Answer:
A bimolecular nucleophilic substitution (SN2) reaction is a type of nucleophilic substitution whereby a lone pair of electrons on a nucleophile attacks an electron deficient electrophilic center and bonds to it, resulting in the expulsion of a leaving group.
Consider the following reaction at 298.15 K: Co(s)+Fe2+(aq,1.47 M)⟶Co2+(aq,0.33 M)+Fe(s) If the standard reduction potential for cobalt(II) is −0.28 V and the standard reduction potential for iron(II) is −0.447 V, what is the cell potential in volts for this cell? Report your answer with two significant figures.
Answer:
The correct answer is 0.186 V
Explanation:
The two hemirreactions are:
Reduction: Fe²⁺ + 2 e- → Fe(s)
Oxidation : Co(s) → Co²⁺ + 2 e-
Thus, we calculate the standard cell potential (Eº) from the difference between the reduction potentials of cobalt and iron, respectively, as follows:
Eº = Eº(Fe²⁺/Fe(s)) - Eº(Co²⁺/Co(s)) = -0.28 V - (-0.447 V) = 0.167 V
Then, we use the Nernst equation to calculate the cell potential (E) at 298.15 K:
E= Eº - (0.0592 V/n) x log Q
Where:
n: number of electrons that are transferred in the reaction. In this case, n= 2.
Q: ratio between the concentrations of products over reactants, calculated as follows:
[tex]Q = \frac{ [Co^{2+} ]}{[Fe^{2+} ]} = \frac{0.33 M}{1.47 M} = 0.2244[/tex]
Finally, we introduce Eº= 0.167 V, n= 2, Q=0.2244, to obtain E:
E= 0.167 V - (0.0592 V/2) x log (0.2244) = 0.186 V
If 100-mL of 1.0 M Sr(OH)2 is added to 100 mL of 1.0 M HCl, the pH of the mixture would be _____. Group of answer choices
Answer:
pH = 13.7
Explanation:
A strong acid (HCl) reacts with a strong base Sr(OH)₂ producing water and a salt, thus:
2HCl + Sr(OH)₂ → 2H₂O + SrCl₂
To solve this problem, we need to find initial moles of both reactants and, with the chemical equation find limiting reactant and moles in excess to find pH as follows:
The initial moles of HCl and Sr(OH)₂ are:
100mL = 0.1L ₓ (1.0mol / L) = 0.100 moles of both HCl and Sr(OH)₂
As 2 moles of HCl reacts per mole of Sr(OH)₂, moles of Sr(OH)₂ that reacts with 0.100 moles of HCl are:
0.100 moles HCl ₓ (1 mol Sr(OH)₂ / 2 mol HCl) = 0.050 moles Sr(OH)₂
That means HCl is limiting reactant and after reaction will remain in solution:
0.100 mol - 0.050mol =
0.050 moles of Sr(OH)₂
Find pH:
1 mole of Sr(OH)₂ contains 2 moles of OH⁻, 0.050 moles contains 0.050×2 = 0.100 moles of OH⁻. In 200mL = 0.2L:, molar concentration of OH⁻ is:
0.100 moles / 0.2L =
[OH⁻] = 0.5M
As pOH of a solution is -log[OH⁻],
pOH = -log 0.5M
pOH = 0.301
And knowing:
pH = 14 - pOH
pH = 14 - 0.301
pH = 13.7Plzzz help and solve this using factor labeling
Answer:
there are 37,8541 liters in 10 gallons
Which of the following ionic lattices would have the highest melting point?
A. Potassium oxide
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B. Boron nitride
C. Beryllium oxide
D. Lithium chloride
Answer:
I think, berryllium oxide, is answer.Explanation:
Hope it helps you....The ionic lattices would have the highest melting point Potassium oxide. option A is correct.
what is ionic lattice?An ionic compound is a giant structure of ions. The ions have a regular, repeating arrangement called an ionic lattice. The lattice is formed because the ions attract each other and form a regular pattern with oppositely charged ions next to each other.
Ionic compounds are held together by electrostatic forces between oppositely charged ions.
