neutron and electron of nitrogen ion. This can be obtained as illustrated follow.
Step 1:Data obtained from the question.
Mass number = 14
Charge = +2
Step 2:Determination of the number of proton.
The atomic number of an element is simply the number of protons in the atom of the element.
Atomic number of nitrogen = 7
Thus, the proton number of nitrogen is 7.
NOTE: The atomic number of an element does not change be it atom or ion, it remains the same.
Therefore the proton number of nitrogen ion is 7
Step 3:Determination of the number of neutron
Mass number = 14
Proton number = 7
Neutron number =?Mass number = Proton + Neutron
14 = 7 + Neutron
Collect like terms
14 – 7 = Neutron
Neutron = 7Step 4Determination of the number of electrons.
Charge = +2
Proton number = 7
Electron number =?Charge = Proton – Electron
+2 = 7 – Electron
Collect like terms
2 – 7 = – Electron
–5 = – Electron
Multiply through by –1
Electron = 5SUMMARY:Nitrogen ion with a charge of +2 has:
1. 7 protons
2. 7 neutrons
3. 5 electrons.
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A number is three times the difference between twenty and the number. What is the number?
Answer:
the number is 7
Explanation:
"Three times" means multiply by 3
"Difference" means subtract
"Sum" means add
3(x - 7) = 23 - (3x + 2)
3x - 21 = 23 - 3x - 2
3x - 21 = 21 - 3x
6x = 42
x = 7
1A. A strontium hydroxide solution is prepared by dissolving 10.45 g of Sr(OH)2 in water to make 41.00 mL of solution. What is the molarity of this solution?
1B. Next the strontium hydroxide solution prepared in part (a) is used to titrate a nitric acid solution of unknown concentration. Write a balanced chemical equation to represent the reaction between strontium hydroxide and nitric acid solutions.
1C. If 23.9 mL of the strontium hydroxide solution was needed to neutralize a 31.5 mL aliquot of the nitric acid solution, what is the concentration (molarity) of the acid?
Answer:
1. 0.00352 M
2. 2HNO3(aq) + Sr(OH)2(aq) -----> Sr(NO3)2(aq) + 2H2O(l)
3. 0.00534 M
Explanation:
1.
Mass of strontium hydroxide= 10.45 g
Volume of solution = 41.00 ml
Number of moles = mass of Sr(OH)2/molar mass of Sr(OH)2 = 10.45g/121.63 g/mol= 0.0859 moles
Molarity= number of moles × volume = 0.0859 ×41/1000 = 0.00352 M
2.
2HNO3(aq) + Sr(OH)2(aq) -----> Sr(NO3)2(aq) + 2H2O(l)
3.
Concentration of acid CA= the unknown
Volume of acid VA= 31.5 ml
Concentration of base CB= 0.00352 M
Volume of base VB= 23.9 ml
Number of moles of acid NA= 2
Number of moles of base NB= 1
From;
CAVA/CBVB = NA/NB
CAVANB= CBVBNA
CA= CBVBNA/VANB
CA= 0.00352 × 23.9 ×2/31.5 ×1
CA= 0.00534 M
A. The molarity of the Sr(OH)₂ solution is 2.09 M
B. The balanced equation for the reaction is
2HNO₃ + Sr(OH)₂ —> Sr(NO₃)₂ + 2H₂O
C. The molarity of the acid, HNO₃ is 3.17 M
A. Determination of the molarity of the Sr(OH)₂ solution
We'll begin by calculating the number of mole in 10.45 g of Sr(OH)₂Mass of Sr(OH)₂ = 10.45 g
Molar mass of Sr(OH)₂ = 88 + 2(16 + 1) = 122 g/mol
Mole of Sr(OH)₂ =?Mole = mass / molar mass
Mole of Sr(OH)₂ = 10.45 / 122
Mole of Sr(OH)₂ = 0.0857 mole Finally, we shall determine the molarity of Sr(OH)₂Mole of Sr(OH)₂ = 0.0857 mole
Volume = 41 mL = 41 / 1000 = 0.041 L
Molarity of Sr(OH)₂ =?Molarity = mole / Volume
Molarity of Sr(OH)₂ = 0.0857 / 0.041
Molarity of Sr(OH)₂ = 2.09 MB. The balanced equation for the reaction.