These forces are usually referred to as the ionic lattice contains such a large number of ions, that a lot of energy is needed to overcome this ionic bonding so ionic compounds have high melting and boiling points.
therefore, sodium oxide has the highest melting point. option A is correct
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proteins contain
a. oxygen
b. nitrogen
c. hydrogen
Answer:
All of the above
Explanation:
Proteins contain a long chain of amino acids which are a chain of oxygen, nitrogen, carbon, hydrogen or sulfur.
HOPE THIS HELPED
Which of the following is an example of a scientific theory?
Matter can be neither created nor destroyed.
Force equals mass times acceleration.
Matter behaves the way it does because it is made of atoms.
There is probably life on Mars.
C. Matter behaves the way it does because it is made of atoms.
Answer:
Matter can neither be created nor destroyed
Explanation:
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An atom of 122In has a mass of 121.910280 amu. Calculate the binding energy in MeV per NUCLEON. Use the masses: mass of 1H atom
The given question is incomplete, the complete question is:
An atom of 122In has a mass of 121.910280 amu. Calculate the binding energy in MeV per atom. Use the masses: mass of 1H atom = 1.007825 amu mass of a neutron = 1.008665 amu 1 amu = 931.5 MeV
Answer:
The correct answer is 1029.95 MeV.
Explanation:
Based on the given information,
The mass of proton is 1.007825, the mass of neutron is 1.008665.
The atomic number of Indium is 49, therefore, the number of neutrons will be, 122-49 = 73.
Now the calculated mass will be,
= 49 * 1.007825 + 73 * 1.008665
= 49.383425 + 73.632545
= 123.01597
The mass defect is calculated by subtracting the actual mas from calculated mass,
Mass defect = Actual mass - Calculated mass
= 121.910280 - 123.01597
= -1.10569 amu
Now the binding energy will be,
Binding energy = 1.10569 * 931.5 MeV
= 1029.95 MeV
Why will the conjugate base of a weak acid affect pH? Select the correct answer below: it will react with hydroxide
Answer:
It will react with water
Explanation:
I know this is an older question, but I just wanted to provide the correct answer.
Since we are dealing with a weak base, and the acid is somewhat stronger, it will react with the water molecules to produce hydronium, which will affect the pH of the solution.
The conjugate base of a weak acid affect pH because it will react with hydronium ion.
A weak acid is an acid that does not dissociate completely in water. On the other hand, a strong acid achieves almost 100% dissociation in water.
Acids dissociate in water to yield the hydronium ion and a conjugate base. For instance, the weak acid, acetic acid is dissociated as follows;
CH3COOH(aq) + H2O(l) ⇄ CH3COO-(aq) + H3O+(aq)
We can see that the conjugate base( CH3COO-) could react with the hydronium ions thereby moving the equilibrium position to the left hand side and affecting the pH by decreasing the hydronium ion concentration.
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Missing parts;
Why will the conjugate base of a weak acid affect pH? Select the correct answer below: O it will react with hydroxide O it will react with water O it will react with hydronium O none of the above
Which is an intensive property of a substance?
Answer:
length
Explanation:
edge 2020
hope this helps!
Answer:
A.) Density
Explanation:
Correct on edge.
The enthalpy change for a chemical reaction is: a. the temperature change b. the amount of heat given off or absorbed c. related to molar volume d. none of the above
Answer:
b. the amount of heat given off or absorbed
Explanation:
Hello,
In this case, we should take into account a formal definition of enthalpy change such as an energetic change that occurs in a system when matter is transformed by a given chemical reaction from reactants to products. Thus, such energetic change is macroscopically exhibited and it is related with either a temperature increase or decrease; it means that if a reaction exhibits a temperature increase, we say that heat was given off and if the temperature exhibits a decrease, we say that heat is absorbed. For that reason, answer is b. the amount of heat given off or absorbed.
Regards.
A central atom has two lone pairs on opposite sides and four single bonds. What is the molecule geometry of the result?
A. octahedral
B. tetrahedral
C. square planar
D. linear
The correct answer is C. square planar
According to the Valence Shell Electron Pair Repulsion Theory(VSEPR), The shape of a molecule depends on the number of electron pairs in the molecule.
VSEPR theory was first coined by Gillespie and Nyhlom in 1957 as an improvement over the Sidgwick - Powell theory.