2HNO₃ + Sr(OH)₂ —> Sr(NO₃)₂ + 2H₂OC. Determination of the molarity of the acid, HNO₃.
From the balanced equation above,
The mole ratio of the acid, HNO₃ (nA) = 2
The mole ratio of the base, Sr(OH)₂ (nB) = 1
From the question given above,
Volume of base, Sr(OH)₂ (Vb) = 23.9 mL
Molarity of base, Sr(OH)₂ (Mb) = 2.09 M
Volume of acid, HNO₃ (Va) = 31.5 mL
Molarity of acid, HNO₃ (Ma) =?MaVa / MbVb = nA/nB
(Ma × 31.5) / (2.09 × 23.9) = 2
(Ma × 31.5) / 49.951 = 2
Cross multiply
Ma × 31.5 = 49.951 × 2
Ma × 31.5 = 99.902
Divide both side by 31.5
Ma = 99.902 / 31.5
Ma = 3.17 MThus, molarity of the acid, HNO₃ is 3.17 M
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12 g of powdered magnesium oxide reacts with nitric acid to
form magnesium nitrate and water.
Calculate the mass of magnesium nitrate formed.
[Relative atomic mass of Mg = 24, N = 14,0 = 16] *
Answer:
80.8 g
Explanation:
First, let's write a balanced equation of this reaction
MgO + 2HNO₃ → Mg(NO₃)₂ + H₂O
Now let's convert grams to moles
We gotta find the weight of MgO
24 + 16 = 40 g/mol
12/40 = 0.3 moles of MgO
We can use this to find out how much Magnesium Nitrate will be formed
0.3 x 1 MgO / 1 Mg(NO₃)₂ = 0.3 moles of Magnesium Nitrate formed
Convert moles to grams
Find the weight of Mg(NO₃)₂ but don't forget that 2 subscript acts as a multiplier of whatever is inside that parenthesis.
24 + 14 x 2 + 16 x 3 x 2 = 148 g/mol
148 x 0.3 = 80.8 g
Determine the relative formula mass of dihydrogen monoxide using the periodic table below.
A. 18 g/mol
B. 17 g/mol
C. 16 g/mol
D. 2 g/mol
The relative atomic mass of dihydrogen monoxide is 18g/mol
Dihydrogen monoxide is a molecule containing two atoms of hydrogen and one atom of oxygen i.e. H2O. It is widely regarded as WATERTo calculate the relative atomic mass of dihydrogen monoxide (H2O), we make use of the atomic mass of each element.According to the periodic table:
Where; H = 1g/mol and O = 16g/mol
H2O = 1(2) + 16
= 2 + 16
= 18g/mol
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molecular weight of K2SO3
Explanation:
the molecular weight of K2SO3 is 158. 2598 m/s.
How is magma formed?
Answer:
“Magma” is exclusively found and formed beneath the earth’s surface. Once magma is on or above the surface of the earth it is referred to as “lava.” Magma is typically formed by extreme temperature melting solid rock within the earth. Pressure and rock composition can also affect magma formation. High pressure can help magma be “squeezed” from partially molten rock. Likewise, as rocks are usually composed of different minerals with different melting points, magma formation from rocks is usually only partial and uneven.
Explanation:
candium forms the ion Sc3+. How many bromite ions could bond with Sc3+, and what would be the chemical formula?
a.3 bromite ions, Sc(Broa)2
b.2 bromite ions, Sc(BrO4)3
c.3 bromite ions, Sc(Broz)
d.2 bromite ions, Sc (BrO2)2
Answer: 3 bromite ions and [tex]Sc(BrO_2)_3[/tex]
Explanation:
For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.