According to this theory, the shape of a molecule is determined by the number of electron pairs that surround the valence shell of the central atom in the molecule. The electron pairs are positioned as far apart in space as possible to minimize repulsion of electron pairs.
However, the presence of lone pairs distorts the shape anticipated for the molecule on the basis of VSEPR.
For a molecule having six electron pairs, an octahedral geometry is expected(electron domain geometry). However, the presence of two lone pairs which are positioned at opposite side of the four single bonds leads to an observed square planar molecular geometry.
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Answer:
square planar
Explanation:
which law states that the pressure and absolue tempeture of a fixed quantity of gas are directly proportional under constant volume conditions?
Answer:
Gay lussacs law
Explanation:
Cite examples of how copper deposits occur. Choose one or more: A. as an agglomeration metal B. as a native metal C. in carbonate ore minerals D. in sulfide ore minerals
Answer:
A. as an agglomeration metal
B. as a native metal
D. in sulfide ore minerals
Explanation:
Copper is a metal with symbol Cu and atomic number 29. It has a pinkish-orange color and is malleable, ductile and has a high thermal and electrical conductivity. This is why it is often used in electrical appliances.
Copper exists as an agglomeration metal, as a native metal or in sulfide ore minerals such as Cu2S.
The examples of copper deposits are agglomeration metal, as a native metal or in sulfide ore minerals. Option A, B, and D are correct.
Copper is a metal with high thermal and electrical conductivity. hence, it is often used in electrical appliances.
Copper found as an agglomeration metal, as a native metal or in sulfide ore minerals such as [tex]\bold { Cu_2S.}[/tex]
Therefore, the examples of copper deposits are agglomeration metal, as a native metal or in sulfide ore minerals. Option A, B, and D are correct.
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If a sample of C-14 initially contains 1.6 mmol of C-14, how many millimoles will be left after 2250 years
Answer: 1.2 millimoles will be left after 2250 years
Explanation:
Expression for rate law for first order kinetics is given by:
[tex]t=\frac{2.303}{k}\log\frac{a}{a-x}[/tex]
where,
k = rate constant
t = age of sample
a = let initial amount of the reactant
a - x = amount left after decay process
a) for completion of half life:
Half life is the amount of time taken by a radioactive material to decay to half of its original value.
[tex]t_{\frac{1}{2}}=\frac{0.693}{k}[/tex]
[tex]k=\frac{0.693}{5730}=0.00012years^{-1}[/tex]
b) Amount left after 2250 years
[tex]2250=\frac{2.303}{k}\log\frac{1.6}{a-x}[/tex]
[tex]2250=\frac{2.303}{0.00012}\log\frac{1.6}{a-x}[/tex]
[tex]\log\frac{1.6}{a-x}=0.117[/tex]
[tex]\frac{1.6}{a-x}=1.31[/tex]
[tex]{a-x}=\frac{1.6}{1.31}=1.2[/tex]
Thus 1.2 millimoles will be left after 2250 years
2. Which one is the odd one
out and why?
o Water
• Hydrogen
Chlorine
o Aluminum
Answer:
Reaction of Chlorine with Hydrogen Chlorine and Hydrogen mixed together explodes when exposed to sunlight, which produces Hydrogen Chloride. In the dark away from sunlight, no reaction occurs, so light energy is required for a reaction. Cl2 + H2 = 2 HCl Reaction of Chlorine with Non-Metals Chlorine directly combines with most non-metals.
Explanation:
I hope this helps bro
what are the monomers of bakelite
Answer:
Bakelite is a polymer made up of the monomers phenol and formaldehyde. This phenol-formaldehyde resin is a thermosetting polymer.
Answer: The monomers of bakelite are formaldehyde and phenol
Explanation:
Methyl iodide reacts irreversibly with azide ion with rate = k[CH3I][N3–]. CH3I(aq) + N3–(aq) → CH3N3(aq) + I–(aq) The reaction is carried out with an initial concentration of CH3I of 0.01 M. Which statement about the reaction is correct?
Answer:
(D) The reaction cannot take place in a single elementary step
Explanation:
Statements are:
(A) The time it takes for [CH3I] to decrease to 0.005 M is independent of [N3-], as long as [N3] >> [CH3I].