Here scandium is having an oxidation state of +3 called as [tex]Sc^{3+}[/tex] cation and bromite is an anion with oxidation state of -1 called as [tex]BrO_2^-[/tex]. Thus 1 Scandium ion combines with three bromite ions and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]Sc(BrO_2)_3[/tex]
Answer:
3 bromite ions and
Explanation:
Consider the reaction for the dissolution of solid magnesium hydroxide.
Mg(OH)2(s)g2 (a) +2OH (ag)
If the concentration of hydroxide ion in a saturated solution of magnesium hydroxide is 2.24 x 104 M.
what is the molar solubility of magnesium hydroxide? Report your answer in scientific notation with three significant figures.
Answer:
Molar solubility is 1.12x10⁻⁴M
Explanation:
The dissolution of magnesium hydroxide is:
Mg(OH)₂(s) ⇄ Mg²⁺ + 2OH⁻
The molar solubility represents the moles of the solid that the solution can dissolve, that could be written as:
Mg(OH)₂(s) ⇄ X + 2X
Where X is solubility.
If you obtained a [OH⁻] = 2.24x10⁻⁴M and you know [OH⁻] = 2X:
2X = 2.24x10⁻⁴M
X = 2.24x10⁻⁴M/2
X =1.12x10⁻⁴M
Molar solubility is 1.12x10⁻⁴M
What happens to the rate of dissolution as the temperature is increased in a gas solution?
A.
The rate stays the same.
B.
The rate decreases.
C.
The rate increases.
D.
There is no way to tell.
Answer:
The rate decreases
Explanation:
When we dissolve a gas in a water, the process is exothermic. This implies that heat is evolved upon dissolution of a gas in water.
Recall from Le Chateliers principle that for exothermic reactions, an increase in temperature favours the reverse reaction. The implication of these is that when the temperature of the gas is increased, less gas will dissolve in water.
Hence increase in temperature decreases the rate of solubility of a gas in water.
Answer:
B.
The rate decreases.
Explanation:
In the experiment students will create solutions with different ratios of ethanol and water. What is the mole fraction of ethanol when 10.00 mL of pure ethanol is combined with 2.00 mL of water
Answer:
[tex]x_{et}=0.6068[/tex]
Explanation:
Hello,
In this case, since the mole fraction of a compound, in this case ethanol, in a binary mixture, in this constituted by both water and ethanol, is mathematically defined as follows:
[tex]x_{et}=\frac{n_{et}}{n_{et}+n_{w}}[/tex]
Whereas [tex]n[/tex] accounts for the moles in the solution for each species, we must first compute the moles of both ethanol (density: 0.789 g/mL and molar mass: 46.07 g/mol) and water (density: 1g/mL and molar mass: 18.02 g/mol)
[tex]n_{et}=10.00mL\ et*\frac{0.789g\ et}{mL\ et} *\frac{1mol\ et}{46.07g\ et}=0.1713mol\ et\\ \\n_w=2.00mL\ w*\frac{1g\ w}{mL\ w} *\frac{1mol\ w}{18.02g\ w}=0.1110mol\ w[/tex]
Therefore, the mole fraction turns out:
[tex]x_{et}=\frac{0.1713mol}{0.1713mol+0.1110mol}\\\\x_{et}=0.6068[/tex]
Best regards.
For a particular reaction at 235.8 °C, ΔG=−936.92 kJ/mol , and ΔS=513.79 J/(mol⋅K) . Calculate ΔG for this reaction at −9.9 °C.
Answer:
-138.9 kJ/mol
Explanation:
Step 1: Convert 235.8°C to the Kelvin scale
We will use the following expression.
K = °C + 273.15 = 235.8°C + 273.15 = 509.0 K
Step 2: Calculate the standard enthalpy of reaction (ΔH°)
We will use the following expression.
ΔG° = ΔH° - T.ΔS°
ΔH° = ΔG° / T.ΔS°
ΔH° = (-936.92kJ/mol) / 509.0K × 0.51379 kJ/mol.K
ΔH° = -3.583 kJ (for 1 mole of balanced reaction)
Step 3: Convert -9.9°C to the Kelvin scale
K = °C + 273.15 = -9.9°C + 273.15 = 263.3 K
Step 4: Calculate ΔG° at 263.3 K
ΔG° = ΔH° - T.ΔS°
ΔG° = -3.583 kJ/mol - 263.3 K × 0.51379 kJ/mol.K
ΔG° = -138.9 kJ/mol
What is an example of an extensive property
One gram is approximately the same as half the mass of a new U.S.
A) penny.
B) dime.
C) quarter.
D) dollar.
Answer:
b) dime
Explanation:
a dime is approximately 2.2g
half of this is 1.1g, which can be rounded down to one gram.
hope this helps
name two device that are using spinning
→ Takli
Takli is a small support style spindle. Takli is a perfect tool for spinning cotton, and this are used too to spin fibers, cotton, cashmere, and silk etc. Takli is known as handspindle. And it is the simplest device for spinning.→ Charkha
Charkha is a device for spinning thread or yarn from fibers etc. This are known as spinning wheel.HAVE A NICE DAY!How many liters of CH₃OH gas are formed when 3.20 L of H₂ gas are completely reacted at STP according to the following chemical reaction? Remember 1 mol of an ideal gas has a volume of 22.4 L at STP.CO(g)+ H2(g) → CH3OH
Answer:
The correct answer is 1.60 Liters.
Explanation:
The given reaction:
CO (g) + H₂(g) ⇔ CH₃OH (g)
Based on the given reaction, two moles of H₂ reacts with one mole of CO and produce one mole of CH₃OH.
It is mentioned that 3.20 L of H₂ is reacted, therefore, there is a need to convert it into moles.
As 22.4 L at standard temperature and pressure is equivalent to 1 mole.
Therefore, 1 L at STP will be, 1/22.4 mole
Now 3.20 L at STP will be,
= 1/22.4 × 3.20
= 0.1428 mole
And as mentioned in the reaction that 2 moles of H₂ gives 1 mole of CH₃OH, therefore, 1 mole of H₂ will give 1/2 mole of CH₃OH
Now, 0.1428 mole of H₂ will give,
= 0.1428/2 = 0.071 mole of CH₃OH
= 0.071 × 22.4 = 1.60 L
The volume, in liters, of CH₃OH gas formed is 1.60 L
From the question,
We are to determine the volume of CH₃OH formed
The given chemical equation for the reaction is
CO(g)+ H₂(g) → CH₃OH
The balanced chemical equation for the reaction is
CO(g)+ 2H₂(g) → CH₃OH
This means
1 mole of CO reacts with 2 moles of H₂ to produce 1 mole of CH₃OH
Now, we will determine the number of moles of H₂ present in the 3.20 L H₂ at STP
1 mol of an ideal gas has a volume of 22.4 L at STP
Then,
x mole of the H₂ gas will have a volume of 3.20 L at STP
x = [tex]\frac{3.20 \times 1}{22.4}[/tex]
x = 0.142857 mole
∴ The number of mole of H₂ present is 0.142857 mole
Since
2 moles of H₂ reacts to produce 1 mole of CH₃OH
Then,
0.142857 mole of H₂ will react to produce [tex]\frac{0.142857}{2}[/tex] mole of CH₃OH
[tex]\frac{0.142857}{2} = 0.0714285[/tex]
∴ The number of moles of CH₃OH produced = 0.0714285 mole
Now, for the volume of CH₃OH formed
Since
1 mol of an ideal gas has a volume of 22.4 L at STP
Then,
0.0714285 mol of CH₃OH will have a volume of 22.4 × 0.0714285 at STP
22.4 × 0.0714285 = 1.5999984 L ≅ 1.60 L
Hence, the volume of CH₃OH gas formed is 1.60 L
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Calculate ΔS∘rxn for the balanced chemical equation 2H2S(g)+3O2(g)→2H2O(g)+2SO2(g) Express the entropy change to four significant figures and include the appropriate units.