B) If the initial concentrations of azide and CH3I are equal, then it takes half as long for [CH3I] to decrease to 0.005 M as it does for it to decrease from 0.005 M to 0.0025 M.
(C) The reaction rate is significantly smaller if excess I- is added to the solution.
(D) The reaction cannot take place in a single elementary step.
The rate of the reaction is:
rate = k[CH3I][N3–].
That means rate depends of concentration of CH₃I as much as N₃⁻ concentration
(A) The time it takes for [CH3I] to decrease to 0.005 M is independent of [N3-], as long as [N3] >> [CH3I]. FALSE. The reaction rate depends of N₃⁻ as much as CH₃I
B) If the initial concentrations of azide and CH3I are equal, then it takes half as long for [CH3I] to decrease to 0.005 M as it does for it to decrease from 0.005 M to 0.0025 M. FALSE. Reaction is second-order. Half-life is 1/K[A]₀. If initial concentration is 0.1M, to a concentration of 0.005M it takes:
1/K*0.1. If initial concentration is 0.005M it takes 1/K*0.005. That means it takes half to decrease from 0.005M to 0.0025 as it does for it to decrease from 0.01M to 0.005M.
(C) The reaction rate is significantly smaller if excess I- is added to the solution. FALSE. Reaction rate is independent of I⁻
(D) The reaction cannot take place in a single elementary step. TRUE. As this reaction is a single-replacement reaction implies the formation of 1 C-N bond. But also the rupture of the C-I bond is impossible to explain this kind of reaction in a single elementary step.
Because of movements at the Mid-Atlantic Ridge, the Atlantic Ocean widens by about 2.5 centimeters each year. Explain which type of plate boundary causes this motion.
Answer:
A divergent plate boundary
Explanation:
At a divergent boundary, the plates pull away from each other and generate new crust.
Answer:
Because the ocean becomes larger, this is a divergent plate boundary. Divergent plates cause the ocean floor to expand, making the ocean larger.
Explanation:
PLATO ANSWER
A 6.0-L vessel was found to contain 1.0 mol BrCl 3 , 2.0 mol Br 2 and 6.0 mol Cl 2 at equilibrium. What is the equilibrium constant, K c , for this equilibrium mixture for the reaction 2BrCl 3 (g) Br 2 (g) 3Cl 2 (g)
Answer:
Writing a balanced Equation for the reaction
Br₂ + 3Cl₂ ==> 2BrCl₃
Kc = [BrCl₃]² / [Br₂][Cl₂]³
Each Concentration (n) = moles/volume of container.
(nBrCl₃)= 1/6 = 0.167moldm-³
(nBr₂) = 2/6 = 0.333moldm-³
(nCl₂) = 6/6 = 1moldm-³
Kc = (0.167)² / (0.333)(1)³
Kc = 0.0838.
Place the following compounds in order of increasing strength of intermolecular forces. CH4 CH3CH2CH3 CH3CH3 Group of answer choices CH3CH2CH3 < CH4 < CH3CH3 CH4 < CH3CH3 < CH3CH2CH3 CH3CH2CH3 < CH3CH3 < CH4 CH4 < CH3CH2CH3 < CH3CH3 CH3CH3 < CH4 < CH3CH2CH3
Answer:
CH4 < CH3CH3 < CH3CH2CH3
Explanation:
Alkanes are saturated aliphatic hydrocarbons that undergoes intermolecular Van der waals forces. Van der waals forces are the attractive forces which make it possible for non-polar molecules to form liquids and solids.
Van der waals force are described as intermolecular forces arising from induced fluctuating dipoles in atoms and molecules brought about by movement of electrons around the atomic nucleus.
An example of the Van der waals force is the london dispersion force that occurs in the alkane family. It is the weakest of all electrical forces that act between atoms and molecules, These forces are responsible for liquefaction or solidification of non-polar substances at low temperature.
The strength of the intermolecular forces is based on the number of electrons surrounding the molecule and the surface area of the molecule. SO, in alkanes, the longer the carbon chain, the more stronger the intermolecular forces.
Which of the following processes release energy? a. ball rolling down a hill b. formation of copper (II) oxide from copper and oxygen c. formation of ice from liquid water d. condensation of water on a wind shield of a car
Answer:
d. condensation of water on a wind shield of a car
Explanation:
Condensation involves the conversion of moist air into liquid.
Gas has a higher energy compared to liquid. This is why Gas particles move at random motion and faster in relation to solid and liquid particles due to the high energy content.
The conversion of the gas to liquid means that there was loss or release of energy which validates the answer.
Suppose a student completes an experiment with an average value of 2.9 mL and a calculated standard deviation of 0.71 mL. What is the minimum value within a 1 SD range of the average
Answer:
The correct answer is 2.2 mL.
Explanation:
Given:
Average: 2.9 mL
SD: 0.71 mL
We can define a 1 SD range in which the value of volume (in mL) will be comprised:
Volume (mL) = Average ± SD = (2.9 ± 0.7) mL
Maximum value= Average + SD= 2.9 + 0.7 mL = 3.6 mL
Minimum value= Average - SD = 2.9 - 0.7 mL = 2.2 mL
Thus, the minimum value within a 1 SD range of the average is 2.2 mL
The minimum value within 1 SD is 2.19 mL
The z score is used to determine by how many standard deviations the raw score is above or below the mean. The z score is given by:
[tex]z=\frac{x-\mu}{\sigma} \\\\where\ x\ is\ raw\ score, \mu=mean,\sigma=standard\ deviation[/tex]
Given that μ = 2.9 mL, σ = 0.71 mL; hence:
The minimum value within 1 SD range = μ ± σ = 2.9 ± 0.71 = (2.19, 3.61)
Therefore the minimum value within 1 SD is 2.19 mL
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An aqueous solution of potassium bromide, KBr, contains 4.34 grams of potassium bromide and 17.4 grams of water. The percentage by mass of potassium bromide in the solution is 20 %.
Answer:
True
Explanation:
The percentage by mass of a substance in a solution can be calculated by dividing the mass of the substance dissolved in the solution by the total mass of the solution. This can be expressed mathematically as:
Percentage by mass = mass of substance in solution/mass of solution x 100
In this case;
mass of KBr = 4.34 grams
mass of water = 17.4 grams
mass of solution = mass of KBr + mass of water = 4.34 + 17.4 = 21.74
Percentage by mass of KBr = 4.34/21.74 x 100
= 19.96 %
19.96 is approximately 20%.
Hence, the statement is true.
For a sample of stomach acid that is 2.02×10−2 M in HCl, how many moles of HCl are in 14.6 mL of the stomach acid?
Answer:
0.0002949 moles
Explanation:
Concentration = 2.02×10−2 M
Volume = 14.6 mL = 0.0146 L (Upon converting to litres)
Number of moles = ?
These variables are related by the fllowing equation;
Concentration = Number of moles / Volume
Number of moles = Concentration * Volume
Number of moles = 2.02×10−2 * 0.0146 = 0.0002949 moles
Arrange the compounds in order of decreasing magnitude of lattice energy:
a. LiBr
b. KI
c. CaO.
Rank from largest to smallest.
Answer:
The correct answer is CaO > LiBr > KI.
Explanation:
Lattice energy is directly proportional to the charge and is inversely proportional to the size. The compound LiBr comprises Li+ and Br- ions, KI comprises K+ and I- ions, and CaO comprise Ca²⁺ and O²⁻ ions.
With the increase in the charge, there will be an increase in lattice energy. In the given case, the lattice energy of CaO will be the highest due to the presence of +2 and -2 ions. K⁺ ions are larger than Li⁺ ion, and I⁻ ions are larger than Br⁻ ion.
The distance between Li⁺ and Br⁻ ions in LiBr is less in comparison to the distance between K⁺ and I⁻ ions in KI. As a consequence, the lattice energy of LiBr is greater than KI. Therefore, CaO exhibits the largest lattice energy, while KI the smallest.
Arranging the chemical compounds in order of decreasing magnitude of lattice energy, we have:
c. CaO.
a. LiBr
b. KI
Lattice energy can be defined as a measure of the energy required to dissociate one (1) mole of an ionic compound into its constituent anions and cations, in the gaseous state.