Answer:
-170.65
188.8+ 256.8-205.8-(2x205.2)
-170.65 is the entropy change.
What is Entropy Change?Entropy trade is the phenomenon that is the measure of change of disorder or randomness in a thermodynamic gadget. It is associated with the conversion of heat or enthalpy completed in work. A thermodynamic device that has extra randomness means it has high entropy.
Subtract the sum of the absolute entropies of the reactants from the sum of the absolute entropies of the products, each extended by using their suitable stoichiometric coefficients, to reap ΔS° for the reaction.
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#SPJ2
An enzyme is discovered that catalyzes the chemical reaction:SAD -------->HAPPY
<-------A team of motivated researchers sets out to study the enzyme which they call Happyase. They find that the Kcat for happyase is 600s-1. They carry out several experiments. When [Et]=20 nM and [SAD]=40 \mu M, the reaction velocity, Vo is 9.6 \mu Ms^{-1} . Calculate the Km for the substrate SAD.
Answer: Km = 10μM
Explanation: Michaelis-Menten constant (Km) measures the affinity a enzyme has to its substrate, so it can be known how well an enzyme is suited to the substrate being used. To determine Km another value associated to an eznyme is important: Turnover number (Kcat), which is the number of time an enzyme site converts substrate into product per unit time.
Enzyme veolcity is calculated as:
[tex]V_{0} = \frac{E_{t}.K_{cat}.[substrate]}{K_{m}+[substrate]}[/tex]
where Et is concentration of enzyme catalitic sites and has to have the same unit as velocity of enzyme, so Et = 20nM = 0.02μM;
To calculate Km:
[tex]V_{0}*K_{m} + V_{0}*[substrate] = E_{t}.K_{cat}.[substrate][/tex]
[tex]K_{m} = \frac{E_{t}.K_{cat}.[substrate]-V_{0}*[substrate]}{V_{0}}[/tex]
[tex]K_{m} = \frac{0.02*600*40-9.6*40}{9.6}[/tex]
Km = 10μM
The Michaelis-Menten for the substrate SAD is 10μM.
19. For the following unbalanced equation: S (s) O2 (g) H2O (l) ----> H2SO4 (aq) At what temperature (K) does O2 have to be if the volume of the gas is 5.01 L with a pressure of 0.860 atm to produce 17.55 grams of H2SO4
Answer:
195.5 K
Explanation:
We'll begin by writing the balanced equation for the reaction. This is given below:
2S + 3O2 + 2H2O → 2H2SO4
Next, we shall determine the number of mole in 17.55 g of H2SO4. This can be obtained as follow:
Molar mass of H2SO4 = (2x1) + 32 + (16x4) = 2 + 32 + 64 = 98 g/mol
Mass of H2SO4 = 17.55 g
Mole of H2SO4 =...?
Mole = mass /Molar mass
Mole of H2SO4 = 17.55/98
Mole of H2SO4 = 0.179 mole.
Next, we shall determine the number of mole of O2 needed for the reaction. This can be obtained as illustrated below:
From the balanced equation above,
3 moles of O2 reacted to produce 2 moles of H2SO4.
Therefore, Xmol of O2 will react to produce 0.179 moleof H2SO4 i.e
Xmol of O2 = (3 x 0.179) / 2
Xmol of O2 = 0.2685 mole
Therefore, 0.2685 mole of O2 is needed for the reaction.
Finally, we shall determine the temperature of O2. This can be obtained by using the ideal gas equation as follow:
Volume (V) of O2 = 5.01 L
Pressure (P) = 0.860 atm
Number of mole (n) of O2 = 0.2685 mole
Gas constant (R) = 0.0821 atm.L/Kmol
Temperature (T) =..?
PV =nRT
0.860 x 5.01 = 0.2685 x 0.0821 x T
Divide both side by 0.2685 x 0.0821
T = (0.860 x 5.01) /(0.2685 x 0.0821)
T = 195.5 K
Therefore, the temperature of O2 must be 195.5 K.