Hence, it is typically used to measure the bond strength of ionic compounds.
Generally, lattice energy is inversely proportional to the size of the ions and directly proportional to their electric charges.
Lithium bromide (LiBr) comprises the following ions:
[tex]Li^+[/tex] and [tex]Br^-[/tex]Potassium iodide (KI) comprises the following ions:
[tex]K^+[/tex] and [tex]I^-[/tex]Calcium oxide (CaO) comprises the following ions:
[tex]Ca^{2+}[/tex] and [tex]O^{2-}[/tex]From the above, we can deduce that there is an increase in the charge possessed by the ionic chemical compounds and as such this would result in an increase in the lattice energy.
In order of decreasing magnitude of lattice energy, the chemical compounds are arranged as:
I. CaO.
II. KI.
III. LiBr.
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A student is performing a Benedict’s test on an unknown substance. He adds the reagent (the chemical required to make a color change), and nothing happens. What can he conclude? A- The substance is glucose-based. B- The substance is not glucose-based. C- The test was inconclusive because he needed to also test with iodine or vinegar. D- The test was inconclusive because he forgot to add heat.
Answer:
The correct answer is : option D. The test was inconclusive because he forgot to add heat.
Explanation:
Benedict's test is a test that is used to confirm the presence of the simple carbohydrates (mono saccharides and some disaccharides). It is a reagent made by mixture of solution of CuSO4 with sodium citrate and Na2CO3.
Benedict's reagent is added to the substance to test and then heated if it turns yellow to orange or red the presence of simple sugar is confirmed.
Thus, the correct answer is : option D. The test was inconclusive because he forgot to add heat.
Answer:
The test was inconclusive because the student forgot to add heat.
Explanation:
If the test revealed it was not glucose, then the student could run these tests. The student, however, does not need these substances to run the glucose test properly.
Write chemical equations for the reactions that occur when solutions of the following substances are mixed:
c. OH- and H₂PO₄-
d. C₅H₅N pyridine, a base) and HC₂H₃O₂ (acetic acid)
#c
[tex]\\ \rm\hookrightarrow H_2PO_4^-+OH-\longrightarrow HPO_4^{2-}+H_2O[/tex]
H_2PO_4 is a base according to bronsted Lowry theory.So it loses a H+ and OH- takes that to form water#2
[tex]\\ \rm\hookrightarrow C_5H_5N+C_2H_4O_2\longrightarrow C_6H_6N^++C_2H_3O_2^-[/tex]
Pyridine is a bronsted base .So it forms pyridine cation by taking one H^+ from acetic acidHow many moles of oxygen are in 49.2 grams of carbon dioxide?
Answer:
Number of mole in Oxygen = 2.24 mol
Explanation:
Given:
Amount of carbon dioxide (CO₂) = 49.2 gram
Find:
Number of moles in Oxygen
Computation:
Molecular weight of CO₂ = 44 gram (Approx)
Number of mole in CO₂ = 49.2 / 44
Number of mole in CO₂ = 1.11818182 mol
CO₂ has 2 mole of Oxygen,
So,
Number of mole in Oxygen = 2 × 1.11818182
Number of mole in Oxygen = 2.23636364
Number of mole in Oxygen = 2.24 mol
When 2 moles of NH3(g) react with N2O(g) to form N2(g) and H2O(g) according to the following equation, 880 kJ of energy are evolved. 2NH3(g) 3N2O(g)4N2(g) 3H2O(g) Is this reaction endothermic or exothermic
Answer:
Explanation:
This is a bit of a trick question.
Usually an exothermic reaction is written as
A + B - heat = C + D
The meaning of this equation is that when the bonds of the reactants break, heat has to be given away to the environment. On the left, exothermic means that heat has to be given.
The wording on this question means that heat is a product
A + B = C + D + heat.
In other words heat is given up to the environment. So this reaction is exothermic.
How are animals used in vaccine development?
Answer:
Animals whose certain organs closely match those of humans or have similar genetic makeup are used in vaccine tests because the results can closely resemble those same results on humans.
Explanation:
Answer:
they use them to test the effectiveness of the vaccine.
Explanation: